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http://dx.doi.org/10.9713/kcer.2012.50.4.632

Effect of Addition Amounts of Hydroxyethyl Methacrylate and Methyl Methacrylate on the Properties of Waterborne Polyurethane-Acrylic Hybrid Solutions  

Kim, Byung Suk (Department of Chemical and Biochemical Engineering, Konyang University)
Yoo, Byung Won (Technical Research Institute, Hanjin Chemical Co., LTD.)
Lee, Myung Goo (K.L.Tech Co., LTD.)
Byun, Tae Gang (Department of Food Science and Biotechnology, Konyang University)
Song, Ki Chang (Department of Chemical and Biochemical Engineering, Konyang University)
Publication Information
Korean Chemical Engineering Research / v.50, no.4, 2012 , pp. 632-638 More about this Journal
Abstract
Waterborne polyurethane dispersions (PUD) were synthesized from isophorone diisocyanate (IPDI), polycarbonate diol (PCD) and dimethylol propionic acid (DMPA) as starting materials. Subsequently, waterborne polyurethane-acrylic hybrid solutions were prepared by reacting the PUD with different amounts of the mixture of acrylate monomers, HEMA (2-hydroxyethyl methacrylate) and MMA (methyl methacrylate). As a result, the average particle size of waterborne polyurethane-acrylic hybrid solutions was increased with increasing the addition amounts of acrylate monomers. Also, the prepared coating films from waterborne polyurethane-acrylic hybrid solutions showed better abrasion resistance and chemical resistance than those of pure PUD.
Keywords
Coating Films; Chemical Resistance; 2-Hydroxyethyl Methacrylate; Methyl Methacrylate; Waterborne Polyurethane-Acrylic Hybrid Solutions;
Citations & Related Records
Times Cited By KSCI : 5  (Citation Analysis)
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1 Shin, Y. T., Hong, M. G., Choi, J. J., Lee, W. K., Lee, G. B., Yoo, B. W., Lee, M. G. and Song, K. C., "Preparation and Properties of Aminosilane Terminated Waterborne Polyurethane," Korean Chem. Eng. Res. (HWAHAK KONGHAK), 48(4), 434-439(2010).
2 Hong, M. G., Shin, Y. T., Choi, J. J., Lee, W. K., Lee, G. B., Yoo, B. W., Lee, M. G. and Song, K. C., "Preparation of Silylated Waterborne Polyurethane/Silica Nanocomposites Using Colloidal Silica," Korean Chem. Eng. Res. (HWAHAK KONGHAK), 48(5), 561-567(2010).
3 Shin, Y. T., Hong, M. G., Choi, J. J., Lee, W. K., Lee, G. B., Yoo, B. W., Lee, M. G. and Song, K. C., "Preparation of Waterborne Polyurethane/Silica Nanocomposites Using Tetraethylorthosilicate," Korean Chem. Eng. Res. (HWAHAK KONGHAK), 48(4), 428-433(2010).
4 Shin, Y. T., Hwang, J. H., Hong, M. G., Choi, J. J., Lee, W. K., Lee, G. B., Yoo, B. W., Lee, M. G. and Song, K. C., "Effect of Types of Silane Coupling Agents on the Properties of Waterborne Polyurethane," Korean Chem. Eng. Res. (HWAHAK KONGHAK), 49(3), 285-291(2011).   DOI
5 Kim, B. S., Hong, M. G., Yoo, B. W., Lee, M. G. and Song, K. C., "Effect of Types of Acrylate Monomers on the Properties of Waterborne Polyurethane-Acrylic Hybrid Solutions," Korean Chem. Eng. Res. (HWAHAK KONGHAK), 50(3), in press(2012).
6 Shin, Y. T., Hong, M. G., Choi, J. J., Lee, W. K., Yoo, B. W., Lee, M. G. and Song, K. C., "Effect of Addition of Pentaerythritol Triacrylate on the Properties of Waterborne Polyurethane," Korean Chem. Eng. Res. (HWAHAK KONGHAK), 49(4), 411-416(2011).   DOI
7 Shin, Y. T., Hong, M. G., Kim, B. S., Lee, W. K., Yoo, B. W., Lee, M. G. and Song, K. C., "Effect of Types of Acrylate Monomers on the Properties of Waterborne Polyurethane Dispersion," Korean Chem. Eng. Res. (HWAHAK KONGHAK), 49(5), 548-553(2011).   DOI
8 Han, S. H. and Park, D. W., "A Study on the Curing Characteristics and the Synthesis of Polyurethane Acrylate Hybrid Emulsion," J. Korean Ind. Eng. Chem., 17(2), 132-137(2006).   과학기술학회마을
9 ASTM D 3359, "Standard Test Methods for Measuring Adhesion by Tape Test," ASTM International, 927-929(1997).
10 Hwang, J. H. and Song, K. C., "Preparation of UV-Curable Organic- Inorganic Hybrid Coatings Using Alumina Sols and Acrylate Monomers," Korean Chem. Eng. Res. (HWAHAK KONGHAK), 49(3), 277-284(2011).   DOI