• Title/Summary/Keyword: MEAs

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Development of a Lightweight 200W Direct Methanol Fuel Cell Stack for UAV Applications and Study of its Operating Characteristics (II) (무인항공기용 200W 급 직접메탄올연료전지 경량화 스택 제작 및 작동 특성 연구 (II))

  • Kang, Kyung-Mun;Park, Sung-Hyun;Gwak, Geon-Hui;Ji, Hyun-Jin;Ju, Hyun-Chul
    • Journal of Hydrogen and New Energy
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    • v.23 no.3
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    • pp.243-249
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    • 2012
  • A lightweight 200W direct methanol fuel cell (DMFC) stack is designed and fabricated to power a small scale Unmanned Aerial Vehicle (UAV). The DMFC stack consists of 33-cells in which membrane-electrode assemblies (MEAs) having an active area of 88 $cm^2$ are sandwiched with lightweight composite bipolar plates. The total stack weight is around 3.485 kg and stack performance is tested under various methanol feed concentrations. The DMFC stack delivers a maximum power of 248 W at 13.2 V and $71.3^{\circ}C$ under methanol feed concentration of 1.2 M. In addition, the voltage of individual cell in the 33-cell stack is measured at various current levels to ensure the stability of DMFC stack operations. The cell voltage distribution data exhibit the maximum cell voltage deviation of 28 mV at 15 A and hence the uniformity of cell voltages is acceptable. These results clearly demonstrate that DMFC technology becomes a potential candidate for small-scale UAV applications.

Vaporization and Conversion of Ethanolamines used in Metalworking Operations

  • Kim, Shin-Bum;Yoon, Chung-Sik;Park, Dong-Uk
    • Safety and Health at Work
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    • v.1 no.2
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    • pp.175-182
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    • 2010
  • Objectives: This study examined how ethanolamines (EAs) with the same functional alcohol group ($HOCH_2CH_2$), such as mono-EA (MEA), di-EA (DEA), and tri-EA (TEA), in water-based metalworking fluids (wbMWFs) are vaporized, condensed, and transformed by heat generated during metalworking. Methods: Two types of experimental apparatus were manufactured to achieve these objectives. Results: Vaporization tests using a water bath showed that the vaporization rate increased markedly from $0.19\;mg/m^2{\cdot}min$ at $23.5^{\circ}C$ to $8.04\;mg/m^2{\cdot}min$ at $60^{\circ}C$. Chamber tests with a heat bulb revealed that "spiked" MEA was fully recovered, while only 13.32% of DEA and no TEA were recovered. Interestingly, non-spiked types of EAs were detected, indicating that heat could convert EAs with more alcohol groups (TEA or DEA) into other EAs with fewer group(s) (DEA or MEA). The EA composition in fresh fluid was 4% DEA, 66% TEA, and 30% MEA, and in used fluids (n = 5) was 12.4% DEA, 68% TEA, and 23% MEA. Conversion from TEA into DEA may therefore contribute to the DEA increment. Airborne TEA was not detected in 13 samples taken from the central coolant system and near a conveyor belt where no machining work was performed. The DEA concentration was $0.45\;mg/m^3$ in the only two samples from those locations. In contrast, airborne MEA was found in all samples (n = 53) regardless of the operation type. Conclusion: MEAs easily evaporated even when MWFs were applied, cleaned, refilled, and when they were in fluid storage tanks without any metalworking being performed. The conversion of TEA to DEA and MEA was found in the machining operations.

Optimum Ratio between Nafion and 20, 40 wt% Pt/C Catalysts for MEAs (20, 40 wt% Pt/C 촉매를 사용한 MEA제조에서 나피온의 최적비)

  • Jung, Ju-Hae;Jung, Dong-Won;Kim, Jun-Bom
    • Journal of the Korean Electrochemical Society
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    • v.14 no.1
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    • pp.50-55
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    • 2011
  • To enhance the performance of a MEA (membrane electrode assembly) in a polymer electrolyte membrane fuel cell (PEMFC), optimum contents of Nafion ionomer as electrolyte in the 20 and 40 wt% Pt/C used in electrodes were examined. Variety characterization techniques were applied to examine optimum Nafion contents: cell performance test, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). According to Pt wt% supported on carbon support, it has been observed that polarization, ohmic, and mass transfer resistances were changed so that the cell performance was significantly dependent on the content of Nafion ionomer. Optimum Nafion ionomer contents in the 20 wt% Pt/C and 40 wt% Pt/C were showed 35 wt% and 20 wt%, respectively. This is due to different surface area of the Pt/C catalyst, and formation of triple phase boundary seems to be affected by the Nafion contents.

Measurement of Organic Solvent from Painting Work Inside the Steel Box Girder of Bridge (교량 스틸박스거더 도장공사의 유기용제 측정 실험)

  • Lee, Jung-Woo;Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.134-142
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    • 2005
  • This study is to find out how organic solvent will be propagated from painting inside the steel box girder of bridge. $2.9m{\times}3.0m$ of inside size of steel box girder is not suitable for painters to do his work comfortably and hygienically. Substance density(ppm)inside the space of the box unsatisfactory hygienical condition. Most of organic solvent(mainly toluene) came down to 0.5m in two minutes and 53sec. But personal protection for painter should be properly kept against flying this heavy organic solvent. longitudinally 27.1m in length is a cell unit of the whole length of bridge. Model XP-3l6A made in Japan is a main instrumentation adjusted to sense organic solvent especially toluene which can be measured up to 10,000ppm. Scenario analysis by computer program, safer release 2.0 has been performed first to estimate how the organic solvent will be propagated. And then actual test was done as a model. This has been measured for approximately five(5) minutes, with 30 sec interval. Actual measurement results showed much higher $10{\sim}20%$ than result analyzed by the computer program, meaning that this painting work can give worse effect to the worker who is painting inside the box girder of the bridge. The first meas urement level over the floor set up at 30cm height from the floor, because organic solvent was estimated to stay at the level. and then, they were measured at 1.0m, 1.5m level respectively, more.

Prevalence and Associated Risk Factors of Toxocara vitulorum Infections in Buffalo and Cattle Calves in Three Provinces of Central Cambodia

  • Dorny, Pierre;Devleesschauwer, Brecht;Stoliaroff, Valerie;Sothy, Meas;Chea, Rortana;Chea, Bunthon;Sourloing, Hor;Samuth, Sum;Kong, Seth;Nguong, Koemseang;Sorn, San;Holl, Davun;Vercruysse, Jozef
    • Parasites, Hosts and Diseases
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    • v.53 no.2
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    • pp.197-200
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    • 2015
  • The prevalence and associated risk factors of Toxocara vitulorum infection in buffalo and cattle calves was studied in 3 provinces in central Cambodia. Fecal samples were collected from 517 calves between the age of 1-15 weeks and processed for nematode egg counts by a modified McMaster method. A total of 64 calves were found to excrete T. vitulorum eggs in their feces (12.4%; 95% exact CI: 9.7-15.5). The mean fecal egg count was 2,798 EPG (SD=16,351; range=0-224,400). A multivariable generalized linear mixed model showed higher odds of T. vitulorum infection for buffalo versus cattle, for animals aged 4-8 weeks versus younger and older ones, and for animals with strongyle infection. There was no association with fecal consistency. Farmers should be aware of the potential impact of T. vitulorum, and treat their calves at the age of 2-3 weeks with anthelmintics such as benzimidazoles or pyrantel.

The Effect of Neurofeedback Traing on the hearing impairments Student about Emotional (뉴로피드백 훈련이 청각장애 학생들의 정서적 성향에 미치는 영향)

  • Bak, Ki-Ja;Ahn, Sang-Kyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.9
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    • pp.3897-3903
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    • 2011
  • This study was to examine the effectiveness of neurofeedback training by observing the pre and post brainwave measurement results of about 39(experimental group 25, comparative group 14) student who have shown emotional. The study was examined at S city M dong A hearing impairments student, from Mar. 2009 and to Feb. 2010. The training took place two times a week, for about 40 minutes per session. The tool used to meas ure the psychological reaction was POMS (Profile of Mood State). First, the result confirmed the differences of both attention quotient(L R) and resistance stress quotient(L R). Second,, the results of the analysis show mood state. Therefore, the result of the study shows that there is possibility that NeuroFeedback technique might be positively affecting emotional of the hearing impairments student.

Prediction of Housing Price Index using Data Mining and Learning Techniques (데이터마이닝과 학습기법을 이용한 부동산가격지수 예측)

  • Lee, Jiyoung;Ryu, Jae Pil
    • Journal of the Korea Convergence Society
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    • v.12 no.8
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    • pp.47-53
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    • 2021
  • With increasing interest in the 4th industrial revolution, data-driven scientific methodologies have developed. However, there are limitations of data collection in the real estate field of research. In addition, as the public becomes more knowledgeable about the real estate market, the qualitative sentiment comes to play a bigger role in the real estate market. Therefore, we propose a method to collect quantitative data that reflects sentiment using text mining and k-means algorithms, rather than the existing source data, and to predict the direction of housing index through artificial neural network learning based on the collected data. Data from 2012 to 2019 is set as the training period and 2020 as the prediction period. It is expected that this study will contribute to the utilization of scientific methods such as artificial neural networks rather than the use of the classical methodology for real estate market participants in their decision making process.

A Review of Strategies to Improve the Stability of Carbon-supported PtNi Octahedral for Cathode Electrocatalysts in Polymer Electrolyte Membrane Fuel Cells

  • In Gyeom Kim;Sung Jong Yoo;Jin Young Kim;Hyun S. Park;So Young Lee;Bora Seo;Kwan-Young Lee;Jong Hyun Jang;Hee-Young Park
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.96-110
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    • 2024
  • Polymer electrolyte membrane fuel cells (PEMFCs) are green energy conversion devices, for which commercial markets have been established, owing to their application in fuel cell vehicles (FCVs). Development of cathode electrocatalysts, replacing commercial Pt/C, plays a crucial role in factors such as cost reduction, high performance, and durability in FCVs. PtNi octahedral catalysts are promising for oxygen reduction reactions owing to their significantly higher mass activity (10-15 times) than that of Pt/C; however, their application in membrane electrode assemblies (MEAs) is challenged by their low stability. To overcome this durability issue, various approaches, such as third-metal doping, composition control, halide treatment, formation of a Pt layer, annealing treatment, and size control, have been explored and have shown promising improvements in stability in rotating disk electrode (RDE) testing. In this review, we aimed to compare the features of each strategy in terms of enhancing stability by introducing a stability improvement factor for a direct and reasonable comparison. The limitations of each strategy for enhancing stability of PtNi octahedral are also described. This review can serve as a valuable guide for the development of strategies to enhance the durability of octahedral PtNi.

Numerical simulation and experimental study of non-stationary downburst outflow based on wall jet model

  • Yongli Zhong;Yichen Liu;Hua Zhang;Zhitao Yan;Xinpeng Liu;Jun Luo;Kaihong Bai;Feng Li
    • Wind and Structures
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    • v.38 no.2
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    • pp.129-146
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    • 2024
  • Aiming at the problem of non-stationary wind field simulation of downbursts, a non-stationary down-burst generation system was designed by adding a nozzle and program control valve to the inlet of the original wall jet model. The computational fluid dynamics (CFD) method was used to simulate the downburst. Firstly, the two-dimensional (2D) model was used to study the outflow situation, and the database of working conditions was formed. Then the combined superposition of working conditions was carried out to simulate the full-scale measured downburst. The three-dimensional (3D) large eddy simulation (LES) was used for further verification based on this superposition condition. Finally, the wind tunnel test is used to further verify. The results show that after the valve is opened, the wind ve-locity at low altitude increases rapidly, then stays stable, and the wind velocity at each point fluctuates. The velocity of the 2D model matches the wind velocity trend of the measured downburst well. The 3D model matches the measured downburst flow in terms of wind velocity and pulsation characteris-tics. The time-varying mean wind velocity of the wind tunnel test is in better agreement with the meas-ured time-varying mean wind velocity of the downburst. The power spectrum of fluctuating wind ve-locity at different vertical heights for the test condition also agrees well with the von Karman spectrum, and conforms to the "-5/3" law. The vertical profile of the maximum time-varying average wind veloci-ty obtained from the test shows the basic characteristics of the typical wind profile of the downburst. The effectiveness of the downburst generation system is verified.

A Study on Ensuring Biosafety of Biotechnology Product under Debate about Trade and the Environment (DDA 무역-환경 논의와 생명공학제품의 안전성 확보)

  • Sung, Bong-Suk;Yoon, Ki-Kwan
    • Environmental and Resource Economics Review
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    • v.13 no.3
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    • pp.519-547
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    • 2004
  • This paper analyze problems about scope of specific trade obligations(STOs), principle of dispute settlement procedure, and non-parties in context of the Cartagena Protocol on Biosafety(POB), which based on sub-paragraph 31(i) of DDA WTO Ministrial Declaration. The implications based on result of this study are as follows. First, to accept the wider scope of STOs under POB in Korea, importing country, won't be harmful to LMOs and Bioindustry. Instead, it will ensure a high level of biosafety concerning the import of LMOs. Exporters can take different kinds of trade measures to countervail adverse effect on the export of LMOs in this case. Therefore importer will endure the aftereffect. However, if korea were in exporter's place, to accept the wider scope STOs under POB will not have a good influence on the export of LMOs. Korea, therefore, should devise scheme for responding to debate about the STOs in MEAs, which have to be based on cost-benefit analysis and scenarios taking into account of speed and level in biotechology progress, status and trend of LMOs R&D and production, and condition of other industries. Second, it is not easy to agree with applying to what's rule between the POB and WTO for settlement dispute. Because there is the incompatibility between the POB characterized according to social rationality and WTO's rules for safety and environmental protection characterized according to scientific rationality. This issue have to be discussed for long period due to gap like that. Accordingly Korea, one of major LMOs importing countries, should suggest continuously that the effort is needed to ensure an adequate level of protection in transboundary movements of LMOs and scientific, environmental and socio-economic study. Third, in case of dispute between party and non-party of the POB, the duties under the WTO of non-party of the POB(if WTO member country) is valid. The country, therefore, will try to settle dispute based on WTO's rules. However, international society have to ensure for sound and safe use of LMOs in the field of transboundary movements. Accordingly Korea should devise scheme for preventing the possibility of dispute between party and non-party of the POB(if WTO member country), which is supported by policy options under the POB.

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