• 한국연소학회지
• /
• 제8권1호
• /
• pp.17-24
• /
• 2003

The conventional regenerative system has a high thermal efficiency as well as energy saving using the high preheated combustion air. in spite of these advantages, it can not avoid high nitric oxide emissions. Recently, flameless combustion has received much attention to solve these problems. In this research, numerical analysis is performed for flow-combustion phenomena in the self regenerative burner. In this analysis we used Fluent 6.0 code. the that is developed for commercial use, Methane gas is used as a fuel and two-step reaction model for methane and Zeldovich mechanism for NO generation are used. the velocity of the preheated combustion air is used as a parameter and we analyze the characteristics of flow-field, temperature distributions and NO emissions. Due to the increased recirculation rate, the maximum temperature of flame is significantly increased and NOx emissions is reduced.

• 통합자연과학논문집
• /
• 제3권3호
• /
• pp.157-161
• /
• 2010

New low temperature synthesis of germanium nanoparticles obtained from the reaction of germanium tetrachloride and sodium/benzophenonewere developed. These germanium nanoparticles terminated with chloride group were oxidized in air to give hydroxy-terminated germanium nanoparticles. Germanium nanoparticle containing 20(S)-camptothecin (CPT) for a noble drug delivery system were developed. FT-IR spectroscopy was used for the characterization of vibrational absorption for the germanium nanoparticle and oxidized germanium nanoparticles containing camptothecin. Electronic absorption and fluorescence properties were measured with UV-Vis and fluorescence spectrometer. The morphology of oxidized germanium nanoparticles containing camptothecin was investigated by using TEM.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
• /
• pp.97-104
• /
• 2002

The conventional regenerative system has a high thermal efficiency as well as energy saving using the high preheated combustion air. in spite of these advantages, it can not avoid high nitric oxide emissions. Recently, flameless combustion has received much attention to solve these problems. In this research, numerical analysis is performed for flow-combustion phenomena in the self regenerative burner. In this analysis we used Fluent 6.0 code. the that is developed for commercial use, Methane gas is used as a fuel and two-step reaction model for methane and Zeldovich mechanism for NO generation are used. the velocity of the preheated combustion air is used as a parameter and we analyze the characteristics of flow-field, temperature distributions and NO emissions. Due to the increased recirculation rate, the maximum temperature of flame is significantly increased and NOx emissions is reduced

• 공업화학
• /
• 제19권2호
• /
• pp.236-241
• /
• 2008

자외선 조사에 따른 광촉매 $TiO_2$의 표면에서 발생하는 활성산소종의 기상확산을 이용하여 실리콘기판 위에 산화박막을 성장시켰다. 자외선의 세기, 기판의 온도와 반응기 내의 산소 압력을 공정변수로 한 결과, 일정두께의 실리콘 산화박막의 성장이 자외선의 세기가 증가할수록 빨랐으며, 자외선램프의 세기를 60 W BLB 램프에서 1 kW 고압수은 랩프로 변경할 경우 성장속도가 8배 정도 빨라졌다. 반응기 내의 압력이 증가할수록 실리콘 산화박막의 성장속도는 느렸다. 대부분 산화박막의 성장은 $20{\AA}$에서 포화되었으며, 자외선의 세기가 증가할수록 포화상태까지 도달시간이 빨라졌다. 성장된 산화박막을 열처리를 통하여 전형적인 열산화막의 물성에 도달할 수 있었다. 광활성 산소종의 기상확산은 실리콘 산화박막의 저온 형성에 대한 광촉매 활용이라는 새로운 산화공정 방법으로 사용이 가능함을 확인할 수 있었다.

• Tribology and Lubricants
• /
• 제30권6호
• /
• pp.330-336
• /
• 2014

Sintered metallic brake pads and low alloy heat resistance steel disks are applied to mechanical brake systems in high energy moving machines that are associated with recently developed 200km/h trains. This has led to the speed-up of conventional urban rapid transit. In this study, we use a lab-scale dynamometer to investigate the effects of the composition of friction materials on the tribological characteristics of sintered metallic brake pads and low alloy heat resistance steel under dry sliding conditions. We conduct test under a continuous pressure of 5.5 MPa at various speeds. To determine the optimal composition of friction materials for 200 km/h train, we test and the evaluate frictional characteristics such as friction coefficients, friction stability, wear rate, and the temperature of friction material, which depend on the relative composition of the Cu-Sn and Fe components. The results clearly demonstrate that the average friction coefficient is lower for all speed conditions, when a large quantity of iron power is added. The specimen of 25 wt% iron powder that was added decreased the wear of the friction materials and the roughness of the disc surface. However when 35 wt% iron powder was added, the disc roughness and the wear rate of friction materials increased By increasing the amount of iron powder, the surface roughness, and temperature of the friction materials increased, so the average friction coefficients decreased. An oxidation layer of $Fe_2O_3$ was formed on both friction surfaces.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2009년 추계학술발표대회
• /
• pp.217-220
• /
• 2009

Conductive adhesives have been investigated for use in microelectronics packaging as a lead-free solder substitute due to their advantages, such as low bonding temperature. However, high resistivity and poor mechanical behavior may be the limiting factors for the development of conductive adhesives. The metal fillers and the polymer resins provide electrical and mechanical interconnections between surface mount device components and a substrate. As metal fillers used in conductive adhesives, silver is the most commonly used due to its high conductivity and the stability. However the cost of conductive adhesives with silver fillers is much higher than usual lead-free solders and silver has poor electro-migration performance. So, copper can be a promising candidate for conductive filler metal due to its low resistivity and low cost, but oxidation causes this metal to lose its conductivity. In this study, electrically conductive adhesives (ECAs) using surface modified copper fillers were developed. Especially, in order to overcome the problem associated with the oxidation of copper, copper particles were coated with silver, and the silver-coated copper was tested as a filler metal. Especially the effect of silver coating on the electrical resistance just after curing and after aging was investigated. As a result, it was found that the electrical resistance of ECA with silver-coated copper filler was clearly lower and more stable than that of ECA with pure copper filler after curing process. And, during high temperature storage test, the degradation rate of electrical resistance for ECA with silver coated copper filler was quite slower than that for ECA with pure copper filler.

• 한국세라믹학회지
• /
• 제48권1호
• /
• pp.57-62
• /
• 2011

The T23 steel, whose composition was Fe-2.3%Cr-1.6%W, was arc-melted, and oxidized between $600^{\circ}C$ and $900^{\circ}C$ in air for up to 7 months. The amount of precipitates in the arc-melted microstructure was as large as 11.4 vol.%. The precipitates increased the oxidation rate of the arc-melted T23 steel. Owing to the low amount of Cr in the T23 steel, breakaway oxidation occurred after a few hours during oxidation above $700^{\circ}C$ in both arc-melted and as-received T23 steels. The scales that formed on arc-melted and as-received T23 steels were similar to each other. They consisted primarily of the outer $Fe_2O_3$ layer and the inner ($Fe_2O_3$, $FeCr_2O_4$)-mixed layer. The precipitates increased the microhardness and the oxidation rates.

• Progress in Superconductivity
• /
• 제7권1호
• /
• pp.58-63
• /
• 2005

We investigated the surface oxidation behavior of cube-textured polycrystalline nickel at various oxidation conditions. Cube-textured NiO film was formed on a cube-textured polycrystalline nickel regardless of oxidation conditions but different growth behavior of NiO crystals was observed depending on the oxidation conditions. The introduction of water vapor into $O_2$ did not affect the texture evolution, but rough and porous microstructure was developed. Microstructure of NiO film tends to be denser as the oxygen partial pressure increases. It is interesting that (111) peak of theta - two theta diffraction pattern started to get stronger in air atmosphere and (111) plane became the major texture in the substrate oxidized in high purity argon gas. Small amount of high index crystallographic plane NiO peak crystal was observed when $N_{2}O$ was used as an oxidant while only (200) plane crystal was formed in dry $O_2$ atmosphere. Flat and smooth surface was changed into rough faceted one when ramping rate to oxidation temperature was faster. The grain size of NiO was decreased when the oxygen partial pressure was low. It was also observed that the modification of nickel surface suppressed the development of (200) texture.

• 한국표면공학회지
• /
• 제35권6호
• /
• pp.415-421
• /
• 2002

Ti-Si-N coating layers were codeposited on silicon wafer substrates by a DC reactive magnetron sputtering technique using separate titanium and silicon targets in $N_2$/Ar gas mixtures. The oxidation behavior of Ti-Si-N coating layers containing 4.0 at.%, 10.0 at.%, and 27.3 at.% Si was investigated at temperatures ranging from 600 to $960^{\circ}C$. The coating layers containing 4.0 at.% Si became fast oxidized from $600^{\circ}C$ while the coating layers containing 10.0 at.% Si had oxidation resistance up to $800^{\circ}C$. It was concluded that an increase in Si content to a level of 10.0 at.% led to the formation of finer TiN grains and a uniformly distributed amorphous Si3N4 phase along grain boundaries, which acted as efficient diffusion barriers against oxidation. However, the coating layers containing 27.3 at.% Si showed relatively low oxidation resistance compared with those containing 10.0 at.% Si. This phenomenon would be explained by the existence of free Si which was not nitrified in the coating layers containing 27.3 at.% Si.

• Korean Chemical Engineering Research
• /
• 제51권4호
• /
• pp.432-437
• /
• 2013

고분자 전해질 연료전지 구동 시 양극 활성 물질에 대한 CO 피독을 방지하기 위해 Cu를 촉매 활성 종으로 사용하고 반응물의 확산이 용이한 몇 가지 메조 세공 물질을 지지체로 이용하여 CO 선택적 산화 반응(PROX반응)을 실시하였다. 그 결과 거대 세공을 가진 SBA-15를 지지체로 사용했을 때 우수한 CO 산화 활성을 보였으며 특히 Cu 담지 량에 비례하여 활성은 증가하였다. 또한 Cu의 분산도를 높이고자 첨가한 Ti 성분은 저온에서 CO 산화 성능을 높이는데 기여하였다. 특히 Ti 성분을 20 wt-% 첨가한 Cu/Ti20-SBA-15 촉매에서 Cu의 분산도가 가장 우수하였으며 CO 산화활성 역시 개선됨을 확인하였다.