• 한국재료학회:학술대회논문집
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• 한국재료학회 1994년도 추계 학술발표 강연 및 논문 개요집
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• pp.1-1
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• 1994

;The electronic state calculations for various types of ceramic materials have beell performed by the use of $DV-X\;{\alpha}$ cluster method. The molecular orbital levels and wave functions for model clusters have been computed to study the electronic properties ami chemical bonding of the ceramics. For ${\beta}-sialon(Si_{6-z}Al_zO_zN_{8-z})$ which is a high temperature structural material based on ${\beta}-Si_3N_4$, we have made model cluster calculations to estimate the strength of chemical bonding between atoms by the Mulliken population analysis. It is found that the covalent bonding between Si and N atoms is very strong in pure ${\beta}-Si_3N_4$, but the covalency around solute atom is considerably weakened when Si atom is substituted by AI. This tendency is enhanced by an additional substitution of oxygen atom for N. The result calculated can well explain the experimental data of changes in mechanical properties such as the reductions of Young's modulus and Vickers hardness with increment of z-value in ${\beta}-sialon$. Various model clusters for transition metal oxides which show many interesting physical and chemical properties have also been calculated. High-valent perovskite-type iron oxides EMFe0_3E(M=Ca and Sr) possess very interesting magnetic and chemical properties. In these oxides, iron exists as $Fe^{4+}$ state, but the experimental measurement of Mossba~er effect suggests that disproportionation $2Fe^{4+}=Fe^{3+}+Fe^{5+}$ takes place for $CaFe0_3$ at low temperatures. The model cluster calculations for these compounds indicated the existence of considerably strong covalent bonding of Fe-O. The calculations of hyperfine interaction at iron neucleus show very good agreement with the experimental Mossbauer measurements. The result calculated also implies that the disproportionation reaction is strongly possible by assuming the quenching of breathing phonon mode at low temperatures.tures.

• Journal of Oral Medicine and Pain
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• 제45권3호
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• pp.56-64
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• 2020

Purpose: Temporomandibular disorders (TMD) is a mosaic of clinical signs and symptoms that can be regarded as a set of phenotypes that are affected by various factors including pain sensitivity, pain disability, sleep and psychological functioning. The aims of this study were to evaluate association of pain experience, sleep quality and psychological distress with different phenotypes of TMD patients. Methods: This retrospective study included a cohort (n=1,858; 63.8% for female, mean age=34.9±15.9 years) of patients with TMD. A set of self-administered questionnaires concerning pain interference (Brief Pain Inventory), pain disability (Graded Chronic Pain Scale), sleep quality (Pittsburg Sleep Questionnaire Index), psychological distress (Symptom Checklist-90 revised), and pain catastrophizing (Pain Catastrophizing Scale) were administered to all participants at the first consultation. All TMD patients were classified into four groups including TMD with internal derangement without pain (TMD_ID, n=370), TMD with joint pain (TMD_J, n=571), TMD with muscle pain (TMD_M, n=541) and TMD with muscle-joint combined pain (TMD_MJ, n=376). Results: The female ratio was particularly high in the group with TMD_MJ (p=0.001). The patients with muscle pain and both muscle and joint pain had longer symptom duration (p=0.004) and presented significantly higher scores in pain experience (p<0.001), subjective sleep quality (p<0.001), pain catastrophizing (p<0.001) and psychological distress (p<0.05) except for paranoid-ideation than the groups with only joint problems. Conclusions: The results of this study highlight the importance of multi-dimensional approach that consider pain disability, sleep quality, and psychological functioning in the management of TMD with muscle component. This study would contribute to a better understanding of interaction between heterogeneous TMD and multiple risk factors in order to build tailored treatment based on different phenotypes.

• Journal of Magnetics
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• 제21권3호
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• pp.476-489
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• 2016

In the present study, squeezing flow of micropolar nanofluid between parallel infinite disks in the presence of magnetic field perpendicular to plane of the disks is taken into account. The constitutive equations that govern the flow configuration are converted into nonlinear ordinary differential with the help of suitable similarity transforms. HAM package BVPh2.0 has been employed to solve the nonlinear system of ordinary differential equations. Effects of different emerging parameters like micropolar parameter K, squeezed Reynolds number R, Hartmann number M, Brownian motion parameter Nb, thermophoresis parameter Nt, Lewis number Le for dimensionless velocities, temperature distribution and concentration profile are also discussed graphically. In the presence of strong and weak interaction (i.e. n = 0 and n = 0.5), numerical values of skin friction coefficient, wall stress coefficient, local Nusselt number and local Sherwood number are presented in tabulated form. To check the validity and reliability of the developed algorithm BVPh2.0 a numerical investigation is also a part of this study.

• 전기화학회지
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• 제14권2호
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• pp.83-91
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• 2011

Mesoporous titanium dioxide ($TiO_2$) thin films were prepared using poly(vinyl chloride)-graft-poly(N-vinyl pyrrolidone) (PVC-g-PVP) as a templating agent via sol-gel process. Grafting of PVC chains from PVC backbone was done by atom transfer radical polymerization (ATRP) technique. The successful grafting of PVP to synthesize PVC-g-PVP was checked by fourier-transform infrared spectroscopy (FT-IR) and gel permeation chromatography (GPC). The carbonyl group interaction of PVC-g-PVP graft copolymer with $TiO_2$ was confirmed by FT-IR. The porous morphologies of the $TiO_2$ films genereated after calcination at $450^{\circ}C$ was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The mesoporous $TiO_2$ films with 580 nm in thickness were used as a photoelectrode for solid state dye sensitized solar cell (DSSC) and showed an energy conversion efficiency of 1.05% at 100 $mW/cm^2$.

• Coupled systems mechanics
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• 제2권1호
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• pp.85-110
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• 2013

Generally, mass concrete structural behavior is governed by the strain components. However, relevant guidelines in dam engineering evaluate the structural behavior of concrete dams using stress-based criteria. In the present study, strain-based criteria are proposed for the first time in a professional manner and their applicability in seismic failure evaluation of an arch dam are investigated. Numerical model of the dam is provided using NSAD-DRI finite element code and the foundation is modeled to be massed using infinite elements at its far-end boundaries. The coupled dam-reservoir-foundation system is solved in Lagrangian-Eulerian domain using Newmark-${\beta}$ time integration method. Seismic performance of the dam is investigated using parameters such as the demand-capacity ratio, the cumulative inelastic duration and the extension of the overstressed/overstrained areas. Real crack profile of the dam based on the damage mechanics approach is compared with those obtained from stress-based and strain-based approaches. It is found that using stress-based criteria leads to conservative results for arch action while seismic safety evaluation using the proposed strain-based criteria leads to conservative cantilever action.

• Journal of Animal Science and Technology
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• 제62권1호
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• pp.74-83
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• 2020

Organic waste used as a feedstock in the anaerobic digestion (AD), it includes carbon and nitrogen. Carbon and nitrogen have an effect on the various digestive characteristics during AD, however, the study is rare about those of the interaction. This study investigates the influence of carbon type and carbon to nitrogens (C/N ratios) on the AD characteristics of organic waste. Experimental treatments involved a combination of three carbon types with three C/N ratios. The AD tests were carried out using a 125-mL serum bottle at a constant temperature of 37℃ and moisture 95% for 18 days. Degradation pattern shows the difference among three-carbon treatments, the starch group was faster than other groups. Maximum methane production date was similar between starch (9.96 ± 0.05 day) and xylan group (10.0 ± 0.52 day), those of the cellulose group (14.6 ± 1.80 day) was slower than other groups (p < 0.05). The lag phase was only affected by the carbon type (p < 0.05). Ammonia nitrogen was mainly affected by nitrogen concentration regardless of carbon type (p < 0.05). This study showed that xylan is useful as feedstock in order to decrease the lag phase, and it showed that ammonia was independently affected by the nitrogen concentration.

• Nuclear Engineering and Technology
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• 제45권7호
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• pp.859-870
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• 2013

The paper summarizes the irradiation test and post-irradiation examination (PIE) data for the U-Mo low-enriched fuel that was irradiated in the MIR reactor under the RERTR Program. The PIE data were analyzed for both full-size fuel rods and mini-rods with atomized powder dispersed in Al matrix as well as with additions of 2%, 5% and 13% of silicon in the matrix and ZrN protective coating on the fuel particles. The full-size fuel rods were irradiated up to an average burnup of ${\sim}60%^{235}U$; the mini-rods were irradiated to an average burnup of ${\sim}85%^{235}U$. The presented data show a significant increase of the void fraction in the U-Mo alloy as the U-235 burnup rises from ~ 40% up to ~ 85%. The effect of irradiation test conditions and U-235 burnup were analyzed with regard to the formation of an interaction layer between the matrix and fuel particles as well as generation of porosity in the U-Mo alloy. Shown here are changes in distribution of U fission products as the U-235 burnup increases from ~ 40% up to ~ 85%.

• Nuclear Engineering and Technology
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• 제50권6호
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• pp.944-949
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• 2018

The mass attenuation coefficients (${\mu}/{\rho}$) of food waste samples (pomegranate peel, acorn cap, lemon peel, mandarin peel, pumpkin peel, grape peel, orange peel, pineapple peel, acorn peel and grape stalk) have been measured employing a Si(Li) detector at 13.92, 17.75, 20.78, 26.34 and 59.54 keV. Also, the theoretical values of the mass attenuation coefficients have been evaluated utilizing mixture rule from WinXCOM program. The results showed that the lemon peel has the highest values of ${\mu}/{\rho}$ among the selected samples. From the obtained mass attenuation coefficients, we determined some absorption parameters such as effective atomic number ($Z_{eff}$), electron density ($N_E$) and molar extinction coefficient (${\varepsilon}$). It was found that the $Z_{eff}$ values of all food wastes lie within the range of 4.034-7.595, whereas the $N_E$ of the studied food wastes was found to be in the range of $0.301-1.720{\times}10^{25}$ (electrons/g) for present energy region.

• Structural Engineering and Mechanics
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• 제77권5호
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• pp.691-703
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• 2021

Reinforced concrete (RC) beams can be subjected to a complex combination of shear forces (V), torsional moments (T), flexural moments (M) and axial loads (N). This paper proposes a unified approach for the analysis of these elements. An existing model for the analysis of orthogonally reinforced concrete membrane elements subjected to in-plane shear and normal stresses is generalized to apply to the case of beams subjected to the complex loading. The combination of V and T can be critical. Torsion is modelled using the hollow-tube analogy. A direct equation for the calculation of the thickness of the equivalent hollow tube is proposed, and the shear stresses caused by V and T are combined using a simple approach. The development and the evaluation of the model are described. The calculations of the model are compared to experimental data from 350 beams subjected to various combinations of stress-resultants and to the calculations of the ACI and the CSA codes. The proposed model provides the most favorable results. It is also shown that it can accurately model the interaction between V and T. The proposed model provides a unified treatment of shear in beams subjected to complex stress-resultants and in thin membrane elements subjected to in-plane stresses.

• 한국정밀공학회지
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• 제24권3호
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• pp.140-146
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• 2007

To understand adhesive phenomena, we need to get force curve between two surfaces. And it is said that high stiffness force analysis system is needed to get precise force curve and more information of the surfaces. Usually the stiffness of the force measurement system is under the order of 10N/m. The stiffer force measurement system, however, results in more information on the surface, because higher stiffness lead to the wider range of force curves, secondly because the force curve obtained through the stiffer one describes more precise relationship between relative tip-sample separation and interaction force. In this paper, considering for stiffness and resolution, the cantilever was designed and we made adhesion force measurement apparatus with high stiffness and high resolution, so we measured adhesive force between Ag-ball and wafer.