• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.276-281
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• 2006

Although fireside corrosion of heat transfer surfaces in coal fired steam generators has been a problem to some extent for a number of tears, with the advent of low NOx firing systems these surfaces can be exposed to conditions that will exacerbate wastage rates. Numerous reports of waterwall wastage in coal fired boilers have appeared in the literature. It is believed that wastage results both from gaseous phase attack of metal surfaces and from deposition of ash and unburned fuel. Gaseous phase attack is known to occur in the presence of reducing sulfur species such as $H_2S$ and in the presence of fuel chlorine. The highest wastage rates are thought to be due to deposition of unoxidized material and the presence of fuel chlorine. Localized wall and near wall conditions that may exacerbate wastage include reducing conditions, high temperatures, high heat fluxes, and a high fraction of unoxidized material deposited. So, this study is directed at developing an advanced corrosion model in coal-fired utility boilers.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2017년도 추계학술발표회
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• pp.208-208
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• 2017

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.491-494
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• 2008

The hydrogen fuel and fuel cell which have high energy efficiency and low pollutant emission are getting interest as an alternative energies due to the fossil fuel exhaust, green house effect and atmospheric pollutant problems. The hydrogen gas is very effective as an alternative energy. But, if it is leaked into the air it forms the mixed gas with the air then the danger of the explosion is risen up. So, the secure the safety is mostly important. In this research, to detect the leakage of the hydrogen rapidly, added the odorant materials which don't include the sulfur component into the hydrogen gas and researched on the effect of each odorant on the performance of the fuel cell. As the results, setting the cumulation electric power on the basis and comparing the pure hydrogen, 2,3-Butanedione 5ppm mixed gas 86.1%, 5-Ethylidene-2-Norbornene 17ppm mixed gas 88.2%, Isovaleraldehyde 10ppm mixed gas 74.8%, Ethyl Isobutyrate 2.2ppm mixed gas 93.5% of performance was shown.

• 한국응용과학기술학회지
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• 제29권3호
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• pp.450-458
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• 2012

최근 정부는 국가 온실가스를 효율적으로 감축시켜 국제적인 기후변화에 대응하기 위하여 여러 부문에서 기술개발을 진행 중에 있다. 이를 달성하기 위하여 정부는 화석연료를 대체하고 이산화탄소를 감축시키는 수단으로 바이오연료를 저탄소와 탄소중립자원으로 검토하고 있는 실정이다. 일반적으로, 목질계로부터 생산된 2세대 바이오연료는 수송부문에서 기존 화석연료를 대체하고 온실가스를 감축하는데 큰 효과가 있는 것으로 알려져 있다. 이러한 이유로 정부는 목질계 기반 바이오매스 액화연료(biomass-to-liquid fuel)에 대해 파일럿 수준으로 기술개발 중에 있다. 따라서 본 연구에서는 바이오매스액화연료 생산을 위한 동일공정으로 합성된 F-T(Fischer-Tropsch) 디젤의 연료적 특성을 연구하였다. 합성 F-T 디젤은 자동차용 경유에 단독 또는 혼합하여 사용할 수 있는 장점으로 인해 자동차용 경유엔진에 사용될 수 있다. 그 이유는 합성 F-T 디젤이 자동차용 경유와 비슷한 물리적 특성을 가지기 때문이다. 본 연구에 사용된 F-T 디젤은 Fischer-Tropsch (F-T) 공정을 이용하여 저온($240^{\circ}C$)에서 철 촉매를 가지고 합성되었다. 합성 F-T 디젤은 n-파라핀과 iso-파라핀을 함유하고, 등유와 경유 성분을 가진 $C_{12}{\sim}C_{23+}$ 분포로 이루어졌다. 합성 F-T 디젤은 합성 F-T 연료부터 증류를 통해 분리된 합성 F-T 디젤은 자동차용 경유에 비해 세탄가가 높으며, 방향족화합물은 매우 낮고, 황함량는 초저황(sulfur free) 수준으로 평가되었다. 또한 합성 F-T 디젤은 자동차용 경유와 비교하여 황과 방향족 화합물의 함량이 낮기 때문에 윤활성이 열악함을 보였다.

• 한국환경과학회지
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• 제5권2호
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• pp.131-140
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• 1996

Analysis of hourly variations of sulfur dioxide ($SO_2$) concentrations affected by regional climates for the period of yellow sandy dusts was carried out from March 31 through April 9, 1993. The concentration of 50, at a coastal city, Kangnung city, was much higher than that at an inland city Wonju in the west, but the hourly distrbutions of $SO_2$ concentrations show a similar tendency at both cities. Under the prevailing synoptic-scale westerly winds blowing over a high Mt. Taegualyang in the west toward Kangnung city in the eastern coastal region, the $SO_2$ at Kangnung is trapped by an easterly sea-breeze during the day and under prevailing easterly winds, it is also isolated by the high wall of Mt. Taegualyang, with its high concentration from 14 to 16 LST. Furthermore, when the westerly winds were dominent all day long the high $SO_2$ concentrations at Kangnung were produced by its intrusion from a urban city, Wonju or China in the west into a mountainous coastal city, Kangnung, to some extent, and when the air becomes rapidly cooled down at the clear daytime or the nighttime, their concentrations are also increased by a great amount of heating fuel combustion. Especilly, its maximum concentrations were shown in Wonju and Kangnung from 08 LST through 10 LST, due to the increase of auto vehicles near the beginning time of office hour and were detected again after sunset due to both increases of vehicles at the end of office hour and heating fuel combustion. During the period of Yellow Sandy Dusts which are transported from China into Korea, the $SO_2$ concentrations on rainy days at Wonju and Kangnung were much lower than the monthly mean values of $SO_2$, and their low concentrations could be caused by the scavenging process of rain.

• 한국연소학회지
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• 제16권4호
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• pp.1-7
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• 2011

The purpose of this study was to analyze the effect of pilot injection strategy on the combustion and emissions characteristics in a four cylinder common-rail direct injection diesel engine fueled with biodiesel(soybean oil) blend. The tested fuel was mixed of 20% biodiesel and 80% ULSD(Ultra low sulfur diesel) by volume ratio. The experiments were performed under two load conditions, and results were compared with those of single injection. The experimental results showed that the ignition delay of BD20 was shorter than compared to that of ULSD in the case of low load condition. Also, the fuel consumption of BD20 was more higher than that of ULSD. Fuel consumption by applied pilot injection strategy were generally decreased compared with that of single injection. In the case of pilot injection, the exhaust emissions such as CO and HC emissions were decreased compared to the single injection.

• 한국자동차공학회논문집
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• 제14권3호
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• pp.75-80
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• 2006

Since air pollution has become a globally critical issue and exhaust emissions from automobiles cause a major source of air pollution, many countries including advanced countries have stipulated stringent emission regulations. Particularly in diesel vehicles, NOx and particulate matters exhaust in significant amounts even though diesel vehicles provide merits in aspects of higher thermal efficiency and lower $CO_2$. To reduce Particulate matters and NOx, after-treatment technology such as filter trap, oxidation catalysts and EGR has been applied. This test was conducted on the effect of continuous regeneration diesel particulate filter and cooled-EGR, and 15ppm low sulfur diesel was used as a test fuel. Exhaust emissions, PM, NOx, CO, HC and Soots were measured and compared under D-13 and D-3 modes.

• 동력기계공학회지
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• 제19권2호
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• pp.49-56
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• 2015

As an alternative fuel that can be used in SI engine, LPG is one of clean fuels with larger H/C ratio compared to gasoline, low $CO_2$ emission, and small amount of pollutants such as sulfur compounds. When LPG is used in spark ignition engine, volumetric efficiency of the engine can be improved and pumping loss can be reduced by performing direct injection into the combustion chamber instead of port fuel injection. LPG-DI engine allows for lean combustion and stratified combustion under low load. In case of stratified combustion, air fuel ratio can be greatly increased compared to theoretic mixture ratio combustion. Improved thermal efficiency of the engine and reduced pumping loss can be expected from stratified combustion. Accordingly in this study, an experimental apparatus for visualization was designed and manufactured to study the combustion process of LPG after injection and ignition, intended to examine ignition probability and combustion characteristics of spark ignition direct injection(SIDI) LPG fuel. Ambient pressure, ambient temperature and fuel injection pressure were found as important variables that affect ignition probability and flame propagation characteristics of LPG-air mixture. Also, it was verified that the injected LPG fuel can be directly ignited by spark plug under appropriate ambient conditions.

• 한국대기환경학회지
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• 제20권2호
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• pp.225-236
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• 2004

Diesel engines which emit a lot of PM and NOx have been known as a main air polluter. Especially, diesel particulate matters (OPM) including black smoke are hazardous air pollutants to human health and environment. The nations retaining advanced engine technologies have reinforced emission regulations. To meet these regulations diesel engine manufacturers have developed low-emission diesel engines, aftertreatment equipments, alternative fuel technologies and so on. In this study, particle number concentrations characteristics according to particle size and engine driving conditions were analyzed when these low-emission technologies were applied. There was a tendency of increasing particle number concentrations from heavy-duty diesel engines with increasing engine rpm and load rate. In the cases of COPF (Catalytic Diesel Particulate Filter), CNG (Compressed Natural Gas) engine and ULSD (Ultra Low Sulfur Diesel) more than 99% of particle number concentration were removed.

• 한국자동차공학회논문집
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• 제19권4호
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• pp.130-136
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• 2011

This study describes the effect of EGR rate on the combustion and emissions characteristics of a four cylinder CRDI diesel engine using biodiesel (soybean oil) blended diesel fuel. The test fuel is composed of 30% biodiesel and 70% ULSD (ultra low sulfur diesel) by volumetric ratio. The experiment of engine emissions and performance characteristics were performed under the various EGR rates. The experimental results showed that ignition delay was extended, the maximum combustion pressure and heat release gradually were decreased with increasing EGR rate. Comparing biodiesel blended fuel to ULSD, the injection quantity of biodiesel blended fuel was further increased than ULSD. The emission results showed that $NO_x$ emission of biodiesel blended fuel becomes higher according to the increase of EGR rate. However, in the case of biodiesel blended fuel, HC, CO and soot emissions were decreased compared to ULSD.