DOI QR코드

DOI QR Code

New Low Temperature Sol-gel Synthesis of Germanium Nanoparticles and Their Optical Characteristics

게르마늄 나노입자의 새로운 저온 졸-겔 합성방법의 개발과 광학적 특성

  • Received : 2010.09.02
  • Accepted : 2010.09.27
  • Published : 2010.09.30

Abstract

New low temperature synthesis of germanium nanoparticles obtained from the reaction of germanium tetrachloride and sodium/benzophenonewere developed. These germanium nanoparticles terminated with chloride group were oxidized in air to give hydroxy-terminated germanium nanoparticles. Germanium nanoparticle containing 20(S)-camptothecin (CPT) for a noble drug delivery system were developed. FT-IR spectroscopy was used for the characterization of vibrational absorption for the germanium nanoparticle and oxidized germanium nanoparticles containing camptothecin. Electronic absorption and fluorescence properties were measured with UV-Vis and fluorescence spectrometer. The morphology of oxidized germanium nanoparticles containing camptothecin was investigated by using TEM.

Keywords

References

  1. A. P. Alivisatos, "Semiconductor clusters, nanocrystals, and quantum dots", Science, Vol. 271, p. 933, 1996. https://doi.org/10.1126/science.271.5251.933
  2. A. P. Alivisatos, "Perspectives on the physical chemistry of semiconductor nanocrystals", J. Phys. Chem., Vol. 100, p. 13226, 1996.
  3. D. L. Feldheim and C. D. Keating, "Self-assembly of single electron transistors and related devices", Chem. Soc. Rev., Vol. 27, p. 1, 1998. https://doi.org/10.1039/a827001z
  4. C. B. Murray, D. J. Norris and M. G. Bawendi, "Synthesis and characterization of nearly monodisperse CdE (E= sulfur, selenium, tellurium) semiconductor nanocrystallites", J. Am. Chem. Soc., Vol. 115, p. 8706, 1993. https://doi.org/10.1021/ja00072a025
  5. J. E. B. Katari, V. L. Colvin and A. P. Alivisatos, "X-ray photoelectron spectroscopy of CdSe nanocrystals with applications to studies of the nanocrystal surface", J. Phys. Chem., Vol. 98, p. 4109, 1994. https://doi.org/10.1021/j100066a034
  6. T. Vossmeyer, L. Katsikas, M. Giersig, I. G. Popovic, K. Diensner, A. Chemseddine, A. Eychmuller and H. Weller, "CdS nanoclusters: synthesis, characterization, size dependent oscillator strength, temperature shift of the excitonic transition energy, and reversible absorbance shift", J. Phys. Chem., Vol. 98, p. 7665, 1994. https://doi.org/10.1021/j100082a044
  7. S. G. Hickey and D. J. Riley, "Photoelectrochemical studies of CdS nanoparticle-modified electrodes", J. Phys. Chem., Vol. 103, p. 4599, 1999. https://doi.org/10.1021/jp990020r
  8. M. L. Steigerwald, A. P. Alivisatos, J. M. Gibson, T. D. Harris, R. Kortan, A. J. Muller, A. M. Thayer, T. M. Duncan, D. C. Douglass, and L. E. Brus, "Surface derivatization and isolation of semiconductor cluster molecules", J. Am. Chem. Soc., Vol. 110, p. 3046, 1988. https://doi.org/10.1021/ja00218a008
  9. X. C. LI, J. R. FRYER, and D. J. C. DJ, "A new, simple and versatile method for the production of nano-scale particles of semiconductors", J. Chem. Soc., Chem. Commun., Vol. 14, p. 1715, 1994.
  10. Y. Xie, Y. T. Qian, W. Z. Wang, S. Y. Zhang, and Y. H. Zhang, "Molecular cloning and disease association of hepatitis G virus: a transfusion-transmissible agent", Science, Vol. 272, p. 1926, 1996. https://doi.org/10.1126/science.272.5270.1926
  11. M. L. Steigerwald, A. P. Alivisatos, J. M. Gibson, T. D. Harris, R. Kortan, A. J. Muller, A. M. Thayer, T. M. Duncan, D. C. Douglass, and L. E. Brus, "Surface derivatization and isolation of semiconductor cluster molecules", J. Am. Chem. Soc., Vol. 110, p. 3046, 1988. https://doi.org/10.1021/ja00218a008
  12. Y. Xie, Y. T. Qian, W. Z. Wang, S. Y. Zhang, and Y. H. Zhang, "A benzene-thermal synthetic route to nanocrystalline GaN", Science, Vol. 272, p. 1926, 1996. https://doi.org/10.1126/science.272.5270.1926
  13. J. M. Lauerhaas and M. J. Sailor, "Chemical Modification of the Photoluminescence Quenching of Porous Silicon", Science, Vol. 261, p. 1567, 1993. https://doi.org/10.1126/science.261.5128.1567
  14. J. L. Heinrich, C. L. Curtis, G. M. Credo,, K. L. Kavanagh, and M. J. Sailor, "Luminescent Colloidal Silicon Suspensions from Porous Silicon", Science, Vol. 255, p. 66, 1992. https://doi.org/10.1126/science.255.5040.66
  15. N. A. Dhas, C. P. Raj, and A. Gedanken, "Preparation of Luminescent Silicon Nanoparticles: A Novel Sonochemical Approach", Chem. Mater., Vol. 10, p. 3278, 1998. https://doi.org/10.1021/cm980408j
  16. C. S. Yang, R. A. Bley, S. M. Kauzlarich, H. W. H. Lee, and G. R. Delgado, "Synthesis of Alkyl-Terminated Silicon Nanoclusters by a Solution Route", J. Am. Chem. Soc., Vol. 121, p. 5191, 1999. https://doi.org/10.1021/ja9828509