• 제목/요약/키워드: MIL 8.0

검색결과 41건 처리시간 0.02초

Synthesis of CdxZn1-xS@MIL-101(Cr) Composite Catalysts for the Photodegradation of Methylene Blue

  • Yang, Shipeng;Peng, Siwei;Zhang, Chunhui;He, Xuwen;Cai, Yaqi
    • Nano
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    • 제13권10호
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    • pp.1850118.1-1850118.17
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    • 2018
  • Nanoparticles of the semiconductor catalyst $Cd_xZn_{1-x}S$ were embedded into the metal organic framework MIL-101(Cr) to obtain $Cd_xZn_{1-x}S@MIL-101$(Cr) nanocomposites. These materials not only possess high surface areas and mesopores but also show good utilization of light energy. The ultraviolet-visible diffuse reflectance patterns of $Cd_xZn_{1-x}S@MIL-101$(Cr) nanocomposites showed that $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) possessed good visible light response ability among the synthesized nanocomposites. The photocatalytic performance of the $Cd_xZn_{1-x}S@MIL-101$(Cr) nanocomposites were tested via degradation and mineralization of methylene blue in neutral water solution under light irradiation using a 300W xenon lamp. As a result, using $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) as a catalyst, 99.2% of methylene blue was mineralized within 30 min. Due to the synergistic effect of adsorption by the MIL-101(Cr) component and photocatalytic degradation provided by the $Cd_{0.8}Zn_{0.2}S$ component, the $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) catalyst displayed superior photocatalytic performance relative to $Cd_{0.8}Zn_{0.2}S$ and MIL-101(Cr). Furthermore, $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) possessed excellent stability during photodegradation and exhibited good reusability. The remarkable photocatalytic performance of $Cd_{0.8}Zn_{0.2}S@MIL-101$(Cr) is likely due to the effective transfer of electrons and holes at the heterojunction interfaces.

Ni Nanoparticles Supported on MIL-101 as a Potential Catalyst for Urea Oxidation in Direct Urea Fuel Cells

  • Tran, Ngan Thao Quynh;Gil, Hyo Sun;Das, Gautam;Kim, Bo Hyun;Yoon, Hyon Hee
    • Korean Chemical Engineering Research
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    • 제57권3호
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    • pp.387-391
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    • 2019
  • A highly porous Ni@MIL-101catalyst for urea oxidation was synthesized by anchoring Ni into a Cr-based metal-organic framework, MIL-101, particles. The morphology, structure, and composition of as synthesized Ni@MIL-101 catalysts were characterized by X-Ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. The electro-catalytic activity of the Ni@MIL-101catalysts towards urea oxidation was investigated using cyclic voltammetry. It was found that the structure of Ni@MIL-101 retained that of the parent MIL-101, featuring a high BET surface area of $916m^2g^{-1}$, and thus excellent electro-catalytic activity for urea oxidation. A $urea/H_2O_2$ fuel cell with Ni@MIL-101 as anode material exhibited an excellent performance with maximum power density of $8.7mWcm^{-2}$ with an open circuit voltage of 0.7 V. Thus, this work shows that the highly porous three-dimensional Ni@MIL-101 catalysts can be used for urea oxidation and as an efficient anode material for urea fuel cells.

여성가장의 성역할 정체감유형과 생의 의미수준 (The Relationships between Sex-Role Identity and the Meaning in Life for a Matriarch)

  • 김숙남;최순옥;신경일;이정지
    • 여성건강간호학회지
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    • 제8권2호
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    • pp.190-200
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    • 2002
  • The purposes of this study were to understand the sex role identity and the meaning in life(MIL) of matriarchs and analyze their relationships to offer basic data for effective nursing strategies for improving MIL. The data for this study was collected from the 10th of August to the 30th of November, 2000. The subjects were women registered in an occupational training program for unemployed matriarchs which is held in the Working Women's Center in Busan. The measurement tools of this study were MIL(unpublished)developed by researchers and sex role inventory designed by Kim Deuk Ran(1992). The results of this study were as follows: 1.Sex role identities of matriarchs were feminity 13.7%, masculinity 13.4%, androgyny 37.8% and undifferentiated 35.1%. 2. The mean MIL for matriarchs was $173.46{\pm}16.09$. 3. The levels of MIL were 57.2% of the subjects felt a loss of meaning in life, i. e. existential vacuum, 42.8% were in pursuit of meaning but had not discovered it completely and 6.0% felt they had established meaning in life. 4.There were significant differences in MIL levels, concurrent to 4 types of sex role identities(F=11.93, P=.000). And according to Scheffe's post test, between feminity and masculinity, feminity and androgyny, masculinity and the undifferentiated, androgyny and the undifferentiated, there were significant differences. From the results of this study, most matriarchs felt loss of meaning in life, i. e. existential vacuum, and the group with masculine sex role identity had the highest level of MIL. In conclusion, the factors related to masculine sex role identity are necessary to develop nursing strategies for improving levels of MIL.

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실험동물 발생 유전자의 확인 (Identification of Developmental Related Genes in the Lab Animal)

  • 이재달
    • 한국산학기술학회논문지
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    • 제10권6호
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    • pp.1407-1413
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    • 2009
  • 본 연구에서는 쥐의 미성숙 난자의 체외 성숙과정에서 매우 특이적으로 발현되는 후보 단백질 변화를 동정하려는 목적으로 체외 성숙 과정에서 GV 단계의 미성숙 난자와 MIl 단계의 난자를 실험 시료로 사용하였다. 그리고 단백질 Chip은 선행 실험에서 가장 효과적인 CM10을 사용하여 SELDI -TOF MS 분석 장치를 이용하여 후보단백질을 동정하였다. MIl 단계의 미성숙 난자와 비교하여 GV 단계의 미성숙 난자에서 16개의 후보단백질이 높게 발현되었으며, 이때 발현된 후보 단백질 각각의 분자량은 8180(후보단백질 2개), 10226 (5개), 15767(5개), 16770(4개) 달톤(dalton)이였다. 또한 29개의 후보단백질은 MIl 단계의 미성숙 난자에서 높게 발현되었고 이들의 분자량은 각각 10832(3개)17743(8개)20122(3개)22131(3개) 24857(7개) 33507(5개) 달톤 이였다. 한편 전체 후보 단백질 45개의 분석을 Real time RT-PCR에서 수행하여 13개의 잠재적인 후보단백질을 확인 동정하였다.

The safety of one-per-mil tumescent infiltration into tissue that has survived ischemia

  • Prasetyono, Theddeus Octavianus Hari;Nindita, Eliza
    • Archives of Plastic Surgery
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    • 제46권2호
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    • pp.108-113
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    • 2019
  • Background The aim of this study was to assess the safety of one-per-mil tumescent injections into viable skin flaps that had survived an ischemic insult, in order to assess the potential suitability of one-per-mil tumescent injections in future secondary reconstructive procedures such as flap revision and refinements after replantation. Methods Forty groin flaps harvested from 20 healthy Wistar rats weighing 220 to 270 g were subjected to acute ischemia by clamping the pedicle for 15 minutes. All flaps showing total survival on the 7th postoperative day were randomly divided into group A (one-per-mil tumescent infiltration; n=14), group B (normal saline infiltration; n=13), and group C (control, with no infiltration; n=13) before being re-elevated. Transcutaneous oxygen tension ($TcPO_2$) was measured before and after infiltration, and changes in $TcPO_2$ were statistically analyzed using analysis of variance, the paired t-test, and the independent t-test. The viability of flaps was also assessed using the Analyzing Digital Images software at 7 days after the second elevation. Results Thirty-nine flaps survived to the final assessment, with the sole exception of a flap from group A that did not survive the first elevation. $TcPO_2$ readings showed significant decreases (P<0.05) following both one-per-mil tumescent ($99.9{\pm}5.7mmHg$ vs. $37.2{\pm}6.3mmHg$) and normal saline ($103{\pm}8.5mmHg$ vs. $48.7{\pm}5.9mmHg$) infiltration. Moreover, all groin flaps survived with no signs of tissue necrosis. Conclusions One-per-mil tumescent infiltration into groin flap tissue that had survived ischemia did not result in tissue necrosis, although the flaps experienced a significant decrease of cutaneous oxygenation.

노인환자에게 제공하는 개국약국 약료서비스의 경제적 가치 (Economic Value of Pharmaceutical Care for the Elderly Patients in Community Pharmacies)

  • 손현순;신현택
    • 약학회지
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    • 제51권5호
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    • pp.327-335
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    • 2007
  • This study was to evaluate economic impact of a comprehensive pharmaceutical care intervention provided by community pharmacists on drug-related morbidity and mortality in the elderly population, in a societal perspective. Clinical outcomes of pharmaceutical care included compliance increase, inappropriate medication discontinuation, and subsequent drug-related morbidity and mortality reduction. Economic outcomes included cost savings from direct medical costs reduction such as medication and healthcare resource utilization. Input costs for pharmaceutical care included pharmacist time and computerized prescription review supporting program costs. Model parameters of outcomes were derived from published literatures, and costs were from literatures and health insurance statistical data in Korea. Annual costs and benefits were estimated in the year 2005. Current usual care and standardized pharmaceutical care required 0.3 and 2.0 hours per year respectively, for elderly outpatient using average 4.4 prescription drugs per visit and average annual frequency of 17.8 pharmacy visits. Comprehensive pharmaceutical care provided to overall elderly outpatients at community pharmacies would have cost of \74,994 mil. and benefit of \357,002 mil. per year. Benefit:cost ratio was 4.8:1 and net benefit was \282,008 mil/year. It was corresponded to net benefit of \73,816/year for individual elderly patient. In addition, pharmaceutical care was estimated to reduce 1,531 drug-related deaths/year. Conclusively this study, a first attempt in Korea to evaluate an economic value of pharmaceutical care at community pharmacies, proved that it was a cost-effective intervention having significant economic benefit.

잡음과 회전에 강인한 SIFT 기반 PCB 영상 정렬 알고리즘 개발 (Robust PCB Image Alignment using SIFT)

  • 김준철;최학남;박은수;최효훈;김학일
    • 제어로봇시스템학회논문지
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    • 제16권7호
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    • pp.695-702
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    • 2010
  • This paper presents an image alignment algorithm for application of AOI (Automatic Optical Inspection) based on SIFT. Since the correspondences result using SIFT descriptor have many wrong points for aligning, this paper modified and classified those points by five measures called the CCFMR (Cascade Classifier for False Matching Reduction) After reduced the false matching, rotation and translation are estimated by point selection method. Experimental results show that the proposed method has fewer fail matching in comparison to commercial software MIL 8.0, and specially, less than twice with the well-controlled environment’s data sets (such as AOI system). The rotation and translation accuracy is robust than MIL in the noise data sets, but the errors are higher than in a rotation variation data sets although that also meaningful result in the practical system. In addition to, the computational time consumed by the proposed method is four times shorter than that by MIL which increases linearly according to noise.

전하결합소자를 이용한 Analog-to-Digital 변화기 (Charge-coupled analog-to-Digital Converter)

  • 경종민;김충기
    • 대한전자공학회논문지
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    • 제18권5호
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    • pp.1-9
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    • 1981
  • 4-bit 전하결합 A/D 변환기에 대한 실험 결과를 제시하였다. Successive approximation algorithm 에 필요한 대개의 기능을 CCADC(charge coupled A/D converter)라는 mono-lithiic chip으로 실현하였다. CCADC는 P-channel 전하결합소자 제작기술에 의하여 만들어졌으며, Chip면적은 약 4,200 $mil^2$이었다. 동작 clock 주파수 범위는 500Hz ~ 200KHz로 나타났으며, 이 주파수 범위내에서는 약 2.4 Volt의 전신호 전압 구간을 1LSB/clok주기의 속도로 변하는 ramp 입력신호에 대하여 16가지의 binary code가 빠짐없이 관찰되었다. MSB단부터 LSB단의 순서로 정격 전하용량이 각각 3.6pC, 1.8pC, 0.9pC, 0.45pC인 4개의 연속된 potential well(M-well)간의 면적비를 (8:4:2:1)로 유지하기 위한 설계기술에 대하여 토론하였다. 끝으로, 제작된 A/D변환기에 있어서 과도한 conversion nonlinearity의 원인이 되는 dumpslot 효과에 대하여 설명하였으며, dump slot으로 인한 오동작을 막기 위한 방법으로서 slot zero 삽입방식을 제안하고 이에 대한 실험결과를 제시하였다.

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한반도(韓半島) 옥천대(沃川帶) 탄질이암층중(炭質泥岩層中)의 저품위(低品位) 우라늄광(鑛)의 부존상태(賦存狀態) 및 우라늄, 바나듐 회수공정개발연구(回收工程開發硏究) ( I ) (Uranium Occurrences, and Process Development for Recovering Uranium and Vanadium from Uranium Ore in Coaly Meta-Pelites in Ogcheon Terrain, Korea (I))

  • 소칠섭;최청송
    • 자원환경지질
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    • 제17권1호
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    • pp.35-47
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    • 1984
  • Combined mineralogical and geochemical studies were made on two hundred eighty one representative samples from uraniferous coaly meta-pelites of the Ogcheon metamorphic terrain. Different mineral occurrence of the areas investigated should be taken into account for chemical processes for uranium extraction. Secondary uranium minerals identified are metauranocircite, metatorbernite and autunite. These are disseminated mostly on the laumontites which infused and filled secondary openings in the coaly matrix, and are often closely associated with iron oxides. The uranium distribution show distinctly log normal. Geochemical correlation coefficient of uranium and organic carbon displays +0.624~+0.796. The relationship of the major components to uranium can be expressed by the following regression equation: Log $(U_3O_8{\times}10^4)$=1.40117-0.00076 (quartz) -0.00118 (muscovite) +0.00235 (biotite) +0.00323 (other silicates) - 0.01114 (apatite) +0.01124 (hematite) +0.00149 (limonite) -0.01823 (opaques)+0.03049 (organic carbon). Uranium in the coaly meta-pelites of the Ogcheon Group was deposited together under same physico-chemical environmental conditions. There is a considerable variation in the ${\delta}^{34}S$ values (11.2~16.8 per mil) of the pyrites from the U-bearing meta-pelites, which implies sedimentary origin. The two U-bearing coaly rocks analyzed have ${\delta}^{13}C$ values between -16.88~-18.00 per mil, which suggests organic.

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A Study on the Electrical Characteristics of Different Wire Materials

  • Jeong, Chi-Hyeon;Ahn, Billy;Ray, Coronado;Kai, Liu;Hlaing, Ma Phoo Pwint;Park, Susan;Kim, Gwang
    • 마이크로전자및패키징학회지
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    • 제20권4호
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    • pp.47-52
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    • 2013
  • Gold wire has long been used as a proven method of connecting a silicon die to a substrate in wide variety of package types, delivering high yield and productivity. However, with the high price of gold, the semiconductor packaging industry has been implementing an alternate wire material. These materials may include silver (Ag) or copper (Cu) alloys as an alternative to save material cost and maintain electrical performance. This paper will analyze and compare the electrical characteristics of several wire types. For the study, typical 0.6 mil, 0.8 mil and 1.0 mil diameter wires were selected from various alloy types (2N gold, Palladium (Pd) coated/doped copper, 88% and 96% silver) as well as respective pure metallic wires for comparison. Each wire model was validated by comparing it to electromagnetic simulation results and measurement data. Measurements from the implemented test boards were done using a vector network analyzer (VNA) and probe station setup. The test board layout consisted of three parts: 1. Analysis of the diameter, length and material characteristic of each wire; 2. Comparison between a microstrip line and the wire to microstrip line transition; and 3. Analysis of the wire's cross-talk. These areas will be discussed in detail along with all the extracted results from each type the wire.