• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.33 no.3
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• pp.375-383
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• 2023

Objectives: Coal-fired power plants feature diverse working conditions, including multi-layered employment structures and irregular work cycles due to outsourcing and non-standardized tasks. The current uniform occupational environment measurement systems have limitations in accurately assessing and evaluating these varied conditions. This study aims to propose alternative measurement and assessment strategies to supplement existing methods. Methods: Major domestic coal-fired power plants were selected as the study targets. To prepare for the study and establish strategies, work processes were identified and existing occupational environment measurement results were compared and analyzed. The study proceeded by employing three strategies: specific exposure groups (SEGs) measurement, continuous monitoring, and supplementary measurements, which were then compared and discussed. Results: Previous exposure index evaluations (5,268 cases) indicated that crystalline silica, a type of respirable particulate matter, had detection limits below the threshold (non-detectable) in 82.6% (4,349 cases) of instances. Exposures below 10% of the exposure limit were observed at a very low concentration of 96.1%. Similar exposure group measurements yielded results where detection limits were below the threshold in 38.2% of cases, and exposures below 10% of the limit were observed in 70.6%. Continuous monitoring indicated detection limits below the threshold in 12.6% of cases, and exposures below 10% of the limit were observed in 75.6%. Instances requiring active workplace management accounted for more than 30% of cases, with SEGs at 11.8% (four cases), showing a higher proportion compared to 3.0% (four cases) in continuous monitoring. For coal dust, exposures below 10% of the limit were highest in legal measurements at 90.2% (113 cases), followed by 74.0% (91 cases) in continuous monitoring, and 47.0% (16 cases) in SEGs. Instances exceeding 30% were most prevalent in SEGs at 14.7% (five cases), followed by legal measurements at 5.0% (eight cases), and continuous monitoring at 2.4% (three cases). When examining exposure levels through arithmetic means, crystalline silica was found to be 104.7% higher in SEGs at 0.0088 mg/m³ compared to 0.0043 mg/m³ in continuous monitoring. Coal dust measurements were highest in SEGs at 0.1247 mg/m³, followed by 0.1224 mg/m³ in legal measurements, and 0.0935 mg/m³ in continuous monitoring. Conclusions: Strategies involving SEGs measurement and continuous monitoring can enhance measurement reliability in environments with irregular work processes and frequent fluctuations in working conditions, as observed in coal-fired power plants. These strategies reduce the likelihood of omitting or underestimating processes and enhance measurement accuracy. In particular, a significant reduction in detection limits below the threshold for crystalline silica was observed. Supplementary measurements can identify worker exposure characteristics, uncover potential risks in blind spots of management, and provide a complementary method for legal measurements.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.466-471
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• 2004

Efficient numerical finite element analysis of creeping concrete structures requires the use Kelvin or Maxwell chain model, which is most conveniently identified from a continuous retardation or relaxation spectrum, the spectrum in turn being determined from the given compliance or relaxation function. The method of doing that within the context of solidification theory for creep with aging was previously worked out by Bazant and Xi, but only for the case of a continuous retardation spectrum based on Kelvin chain. The present paper is motivated by the need to incorporate concrete creep into the recently published microplane model M4 for nonlinear triaxial behavior of concrete, including tensile fracturing and behavior under compression. In that context. the Maxwell chain is more effective than Kelvin chain. because of the kinematic constraint of the microplanes used in M4. Determination of the continuous relaxation spectrum for Maxwell chain. based on the solidification theory, is outlined and numerical examples are presented.

• Earthquakes and Structures
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• v.7 no.6
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• pp.895-908
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• 2014

The main objective of critical excitation methods is to reveal the worst possible response of structures. This goal is accomplished by considering the uncertainties of ground motion, which is subjected to the appropriate constraints, such as earthquake power and intensity limit. The concentration of this current study is on the theoretical optimization aspect, as is the case with the majority of conventional critical excitation methods. However, these previous studies on critical excitation lead to a discontinuous power spectral density (PSD). This paper introduces some critical excitations which contain proper continuity in frequency domain. The main idea for generating such continuous excitations stems from the combination of two continuous functions. On the other hand, in order to provide a non-stationary model, this paper attempts to present an appropriate envelope function, which unlike the previous envelope functions, can properly cover the natural earthquakes' accelerograms based on multi-peak conditions. Finally, the proposed method is developed into the multiple-degree-of-freedom (M.D.O.F) structures.

• Applied Chemistry
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• v.16 no.1
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• pp.25-28
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• 2012

A determination method of cyanide ion (CN^-) using nickel complexation reaction by continuous monitoring system. The mechanical parameters and chemical conditions of the complexation reaction were investigated prior to application of continuous monitoring system for determination of cyanide. On the optimized conditions, the calibration curve was linear over the range from 5.0×10^-6 to 1.0×10^-4 M. In this range, 2.40% of the reproducibility (RSD, n=3) was obtained. The limit of detection (3σ/s) was calculated to be 1.8×10^-6 M.

• BMB Reports
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• v.37 no.5
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• pp.629-633
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• 2004

NADPH-cytochrome P450 reductase (CPR) transfers electrons from NADPH to cytochrome P450, and catalyzes the one-electron reduction of many drugs and foreign compounds. Various forms of spectrophotometric titration have been performed to investigate the electron-accepting properties of CPR, particularly, to examine its ability to reduce cytochrome c and ferricyanide. In this study, the reduction of 1,1-diphenyl-2-picrylhydrazyl (DPPH) by CPR was assessed as a means of monitoring CPR activity. The principle advantage of DPPH is that its reduction can be assayed directly in the reaction medium by a continuous spectrophotometry. Thus, electrons released from NADPH by CPR were transferred to DPPH, and DPPH reduction was then followed spectrophotometrically by measuring $A_{520}$ reduction. Optimal assay concentrations of DPPH, CPR, potassium phosphate buffer, and NADPH were first established. DPPH reduction activity was found to depend upon the strength of the buffer used, which was optimal at 100 mM potassium phosphate and pH 7.6. The extinction coefficient of DPPH was $4.09\;mM^{-1}\;cm^{-1}$. DPPH reduction followed classical Michaelis-Menten kinetics ($K_m\;=\;28\;{\mu}M$, $K_{cat}\;=\;1690\;min^{-1}$). This method uses readily available materials, and has the additional advantages of being rapid and inexpensive.

• Journal of Microbiology and Biotechnology
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• v.29 no.9
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• pp.1453-1459
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• 2019

Zeaxanthin is an important pigment in the photo-protection mechanism of microalgae. However, zeaxanthin epoxidase, an enzyme involved in the accumulation and conversion of zeaxanthin, has not been extensively studied in microalgae. In this work, we report the expression pattern of zeaxanthin epoxidase in Dunaliella tertiolecta (DtZEP) at different light and diverse salinity conditions. To confirm the responsiveness to light conditions, the ZEP expression pattern was investigated in photoperiodic (16 h of light and 8 h of dark) and continuous (24 h of light and 0 h of dark) light conditions. mRNA expression levels in photoperiodic conditions fluctuated along with the light/dark cycle, whereas those in continuous light remained unchanged. In varying salinity conditions, the highest mRNA and protein levels were detected in cells cultured in 1.5 M NaCl, and ZEP expression levels in cells shifted from 0.6 M NaCl to 1.5 M NaCl increased gradually. These results show that mRNA expression of DtZEP responds rapidly to the light/dark cycle or increased salinity, whereas changes in protein synthesis do not occur within a short period. Taken together, we show that DtZEP gene expression responds rapidly to light irradiation and hyperosmotic stress. In addition, ZEP expression patterns in light or salinity conditions are similar to those of higher plants, even though the habitat of D. tertiolecta is different.

• Computers and Concrete
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• v.16 no.3
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• pp.357-380
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• 2015

In this study, a simple indeterminate strut-tie model which reflects complicated characteristics of the ultimate structural behavior of continuous reinforced concrete deep beams was proposed. In addition, the load distribution ratio, defined as the fraction of applied load transferred by a vertical tie of truss load transfer mechanism, was proposed to help structural designers perform the analysis and design of continuous reinforced concrete deep beams by using the strut-tie model approaches of current design codes. In the determination of the load distribution ratio, a concept of balanced shear reinforcement ratio requiring a simultaneous failure of inclined concrete strut and vertical steel tie was introduced to ensure the ductile shear failure of reinforced concrete deep beams, and the primary design variables including the shear span-to-effective depth ratio, flexural reinforcement ratio, and compressive strength of concrete were reflected upon. To verify the appropriateness of the present study, the ultimate strength of 58 continuous reinforced concrete deep beams tested to shear failure was evaluated by the ACI 318M-11's strut-tie model approach associated with the presented indeterminate strut-tie model and load distribution ratio. The ultimate strength of the continuous deep beams was also estimated by the experimental shear equations, conventional design codes that were based on experimental and theoretical shear strength models, and current strut-tie model design codes. The validity of the proposed strut-tie model and load distribution ratio was examined through the comparison of the strength analysis results classified according to the primary design variables. The present study associated with the indeterminate strut-tie model and load distribution ratio evaluated the ultimate strength of the continuous deep beams fairly well compared with those by other approaches. In addition, the present approach reflected the effects of the primary design variables on the ultimate strength of the continuous deep beams consistently and reasonably. The present study may provide an opportunity to help structural designers conduct the rational and practical strut-tie model design of continuous deep beams.

• Bulletin of the Korean Chemical Society
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• v.24 no.3
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• pp.291-294
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• 2003

A highly interferent-resistive membrane, poly-5-amino-1-naphthol (poly-5A1N), underlied beneath enzymeembedded poly-1,3-phenylendiamine (poly-m-PD) network for miniturized continuous monitoring glucose sensors. The enzyme layer was prepared from a mixed solution of glucose oxidase (GOx) and m-PD monomer by simple electrolysis. The mass change of poly-5A1N was monitored by electrochemical quartz crystal microbalance (EQCM) in situ and the corresponding thickness was measured. Successive electropolymerization of poly-5A1N and poly-m-PD create a several tens nm-thick bilayer showing excellent selectivity for $H_2O_2$ and low activity loss of immobilized enzymes.

• KSBB Journal
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• v.8 no.1
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• pp.42-48
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• 1993

Continuous degradation of formaldehyde by using a rotating disc contactor was investigated in this study. Peudomonas putida H-5K was selected as a mutant using N-methyl N'-nitro N-nitrosoguandine (250$\mu\textrm{g}$/$m\ell$), which showed 1.5 times higher ability of formaldehyde degradation than that of the parent strain. Enzyme activity for formaldehyde degradation released form Peudomonas putida H-5K showed the highest level of 6.2mo1/min/mg protein in the 2% glucose mineral medium containing 0.02% formaldehyde. Degradation of formaldehyde from the first stage in rotating disc contactor was 95% and 5% from the 4th stage when the reactor was fed with 0.02% or 0.04% formaldehyde solution at a rate of 20$m\ell$ per hour. Continuous degradation of formaldehyde using rotating disc contactor was above 95%o in the medium containing 0.04% formalchyde, at the medium feed ratc of 20$m\ell$ per hour.

• Journal of applied mathematics & informatics
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• v.41 no.3
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• pp.525-540
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• 2023

In this paper, we introduce the concept of fuzzy nano M open and fuzzy nano M closed mappings in fuzzy nano topological spaces. Also, we study about fuzzy nano M Homeomorphism, almost fuzzy nano M totally mappings, almost fuzzy nano M totally continuous mappings and super fuzzy nano M clopen continuous functions and their properties in fuzzy nano topological spaces. By using these mappings, we can able to extended the relation between normal spaces and regular spaces in fuzzy nano topological spaces.