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The Effect of an Aromatic Content on Exhaust Emissions in Low Temperature Diesel Combustion (저온 디젤 연소에서 연료의 방향족 성분이 배기가스에 미치는 영향)

  • Han, Man-Bae
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.3
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    • pp.106-112
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    • 2011
  • This study is to investigate the effect of an aromatic content in high cetane number (CN) fuels on exhaust emissions under low temperature diesel combustion, which expands the previous research about an aromatic content in low CN fuels. A 1.9L common rail direct injection diesel engine was run at 1500 rpm 2.6 bar BMEP with four fuel sets: an aromatic content of 20% (A20) or 45% (A45) with CN30, i.e. low CN fuels, and CN55, i.e. high CN fuels. Given experimental conditions, the trend of exhaust emissions in high CN fuels was inconsistent with that of low CN fuels which all produced nearly zero smoke but higher NOx for the high aromatic fuel (CN30-A45). For high CN fuels, however, the low aromatic fuel (CN55-A20) produced lower smoke than the high one (CN55-A45) while NOx was similar to each other. The cause of this discrepancy between high CN and low CN fuels is unclear whether it comes from that CN may be a dominant factor to govern exhaust emissions rather than an aromatic content or that the actual CN value of CN55-A45 is lower than CN55-A20. More decent fuel matrix should be prepared and further experiments are needed to confirm it.

Mitochondria-Targeted Vitamin E Protects Skin from UVB-Irradiation

  • Kim, Won-Serk;Kim, Ikyon;Kim, Wang-Kyun;Choi, Ju-Yeon;Kim, Doo Yeong;Moon, Sung-Guk;Min, Hyung-Keun;Song, Min-Kyu;Sung, Jong-Hyuk
    • Biomolecules & Therapeutics
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    • v.24 no.3
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    • pp.305-311
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    • 2016
  • Mitochondria-targeted vitamin E (MVE) is designed to accumulate within mitochondria and is applied to decrease mitochondrial oxidative damage. However, the protective effects of MVE in skin cells have not been identified. We investigated the protective effect of MVE against UVB in dermal fibroblasts and immortalized human keratinocyte cell line (HaCaT). In addition, we studied the wound-healing effect of MVE in animal models. We found that MVE increased the proliferation and survival of fibroblasts at low concentration (i.e., nM ranges). In addition, MVE increased collagen production and downregulated matrix metalloproteinase1. MVE also increased the proliferation and survival of HaCaT cells. UVB increased reactive oxygen species (ROS) production in fibroblasts and HaCaT cells, while MVE decreased ROS production at low concentration. In an animal experiment, MVE accelerated wound healing from laser-induced skin damage. These results collectively suggest that low dose MVE protects skin from UVB irradiation. Therefore, MVE can be developed as a cosmetic raw material.

Multiple Electron Beam Lithography for High Throughput (생산성 향상을 위한 멀티빔 리소그라피)

  • Choi, Sang-Kook;Yi, Cheon-Hee
    • Korean Journal of Optics and Photonics
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    • v.16 no.3
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    • pp.235-238
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    • 2005
  • A Multiple electron beam lithography system with arrayed microcolumns has been developed for high throughput applications. The small size of the microcolumn opens the possibility for arrayed operation on a scale commensurate. The arrayed microcolumns based on of Single Column Module (SCM) concept has been fabricated and successfully demonstrated. Low energy microcolumn lithography has been operated in the energy range from 250 eV to 300 eV for the generation of nano patterns. Probe beam current at the sample was measured about >1 nA at a total beam current of $0.5\;{\mu}A$ and a working distance of $\~1\;mm$. The magnitude of probe beam current is strong enough for the low energy lithography. The thin layers of PMMA resist have been employed. The results of nano-patterning by low energy microcolumn lithography will be discussed.

Electrical Properties of Low Density Polyethylene Film by Superstructure Change (고차구조 변화에 따른 저밀도폴리에틸렌 박막의 전기적 특성)

  • Shin, Jong-Yeol;Shin, Hyun-Taek;Lee, Soo-Won;Hong, Jin-Woong
    • Journal of the Korean Society of Safety
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    • v.17 no.4
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    • pp.101-109
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    • 2002
  • The electrical properties of polyethylene are changed by the superstructure. Such crystalline polymer as polyethylene or polypropylene changes crystallinity and products spherulite or trans-crystal when it is cooled slowly. In this study, after thermal treatment of LDPE at 100[${circ}C$], in silicone oil for an hour, we made specimens in order of slow cooling, water cooling, quenching according to cooling speed. Also, to study the influence of electrical properties due to the superstructure change, we analyzed physical properties and performed dielectric breakdown experiments using DC and impulse voltage Moreover we measured space charges in bulk using Laser Induced Pressure Pulse(LIPP) method. Trap level of specimen is 0.064[eV] at the low temperature region 0.31[eV] at the high temperature region in DC dielectric strength, 0.03[eV] at the low temperature region 0.0925[eV] at the high temperature region in impulse dielectric strength. As its result shows that the quantity of charges induced from the electrode surface increases with applied voltage time, and the distribution of space charges in samples increases the quantity of charges in proportion to applied voltage.

Electron-excitation Temperature with the Relative Optical-spectrumIntensity in an Atmospheric-pressure Ar-plasma Jet

  • Han, Gookhee;Cho, Guangsup
    • Applied Science and Convergence Technology
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    • v.26 no.6
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    • pp.201-207
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    • 2017
  • An electron-excited temperature ($T_{ex}$) is not determined by the Boltzmann plots only with the spectral data of $4p{\rightarrow}4s$ in an Ar-plasma jet operated with a low frequency of several tens of kHz and the low voltage of a few kV, while $T_{ex}$ can be obtained at least with the presence of a high energy-level transition ($5p{\rightarrow}4s$) in the high-voltage operation of 8 kV. The optical intensities of most spectra that are measured according to the voltage and the measuring position of the plasma column increase or decay exponentially at the same rate as that of the intensity variation; therefore, the excitation temperature is estimated by comparing the relative optical-intensity to that of a high voltage. In the low-voltage range of an Ar-jet operation, the electron-excitation temperature is estimated as being from 0.61 eV to 0.67 eV, and the corresponding radical density of the Ar-4p state is in the order of $10^{10}{\sim}10^{11}cm^{-3}$. The variation of the excitation temperature is almost linear in relation to the operation voltage and the position of the plasma plume, meaning that the variation rates of the electron-excitation temperature are 0.03 eV/kV for the voltage and 0.075 eV/cm along the plasma plume.

Effects of lead metal and annealing methods on low resistance contact formation of polycrystalline CdTe thin film (다결정 CdTe박막의 저저항 접축을 위한 배선금속 및 열처리방법의 효과에 관한 연구)

  • 김현수;이주훈;염근영
    • Electrical & Electronic Materials
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    • v.8 no.5
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    • pp.619-625
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    • 1995
  • Polycrystalline CdTe thin film has been studied for photovoltaic application due to the 1.45 eV band gap energy ideal for solar energy conversion and high absorption coefficient. The formation of low resistance contact to p-CdTe is difficult because of large work function(>5.5eV). Common methods for ohmic contact to p-CdTe are to form a p+ region under the contact by in-diffusion of contact material to reduce the barrier height and modify a p-CdTe surface layer using chemical treatment. In this study, the surface chemical treatment of p CdTe was carried out by H$\_$3/PO$\_$4/+HNO$\_$3/ or K$\_$2/Cr$\_$2/O$\_$7/+H$\_$2/SO$\_$4/ solution to provide a Te-rich surface. And various thin film contact materials such as Cu, Au, and Cu/Au were deposited by E-beam evaporation to form ohmic contact to p-CdTe. After the metallization, post annealing was performed by oven heat treatment at 150.deg. C or by RTA(Rapid Thermal Annealing) at 250-350.deg. C. Surface chemical treatments of p-CdTe thin film improved metal/p-CdTe interface properties and post heat treatment resulted in low contact resistivity to p-CdTe.Of the various contact metal, Cu/Au and Cu show low contact resistance after oven and RTA post-heat treatments, respectively.

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Enhanced Spectral Hole Substitution for Improving Speech Quality in Low Bit-Rate Audio Coding

  • Lee, Chang-Heon;Kang, Hong-Goo
    • The Journal of the Acoustical Society of Korea
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    • v.29 no.3E
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    • pp.131-139
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    • 2010
  • This paper proposes a novel spectral hole substitution technique for low bit-rate audio coding. The spectral holes frequently occurring in relatively weak energy bands due to zero bit quantization result in severe quality degradation, especially for harmonic signals such as speech vowels. The enhanced aacPlus (EAAC) audio codec artificially adjusts the minimum signal-to-mask ratio (SMR) to reduce the number of spectral holes, but it still produces noisy sound. The proposed method selectively predicts the spectral shapes of hole bands using either intra-band correlation, i.e. harmonically related coefficients nearby or inter-band correlation, i.e. previous frames. For the bands that have low prediction gain, only the energy term is quantized and spectral shapes are replaced by pseudo random values in the decoding stage. To minimize perceptual distortion caused by spectral mismatching, the criterion of the just noticeable level difference (JNLD) and spectral similarity between original and predicted shapes are adopted for quantizing the energy term. Simulation results show that the proposed method implemented into the EAAC baseline coder significantly improves speech quality at low bit-rates while keeping equivalent quality for mixed and music contents.

Corrosion Inhibition Studies on Low Carbon Steel in Hydrochloric Acid Medium Using o-Vanillin-Glutamine Schiff Base

  • Thusnavis, G. Rexin;Archana, T.V.;Palanisamy, P.
    • Corrosion Science and Technology
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    • v.21 no.1
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    • pp.32-40
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    • 2022
  • The o-Vanillin - Glutamine Schiff base [2-Hydroxy-3-Methoxy BenzylidineCarbomyl) -2-Butanoic Acid] was examined for low carbon steel corrosion inhibition in acid media. Weight loss studies were carried out at three different temperatures to determine the inhibition efficiency (IE). Electrochemical impedance spectroscopy revealed that the charge transfer resistance controlled the corrosion reaction and Tafel polarization indicated that the Schiff base acts as mixed mode of inhibitor. SEM images were recorded for the surface morphology of the low carbon steel surface. DFT studies revealed corrosion control mechanisms using quantum chemical parameters such as EHOMO, ELUMO, energy gap (∆E), chemical Hardness (η), chemical Softness (σ), Electronegativity (χ), and the fraction of electron transferred (∆N), which is calculated using Gaussian software 09. The gas-phase geometry was fully optimized in the Density Functional Theory (DFT/B3LYP-6-31G (d)).The DFT results are in good agreement with the experimental results. All the results proved that the Schiff Base (2-Hydroxy-3-Metoxy BenzylidineCarbomyl) -2-Butanoic is a suitable alternative for corrosion inhibition of low carbon steel in acid media.

Analysis on the concept design of the nuclear waste disposal site in foreign country (해외 방사성 폐기물 처분장 개념 설계 분석)

  • Seo, Kyoung-Won;Kim, Woong-Ku;Baek, Ki-Hyun;Jun, Seong-Keun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.791-800
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    • 2010
  • This paper presents the construction status and the conceptual designs of midium and high level radioactive waste disposal facilities from all around world. For the midium radioactive waste, a shallow disposal using trench or a deep depth disposal are adopted. However, these are rather focusing on the social and cultural point of view than the technical. Meanwhile, the high level radioactive waste is basically disposed in the deep underground. The corresponding ground conditions are usually dense and composed of sedimentary and crystalline rocks mainly with low permeability. A barrier system is made of canister which consists of copper, titanium, and tin. The inner and outer side of the canister are composed of different materials respectively.

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Contact Stress of Slewing Ring Bearing with External Pinwheel Gear Set (핀 휠을 구비한 외륜형 선회베어링의 면압강도)

  • Kwon, Soon-man
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.2
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    • pp.231-237
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    • 2015
  • The pin-gear drive is a special form of fixed-axle gear mechanism. A large wheel with cylindrical pin teeth is called a pinwheel. As pinwheels are rounded, they have a simple structure, easy processing, low cost, and easy overhaul compared with general gears. They are also suitable for low-speed, heavy-duty mechanical transmission and for occasions with more dust, poor lubrication, etc. This paper introduces a novel slewing ring bearing with an external pinwheel gear set (e-PGS). First, we consider the exact cam pinion profile of the e-PGS with the introduction of a profile shift. Then, the contact stresses are investigated to determine the characteristics of the surface fatigue by varying the shape design parameters. The results show that the contact stresses of the e-PGS can be lowered significantly by increasing the profile shift coefficient.