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http://dx.doi.org/10.5012/bkcs.2014.35.10.2929

Cd(II) and Zn(II) Complexes Containing N,N'-Bidentate N-(Pyridin-2-ylmethylene)cyclopentanamine: Synthesis, Characterisation and Methyl Methacrylate Polymerisation  

Song, Yujin (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Kim, Dongil (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Lee, Ha-Jin (Jeonju Center, Korea Basic Science Institute (KBSI))
Lee, Hyosun (Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.10, 2014 , pp. 2929-2934 More about this Journal
Abstract
The reaction between $[CdBr_2{\cdot}4H_2O]$ and anhydrous $[ZnCl_2]$ with N,N'-bidentate N-(pyridin-2-ylmethylene)-cyclopentanamine (impy) in ethanol yields dimeric $[(impy)Cd({\mu}-Br)Br]_2$ and monomeric $[(impy)ZnCl_2]$ complexes, respectively. The X-ray crystal structure of Cd(II) and Zn(II) complexes revealed that the cadmium atom in $[(impy)Cd({\mu}-Br)Br]_2$ and zinc in $[(impy)ZnCl_2]$ formed a distorted trigonal-bipyramidal and tetrahedral geometry, respectively. Both complexes showed moderate catalytic activity for the polymerisation of methyl methacrylate (MMA) in the presence of modified methylaluminoxane (MMAO), with polymethylmethacrylate (PMMA) syndiotacticity of about 0.70.
Keywords
Pyridyl-imines; Dimeric cadmium(II) complex; Zinc(II) complex; Methyl methacrylate (MMA); Syndiotacticity;
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