• 제목/요약/키워드: Low-temperature corrosion

검색결과 326건 처리시간 0.024초

오일샌드 플랜트용 금속소재의 마모 특성에 대한 실험적 연구 (Experimental Study on Wear Characteristics of Metallic Materials used in Oil Sands Plants)

  • 원성재;조승현;강대경;허중식
    • Tribology and Lubricants
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    • 제33권1호
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    • pp.31-35
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    • 2017
  • Recently, international attention has been focused on the development of non-traditional energy resources such as shale gas and oil sands, due to the steep increase in the demand for natural resources. The materials incorporated in an oil gas plant module experience extreme environments, and are prone to various problem such as fracture, corrosion and abrasion due to low-temperature brittleness. In order to improve the plant life, it is necessary to perform characteristics study and performance evaluation of the materials. In particular, this paper explains the main set of materials which are most frequently used in oil sands plant project. In order to investigate wear characteristics, the authors carried out abrasive wear tests of TP 316, stainless steel and SS 400, structural rolled steel. For the analysis of the abrasive wear resistance of an oil sands plant, the authors carried out the test according to ASTM G 105 "Standard Test Method for Conducting Wet Sand/Rubber Wheel Abrasion Test" standard guidelines. The authors have derived the results from the data associated with the loss of mass with respect to wear rate. During the test, for a given wear length for 10,000 revolutions, the rotational speed and applied force of the rubber wheel were varied.

알루미늄 후판을 이용한 Moss Spherical 타입의 LNG탱크 곡면 성형해석 및 스프링백 예측 (Forming Analysis of A5083 Thick Plate for Moss Spherical LNG Tank and Prediction of Springback)

  • 윤종헌;전효원;이정환;김병민
    • 소성∙가공
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    • 제21권5호
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    • pp.305-311
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    • 2012
  • One of the main methods of building LNG tankers uses the Moss spherical tank design since it can be precisely analyzed with respect to reliability and safety of construction by stress analysis. Aluminum alloy 5083 is generally used in the Moss spherical tank design for the wall in constructing the LNG tanker. This aluminum alloy does not have low temperature brittleness, but has good corrosion resistance, good weldability, and excellent material properties for the application. The Moss spherical tank is constructed with several sections of A5083 thick plate with curved surfaces, which are welded together. It is essential to predict the amount of springback for the deformed thick plates in design to insure a reliable construction because the structure needs to be assembled into a perfect sphere. Unless the initial construction meets the design, there are additional processing costs for reworking to meet the specifications as well as a cost penalty paid to a consumer. In this paper, FE analyses were conducted to predict the amount of springback for various forming conditions and forming processes. The various forming processes were evaluated with respect to reducing springback and compared with the conventional forming process used for curved surfaces of thick Al plate.

나노 실리카분말의 충진효과를 이용한 극미세 3차원 세라믹 구조물 정밀화 (Improvement of precision of three-dimensional ceramic microstructures employing silica nanoparticle-mixed precursor)

  • 임태우;박상후;양동열;;김동표
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.157-158
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    • 2006
  • A novel nanofabrication process has been developed using two-photon crosslinking (TPC) for the fabrication of three-dimensional (3D) SiCN ceramic microstructures applicable to high functional 3D devices, which can be used in harsh working environments requiring a high temperature, a resistance to chemical corrosion, as well as tribological properties. After sequential processes: TPC and pyrolysis, 3D ceramic microstructures are obtained. However, large shrinkage due to low-ceramic yield during the pyrolysis is a serious problem to be solved in the precise fabrication of 3D ceramic microstructures. In this work, silica nanoparticles were employed as a filler to reduce the amount of shrinkage. In particular, the ceramic microstructures containing 40 wt% silica nanoparticles exhibited relatively isotropic shrinkage owing to its sliding free from the substrate during pyrolysis.

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EFFECTS OF IRRADIATION ON THERMAL CONDUCTIVITY OF ALLOY 690 AT LOW NEUTRON FLUENCE

  • Ryu, Woo Seog;Park, Dae Gyu;Song, Ung Sup;Park, Jin Seok;Ahn, Sang Bok
    • Nuclear Engineering and Technology
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    • 제45권2호
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    • pp.219-222
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    • 2013
  • Alloy 690 has been selected as a steam generator tubing material for SMART owing to a near immunity to primary water stress corrosion cracking. The steam generators of SMART are faced with a neutron flux due to the integrated arrangement inside a reactor vessel, and thus it is important to know the irradiation effects of the thermal conductivity of Alloy 690. Alloy 690 was irradiated at HANARO to fluences of (0.7-28) ${\times}10^{19}n/cm^2$ (E>0.1MeV) at $250^{\circ}C$, and its thermal conductivity was measured using the laser-flash equipment in the IMEF. The thermal conductivity of Alloy 690 was dependent on temperature, and it was a good fit to the Smith-Palmer equation, which modified the Wiedemann-Franz law. The irradiation at $250^{\circ}C$ did not degrade the thermal conductivity of Alloy 690, and even showed a small increase (1%) at fluences of (0.7~28) ${\times}10^{19}n/cm^2$ (E>0.1MeV).

분말형 자극제를 이용한 고로슬래그미분말 혼입 시멘트 모르타르의 조기 압축강도 향상에 관한 실험적 연구 (An Experimental Study on the Early Compressive Strength Improvement of Cement Mortar Mixed with Blast Furnace Slag using Powdered Stimulants)

  • 이강진;김진형;박기봉;이한승
    • KIEAE Journal
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    • 제12권3호
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    • pp.115-122
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    • 2012
  • Based on previous research and existing literature, this study examines the development of admixture, which increases the early concrete strength (1 and 3 day) by mixing blast furnace slag cement and concrete stimulant. The research on early strength development of concrete is necessary in dealing with the drawbacks of slow early strength concrete on site and to shorten the construction time. The study confirmed that when a high alkaline mortar mixture is mixed with blast furnace slag, the early strength of admixture exceeds that of ordinary portland cement (OPC). The use of calcium chloride ($CaCl_2$) promotes hydration of cement at low temperature and show similar strength as the blast furnace slag admixture. Although calcium chloride seems economically advantageous, it causes steel corrosion and its use in concrete should be further studied in-depth.

Improvement of Electrochemical Characteristics and Study of Deterioration of Aluminum Foil in Organic Electrolytes for EDLC

  • Lee, Mun-Soo;Kim, Donna H.;Kim, Seung-Cheon
    • Journal of Electrochemical Science and Technology
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    • 제9권1호
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    • pp.9-19
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    • 2018
  • The anodic behavior of aluminum (Al) foils with varying purity, capacitance, and withstand voltage in organic electrolytes was examined for EDLC. The results of cyclic voltammetry (CV) and chronoamperometry (CA) experiments showed that the electrochemical stability improves when Al foil has higher purity, lower capacitance, and higher withstand voltage. To improve the electrochemical stability of EDLC current collectors made of low-purity foil (99.4% Al foil), the foil was modified by chemical etching to reduce its capacitance to $60{\mu}F/cm^2$ and forming to have withstand a voltage of 3 Vf. EDLC cells using the modified Al foil as a current collector were made to 2.7 V with 360 F, and a constant voltage load test was subsequently performed for 2500 hours at high temperature under a rated voltage of 2.7 V. The reliability and stability of the EDLC cell improved when the modified Al foil was used as a current collector. To understand the deterioration process of the Al current collector, standard cells made of conventional Al foil under a constant voltage load test were disassembled, and the surface changes of the foil were measured every 500 hours. The Al foil became increasingly corroded, causing the adhesion between the AC coating layer and the Al foil to weaken, and it was confirmed that partial AC coating layer peeling occurred.

유도 결합 플라즈마 스퍼터 승화법을 이용한 고속증착 시스템 (High Rate Deposition System by Inductively Coupled Plasma Assisted Sputter-sublimation)

  • 최지성;주정훈
    • 한국표면공학회지
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    • 제45권2호
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    • pp.75-80
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    • 2012
  • A sputter-sublimation source was tested for high rate deposition of protective coating of PEMFC(polymer electrolyte membrane fuel cell) with high electrical conductivity and anti-corrosion capability by DC biasing of a metal rod immersed in inductively coupled plasma. A SUS(stainless steel) tube, rod were tested for low thermal conductivity materials and copper for high thermal conductivity ones. At 10 mTorr of Ar ICP(inductively coupled plasma) with 2.4 MHz, 300 W, the surface temperature of a SUS rod reached to $1,289^{\circ}C$ with a dc bias of 150 W (-706 V, 0.21 A) in 2 mins. For 10 min of sputter-sublimation, 0.1 gr of SUS rod was sputter-sublimated which is a good evidence of a high rate deposition source. ICP is used for sputter-sublimation of a target material, for substrate pre-treatment, film quality improvement by high energy particle bombardment and reactive deposition.

Buckling of axially loaded shell structures made of stainless steel

  • Ozer Zeybek;Ali Ihsan Celik;Yasin Onuralp Ozkilic
    • Steel and Composite Structures
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    • 제48권6호
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    • pp.681-691
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    • 2023
  • Stainless steels are commonly employed in engineering applications since they have superior properties such as low maintenance cost, and high temperature and corrosion resistance. These features allow them to be preferred in cylindrical shell structures as well. The behavior of a cylindrical shell structure made of stainless steel can be quite different from that made of carbon steel, as the material properties differ from each other. This paper deals with buckling behavior of axially loaded cylindrical shells made of stainless-steel. For this purpose, a combined experimental and numerical study was carried out. The experimental study comprised of testing of 18 cylindrical specimens. Following the experimental study, a numerical study was first conducted to validate test results. The comparisons show that finite element models provide good agreement with test results. Then, a numerical parametric study consisting of 450 models was performed to develop more generalized design recommendations for axially compressed cylindrical shell structures made of stainless steel. A simple formula was proposed for the practical design purposes. In other words, buckling strength curve equation is developed for three different fabrication quality.

페치니 공정을 이용한 몰리브덴-텅스텐 나노 분말 제조 및 소결 특성 평가 (Fabrication and Sintering Behavior Analysis of Molybdenum-tungsten Nanopowders by Pechini Process)

  • 김수연;권태현;김슬기;이동주
    • 한국분말재료학회지
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    • 제30권5호
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    • pp.436-441
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    • 2023
  • Molybdenum-tungsten (Mo-W) alloy sputtering targets are widely utilized in fields like electronics, nanotechnology, sensors, and as gate electrodes for TFT-LCDs, owing to their superior properties such as high-temperature stability, low thermal expansion coefficient, electrical conductivity, and corrosion resistance. To achieve optimal performance in application, these targets' purity, relative density, and grain size of these targets must becarefully controlled. We utilized nanopowders, prepared via the Pechini method, to obtain uniform and fine powders, then carried out spark plasma sintering (SPS) to densify these powders. Our studies revealed that the sintered compacts made from these nanopowders exhibited outstanding features, such as a high relative density of more than 99%, consistent grain size of 3.43 ㎛, and shape, absence of preferred orientation.

질소침투 열처리한 STS 410 및 410L 마르텐사이트계 스테인리스강의 템퍼링에 의한 조직변화 (Microstructural Changes during Tempering Treatment of Nitrogen-permeated STS 410 and 410L Martensitic Stainless Steels)

  • 이해정;공정현;이해우;유대경;강창룡;성장현
    • 열처리공학회지
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    • 제20권2호
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    • pp.84-93
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    • 2007
  • Microstructural changes during tempering at the temperature range of $300^{\circ}C{\sim}700^{\circ}C$ for the nitrogen-permeated STS 410 and 410L martensitic stainless steels has been investigated. After nitrogen permeation at temperature between 1050 and $1150^{\circ}C$, the surface layer appeared fine $Cr_2N$ of square and rod types in the martensite matrices. Hardness of the nitrogen-permeated surface layer represented 680Hv and 625Hv, respectively, for 410 and 410L steels. It is considered that the fine homogeneously dispersive effect of precipitates by nitrogen caused the increased hardness. Due to the counter current effect of carbon from interior to surface during nitrogen diffusion from surface to interior, the 0.1%C alloyed 410 steel showed the low nitrogen content of 0.025% compared with 0.045% of 410L steel at the distance of $100{\mu}m$ from the surface. Tempering of nitrogen-alloyed 410 and 410L showed the maximum hardness at $450^{\circ}C$. This maximum hardness was considered to be the secondary hardening effect of very fine carbide and nitride. The decrease in hardness at $700^{\circ}C$ was the softening effect of the matrix due to the precipitation of many needle-shaped $Cr_2N$ for 410 steel and the precipitation of coarse nitride of $Cr_2N$ in line with the spherical precipitates with directionality for 410L steel. For 410 steel, the corrosion resistance of nitrogen permeated surface in the solution of 1 N $H_2SO_4$ were nearly unchanged, however the superior corrosion resistance was obtained for nitrogen permeated 410L steel compared to the solution annealed condition.