• 제목/요약/키워드: Low temperature aging

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Equilibrium Analysis on the Pyrotechnic Reactions of Igniters (열역학 평형 계산을 이용한 점화제의 점화반응 분석)

  • Eom, Ki Heon;Kim, Kyung Min;Won, Yong Sun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.1036-1037
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    • 2017
  • This study investigated the aging reactions of three kinds of igniters(BKNO3, THPP, ZPP). The life-time of igniter depends on oxygen and moisture in the air. For example, Magnesium contained in the $BKNO_3$ reacts with oxygen and water to form oxide and hydrate. This reaction has an adverse effect on ignition reaction and could be information to analyze aging. Thermodynamic calculation could interpret the aging reaction by calculating flame temperature applying several variables(initial temperature, composition, etc.). If combustion is not completed because of aging igniters, flame temperature will be formed at a low range. The result of this research is expected to support the analysis of igniters aging reactions.

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Effect of Low-Temperature Sintering on Electrical Properties and Aging Behavior of ZVMNBCD Varistor Ceramics

  • Nahm, Choon-Woo
    • Korean Journal of Materials Research
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    • v.30 no.10
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    • pp.502-508
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    • 2020
  • This paper focuses on the electrical properties and stability against DC accelerated aging stress of ZnO-V2O5-MnO2-Nb2O5-Bi2O3-Co3O4-Dy2O3 (ZVMNBCD) varistor ceramics sintered at 850 - 925 ℃. With the increase of sintering temperature, the average grain size increases from 4.4 to 11.8 mm, and the density of the sintered pellets decreases from 5.53 to 5.40 g/㎤ due to the volatility of V2O5, which has a low melting point. The breakdown field abruptly decreases from 8016 to 1,715 V/cm with the increase of the sintering temperature. The maximum non-ohmic coefficient (59) is obtained when the sample is sintered at 875 ℃. The samples sintered at below 900 ℃ exhibit a relatively low leakage current, less than 60 mA/㎠. The apparent dielectric constant increases due to the increase of the average grain size with the increase of the sintering temperature. The change tendency of dissipation factor at 1 kHz according to the sintering temperature coincides with the tendency of the leakage current. In terms of stability, the samples sintered at 900 ℃ exhibit both high non-ohmic coefficient (45) and excellent stability, 0.8% in 𝚫EB/EB and -0.7 % in 𝚫α/α after application of DC accelerated aging stress (0.85 EB/85 ℃/24 h).

Influence of the Cure Systems on Long Time Thermal Aging Behaviors of NR Composites

  • Choi, Sung-Seen;Kim, Jong-Chul;Lee, Seung-Goo;Joo, Yong-L.
    • Macromolecular Research
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    • v.16 no.6
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    • pp.561-566
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    • 2008
  • NR composites with different curing systems were aged thermally at 60, 70, 80, and $90^{\circ}C$ for 2-185 days in a convection oven, and the changes in the crosslink density were investigated as a function of the accelerated thermal aging. The overall crosslink densities increased with increasing aging time irrespective of the aging temperatures and curing systems. The changes in crosslink density were enhanced by increasing the aging temperature. The degree of the increased crosslink density was in the following order: "the conventional cure system > the semi-EV system > the EV system". For short term thermal aging, the change in crosslink density with the aging time was complicated, particularly for low temperature aging. The activation energies of the change in crosslink density with thermal aging using the conventional and semi-EV cure systems increased and then remained relatively constant with increasing aging time, whereas that of the specimen with an EV cure system tended to increase linearly. The experimental results were explained by the dissociation of the existing polysulfidic linkages and the formation of new cross links through the crosslinking-related chemicals remaining in the sample.

The Energized Aging Property of Pole Mount Mold transformer by Back-to-back Method (반환부하법에 의한 옥외 주상용 몰드변압기의 과전열화 특정)

  • Hwang, Bo-Guk;Cho, Han-Goo;Lee, Un-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.484-487
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    • 2002
  • The mold transformers have been widely used in underground substations in large building and have some advantages in comparison to oil-transformer, that is low fire risk, excellent environmental compatibility, compact size and high reliability. In addition, the application of mold transformer for outdoor is possible due to development of epoxy resin. The mold transformer generally has cooling duct between low voltage coil and high voltage coil. A mold transformer made by one body molding method has been developed for small size and low loss. In this paper, the proto type mold transformer of 50kVA class is investigated by routine, type, special test. The outdoor energized aging test is investigated by back-to-back method to verify the long time performance of pole mold transformer. The aging process of transformer is analyzed by various diagnosis method such as DC voltage-current test, $tan{\delta}$, Meggar measurement, winding temperature and etc.

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Effects of Mg Addition to Cu/Al2O3 Catalyst for Low-Temperature Water Gas Shift (LT-WGS) Reaction

  • Zakia Akter Sonia;Ji Hye Park;Wathone Oo;Kwang Bok Yi
    • Clean Technology
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    • v.29 no.1
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    • pp.39-45
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    • 2023
  • To investigate the effects of Mg addition at different aging times and temperatures, Cu/MgO/Al2O3 catalysts were synthesized for the low-temperature water gas shift (LT-WGS) reaction. The co-precipitation method was employed to prepare the catalysts with a fixed Cu amount of 30 mol% and varied amounts of Mg/Al. Synthesized catalysts were characterized using XRD, BET, and H2-TPR analysis. Among the prepared catalysts, the highest CO conversion was achieved by the Cu/MgO/Al2O3 catalyst (30/40/30 mol%) with a 60 ℃ aging temperature and a 24 h aging time under a CO2-rich feed gas. Due to it having the lowest reduction temperature and a good dispersion of CuO, the catalyst exhibited around 65% CO conversion with a gas hourly space velocity (GHSV) of 14,089 h-1 at 300 ℃. However, it has been noted that aging temperatures greater or less than 60 ℃ and aging times longer than 24 h had an adverse impact, resulting in a lower surface area and a higher reduction temperature bulk-CuO phase, leading to lower catalytic activity. The main findings of this study confirmed that one of the main factors determining catalytic activity is the ease of reducibility in the absence of bulk-like CuO species. Finally, the long-term test revealed that the catalytic activity and stability remained constant under a high concentration of CO2 in the feed gas for 19 h with an average CO conversion of 61.83%.

Effect of Thermal Aging on Microstructure and Mechanical Properties of China Low-Activation Martensitic Steel at 550℃

  • Wang, Wei;Liu, Shaojun;Xu, Gang;Zhang, Baoren;Huang, Qunying
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.518-524
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    • 2016
  • The thermal aging effects on mechanical properties and microstructures in China low-activation martensitic steel have been tested by aging at $550^{\circ}C$ for 2,000 hours, 4,000 hours, and 10,000 hours. The microstructure was analyzed by scanning and transmission electron microscopy. The results showed that the grain size and martensitic lath increased by about $4{\mu}m$ and $0.3{\mu}m$, respectively, after thermal exposure at $550^{\circ}C$ for 10,000 hours. MX type particles such as TaC precipitated on the matrix and Laves-phase was found on the martensitic lath boundary and grain boundary on aged specimens. The mechanical properties were investigated with tensile and Charpy impact tests. Tensile properties were not seriously affected by aging. Neither yield strength nor ultimate tensile strength changed significantly. However, the ductile-brittle transition temperature of China low-activation martensitic steel increased by $46^{\circ}C$ after aging for 10,000 hours due to precipitation and grain coarsening.

Effects of Dislocation Distribution and Carbon Effective Diffusion on Strain Aging Behavior of a Low Carbon Dual Phase Steel (저탄소 Dual Phase강의 가공시효에 미치는 탄소유효확산 및 전위분포의 영향)

  • Yoo, S.H.;Jung, K.C.;Hong, K.H.;Park, KT.
    • Transactions of Materials Processing
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    • v.30 no.5
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    • pp.226-235
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    • 2021
  • The strain aging behavior of a low carbon dual phase steel was examined in two conditions: representing room temperature strain aging (100 ℃ × 1 hr after 7.5 % prestrain) and bake hardening process (170 ℃ × 20 min after 2 % prestrain), basing on carbon effective diffusion and dislocation distribution. The first principle calculations revealed that (Mn or Cr)-vacancy-C complexes exhibit the strongest attractive interaction compared to other complexes, therefore, act as strong trapping sites for carbon. For room temperature strain aging condition, the carbon effective diffusion distance is smaller than the dislocation distance in the high dislocation density region near ferrite/martensite interfaces as well as ferrite interior considering the carbon trapping effect of the (Mn or Cr)-vacancy-C complexes, implying ineffective Cottrell atmosphere formation. Under bake hardening condition, the carbon effective diffusion distance is larger compared to the dislocation distance in both regions. Therefore, formation of the Cottrell atmosphere is relatively easy resulting in to a relatively large increase in yield strength under bake hardening condition.

A Study on the 43$0^{\circ}C$ Degradation Behavior of Cast Stainless Steel(CF8M)(II)-Evaluation of Low Cycle Fatigue Characteristics- (주조 스테인리스강 CF8M의 43$0^{\circ}C$ 열화거동에 관한 연구 (II) -저사이클 피로특성 평가-)

  • Gwon, Jae-Do;U, Seung-Wan;Park, Jung-Cheol;Lee, Yong-Seon;Park, Yun-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.9 s.180
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    • pp.2183-2190
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    • 2000
  • A thermal aging is observed in a primary reactor cooling system(RCS) made of a casting stainless steel when the RCS is exposed for long period at the reactor operating temperature, 290~3300C An investigation of effects of thermal aging on a low cycle fatigue characteristics included a stress variations caused by a reactor operation and trip, is required. The purpose of the present investigation is to find an effect of a thermal aging of the CF8M on a low cycle fatigue life. The specimen of CF8M are prepared by an artificially accelerated aging technique holding 300 and 1800hr at 4300C respectively. The low cycle fatigue tests for the virgin and two aged specimens are performed at the room temperature for various strain amplitudes($\varepsilon$ta), 0.3, 0.5, 0.8, 1.0, 1.2 and 1.5% strain. Through the experiment, it is found that the fatigue life is rapidly reduced with an creasing of the aging time. The experimental fatigue life estimation formulas between the virgin and two aged specimen are obtained and are proposed to a analysis purpose.

Low Cycle Fatigue Behavior of 429EM Stainless Steel at Elevated Temperature (429EM 스테인리스강의 고온 저주기 피로 거동)

  • Lee, Keum-Oh;Yoon, Sam-Son;Hong, Seong-Gu;Kim, Bong-Soo;Lee, Soon-Bok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.4
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    • pp.427-434
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    • 2004
  • Ferritic stainless steel is recently used in high temperature structures because of its good properties of thermal fatigue resistance, corrosion resistance, and low price. Tensile and low-cycle fatigue (LCF) tests on 429EM stainless steel used in exhaust manifold were performed at several temperatures from room temperature to 80$0^{\circ}C$. Elastic Modulus, yield strength, and ultimate tensile strength monotonically decreased when temperature increased. Cyclic hardening occurred considerably during the most part of the fatigue life. Dynamic strain aging was observed in 200~50$0^{\circ}C$, which affects the cyclic hardening behavior. Among the fatigue parameters such as plastic strain amplitude, stress amplitude, and plastic strain energy density (PSED), PSED was a proper fatigue parameter since it maintained at a constant value during LCF deformation even though cyclic hardening occurs considerably. A phenomenological life prediction model using PSED was proposed considering the influence of temperature on fatigue life.

Characteristic of High Voltage Aging in AC PDPs

  • Lee, Yong-Han;Kim, Oe-Dong;Ahn, Byoung-Nam;Choi, Kwang-Yeol;Kim, Sung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.932-934
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    • 2006
  • A relationship between discharge delay time and the aging method were investigated: A-Y (Address electrode - Scan electrode) aging and conventional X-Y(Common electrode - Scan electrode) aging with the variation of sustain voltage beyond self-erasing discharge. Although A-Y aging decreases discharge delay time, it has several drawbacks like non-uniformity of discharge, degradation of luminous efficiency and a color temperature. In a conventional aging condition which is carried out near the mid-margin voltage, discharge delay time is short in low voltage and high frequency condition. As an alternative to conventional voltage aging, high voltage aging is suggested which is carried out at self-erasing sustain voltage region. High voltage aging shows lower discharge delay time and fast aging speed than conventional voltage aging.

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