• Title/Summary/Keyword: Low-dye

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Photocatalytic Oxidation for Organic Dye using Phenol Resin-based Carbon-titania Composites

  • Oh, Won-Chun;Na, Yu-Ri
    • Journal of the Korean Ceramic Society
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    • v.45 no.1
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    • pp.36-42
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    • 2008
  • Carbon/$TiO_2$ composite photocatalysts were thermally synthesized with different mixing ratios of anatase to phenol resin through an ethanol solvent dissolving method. The XRD patterns revealed that only anatase phase can be identified for Carbon/$TiO_2$ composites. The diffraction peaks of carbon were not observed, however, due to the low carbon content on the $TiO_2$ surfaces and the low crystallinity of amorphous carbon. The results of chemical elemental analyses of the Carbon/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for carbon and Ti metal than that of any other elements. The BET surface area increases to the maximum value of $488\;m^2/g$ with the area depending on the amount of phenol resin. From the SEM images, small $TiO_2$ particles were homogeneously distributed to a composite cluster with the porosity of phenol resin-based carbon. From the photocatalytic results, the MB degradation should be attributed to the three kinds of synergetic effects, such as photocatalysis, adsorptivity, and electron transfer by light absorption between supporter $TiO_2$ and carbon.

Kinetic Study on the Low-lying Excited States of Ga Atoms in Ar

  • Kuntack Lee;Ju Seon Goo;Ja Kang Ku
    • Bulletin of the Korean Chemical Society
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    • v.15 no.8
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    • pp.663-669
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    • 1994
  • Decay kinetics of Ga(5s), Ga(5p) and Ga(4d) atoms in Ar were studied by laser induced fluorescence technique. Theground state gallium atoms in the gas phase were generated by pulsed dc discharge of trimethyl gallium and argon mixtures. Both pulsed discharge and YAG-DYE laser system were controlled by a dual channel pulse generator and the delay time between the end of discharge and laser pulses was set 3.0-6.0 ms. The Ga(5s) and Ga(4d) atoms were generated by single photon excitation from the ground state Ga atoms and radiative lifetimes as well as the total quenching rate constants in Ar were obtained from the pressure dependence of the fluorescence decay rates. The Ga(5p) atoms were populated by a two-photon excitation method and the cascade fluorescence from Ga(5s) atoms were analyzed to extract quenching rate constant of Ga(5p) atoms by Ar in addition to radiative lifetimes of Ga(5p) state. The magnitudes of the quenching rate constants by Ar for the low-lying excited states of Ga atoms are 1.6-3$ {\times}10^{-11}cm^3$ molecul$e^{-1}s^{-1}$, which are much larger than those for alkali, alkaline earth and Group 12 metals. Based on the measured rate constants, kinetic simulations were done to assign state-to-state rate constants.

Validation and measurement uncertainty of HPLC method for simultaneous determination of 10 dyes in adulterated Phellodendron

  • Lim, Suji;Yun, Choong-In;Ko, Kyung Yuk;Kim, Young-Jun
    • Korean Journal of Food Science and Technology
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    • v.53 no.4
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    • pp.391-398
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    • 2021
  • As global interest in herbal medicines has increased, the adulteration of herbal medicines has become a critical safety issue. Adulteration with dyes to improve the appearance of low-quality products is of particular concern. This study aimed to develop a high-performance liquid chromatography (HPLC) method to detect dyes added as adulterants to Phellodendron. Samples were analyzed on a C18 column using 50 mM ammonium acetate and acetonitrile as the mobile phase. All calibration curves showed good linearity (r2 ≥0.9999) over the five-point concentration range (1-50 mg/kg). Limit of detection ranged from 0.04-0.35 mg/kg, and limit of quantification ranged from 0.11-1.07 mg/kg. The repeatability and reproducibility for these measurements were 94.2-103.3% and 96.6-103.8% for accuracy and 0.14-2.28 RSD (%) and 0.80-2.37 RSD (%) for precision. Moreover, the measurement uncertainty of the low, medium, and high concentrations for 10 dyes was considered. Thus, this HPLC method is suitable for detecting color adulteration of Phellodendron.

A Study on the Application Method of Look-up Table to Color Proofing Systems (컬러교정인쇄에 대한 룩업테이블의 적용방법에 관한 연구)

  • 송경철;강상훈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.35-45
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    • 2000
  • Recently, as the prepress mainstream is changed to the digital workflow, various digital proofing systems such as high price dye sublimation printers and low price ink jet printers are widely used in printing industry. However, most of the digital proofing devices have lower resolution than analog proofing systems and differ with actual color presses in the color gamuts. Therefore, proper color compensations are needed for digital color proofing in order to match colors between the proofs and the press sheets. This study shows the application method of Look-up Table to the digital color proofer of Rainbow, the analog proofer of Matchprint-II, and an actual offset press is effective on the color compensations.

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Some of the Food Color Additives Are Potent Inhibitors of Human Protein Tyrosine Phosphatases

  • Shrestha, Suja;Bhattarai, Bharat Raj;Lee, Keun-Hyeung;Cho, Hyeong-Jin
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1567-1571
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    • 2006
  • Synthetic color additives approved for general food use are sixteen in European Union, seven in U. S. A. and twelve in Japan. Twelve food dyes were examined for their inhibitory potency against human protein tyrosine phosphatases (PTPases). Half of the food colorants inhibited PTPases significantly and three of them were potent inhibitors with low micromolar IC50 values. Also examined were the synthetic dyes structurally similar but not allowed in food. Some of them were potent inhibitors of PTPases. Considering the importance of PTPases in cellular signal transduction, inhibition of PTPases by food colorants might cause harmful effects in human health.

Fuzzy Inference based Digital Color Management of Textile Dye Manufacturing (퍼지 추론에 기반 한 직물 염료 생산공정의 디지털 색상관리)

  • Kyungwon Jang;Jinhyun Kang;Jaemyoung Hwang;Taechon Ahn
    • Proceedings of the IEEK Conference
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    • 2003.07d
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    • pp.1533-1536
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    • 2003
  • In this paper, instead of conventional color management method that using spectrum analysis, a simplified color management scheme is proposed that is low-cost required method to reproduce the visual color perception of human. Proposed scheme uses computer color scanner to obtain a bit map image from dyed original color sample, and conducts pixel analysis by image histogram. From obtained image histogram, extract the color and RGB value from histogram that shows dominant pixel distribution of the sample image.

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Fixation of Reactive Dyes on Ink-jet Dyeing

  • Urakawa, Hiroshi;Tamura, Kyoko;Yasukawa, Ryoko;Ueda, Mitsuo;Kajiwara, Kanji
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.31-32
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    • 2003
  • The fixation of reactive dyes onto cotton fabrics by means of dry heat treatment was examined in terms of water regain in fabrics. Dye liquors were applied to fabrics by ink-jet printer. The fixation strongly depended on water regain. At certain level of water regain the fixation showed stepwise increase. After this point the fixation reached to saturated value. The observed results were interpreted by the aggregation behavior of dyes and reactivity of hydroxyl group of cellulose depending on the amount of the surrounding water molecules. Urea molecules played a role of water at low water regain to increase the fixation.

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Surface Temperature Measurements in Microscale with Temperature Sensitive Fluorescence (온도 민감 형광을 이용한 마이크로 스케일 표면온도 측정)

  • Jung, Woon-Seop;Kim, Sung-Wook;Kim, Ho-Young;Yoo, Jung-Yul
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1225-1230
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    • 2004
  • The effects of substrate material on the local heating performance of microheaters are studied by both numerical analysis and experiment. Transient conduction analysis shows that the substrate material with low thermal conductivity is critical to the local heating and fast response. A measurement technique for surface temperature field in microscale is newly proposed, which uses temperature sensitive fluorescent dye coated on the surface. The measured surface temperature fields on microheater arrays fabricated on different substrates are presented.

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A study on the development of DC-DC converter to drive small instruments using DSC (DSC를 이용한 소형기기 구동의 DC-DC Converter 개발에 관한 연구)

  • Kim Jeonghoon;Park Sungjoon;Kim Jinyoung;Park Haeyoung;You Dongwook;Kim Heeje
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.201-204
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    • 2005
  • In this research, we have studied the development of dc-dc converter suitable for the driving of mobile instruments by using a dye-sensitized solar cell(DSC). We also have designed a interlocking circuit. The circuit makes power from DSC be saved in one battery and concurrently be discharged in the other battery. As this application, mobile devices like MP3, cellular phone are drived by using power from DSC during the daytime and they can be drived by using the saving energy of the daytime during the night. Besides, we designed dc-dc converter circuit to drive low power instruments by using NMOS switch and PMOS rectifier.

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Coloration of Pure Polypropylene Fiber with Super Hydrophobic Dyes; Application of Anthraquinone Derivatives with linear Alkyl Substituents

  • Kim, Tae-Kyeong;Yoon, Seok-Han;Hong, Jin-Pyo;Kim, Hong-Je;Bae, Jin-Seok
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.30-34
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    • 2006
  • Polypropylene fiber was dyed with 4 super hydrophobic dyes having different alkyl derivatives on the same chromophore. Double-tailed cationic surfactant, didodecyldimethylammonium bromide(DDAB), was used to make dye-dispersant complex to improve the dispersion of dyes. As the alkyl groups are longer and the hydrophobicity is increased, the dyeability onto polypropylene fiber was improved and deep coloration was obtained. As for the fastness properties, wash fastness was relatively good, while light fastness was bit low.