• 제목/요약/키워드: Long-Term Aging

검색결과 439건 처리시간 0.032초

TGA와 가속열화를 이용한 전선 피복용 PVC의 열적 열화평가 (Evaluation of Thermal Aging on PVC Using Thermo Gravimetry Analysis and Accelerated Thermal Aging Test)

  • 박형주;김기환;김홍
    • 한국화재소방학회논문지
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    • 제18권3호
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    • pp.45-50
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    • 2004
  • 600V용 비닐절연전선의 절연체로 사용되는 PVC의 열적 열화 특성을 열중량분석과 가속열화시험을 이용하여 연구하였다. TGA를 이용한 활성화에너지는 Kissinger method와 Flynn-Wall-Ozawa method를 이용하여 측정하였다. 활성화에너지를 계산한 결과 600V용 PVC 절연전선은 89.29 kJ/mol~111.39 kJ/mol, 내열 PVC절연전선은 97.80 kJ/mol~119.25 kJ/mol로 나타났다. 또한, 저온인 80, 90, 10$0^{\circ}C$에서 장기가속열화를 통한 활성화에너지를 아레니우스 방정식을 이용하여 계산하였다. 그 결과 PVC 절연전선은 92.16 kJ/mol,내열 PVC절연전선은 97.52kJ/mol로 나타났다. 연구결과에 있어 600V내열 PVC절연 전선이 PVC 절연전선에 비해 활성화에너지가 큼을 알 수 있었으며, 사용 수명을 예측함에 있어서도 장기적으로 안정함을 예측할 수 있다.

SEI 성장 모델을 이용한 리튬 이온 배터리의 캘린더 노화 연구 (Study of the Calendar Aging of Lithium-Ion Batteries Using SEI Growth Models)

  • 전동협;채병만;이상우
    • 공업화학
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    • 제35권1호
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    • pp.48-53
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    • 2024
  • 전기화학 기반의 SEI 성장 모델을 이용하여 리튬이온 배터리의 캘린더 노화 및 장기 수명을 예측하였다. 네 가지 유형의 장기 SEI 성장 모델(용매 확산 제한 모델, 전자 이동 제한 모델, 리튬-간극 확산 제한 모델, 반응 제한 모델)을 적용하여 수치해석이 이루어졌고, 캘린더 에이징 동안의 용량 감소와 리튬 재고 손실을 계산하였다. 수치해석 결과, 전자 이동 제한 모델과 리튬-간극 확산 제한 모델이 낮은 용량 감소를 보였으며, 용매 확산 제한 모델과 반응 제한 모델은 10년이내에 80%의 용량 감소를 보였다. 캘린더 노화 중 저온 보관 시 SEI의 성장을 저하시켜 용량 감소가 적었다. 사이클링 중 C-rate가 증가할수록 SEI 두께 증가로 수명 하락이 크게 나타났으나 그 차이는 크지 않았다.

Electric Field Induced Super-cooling System for Long Term Dry-aged Beef Loin

  • Park, Sin-Young;Kim, Hack-Youn
    • 한국축산식품학회지
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    • 제40권2호
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    • pp.286-296
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    • 2020
  • This study investigates the utilization of an electric-field-induced super cooling system in long-term dry aging of beef loin. Analyzed quality properties of dry-aged beef loin applied with electric field refrigeration (EFR) versus commercial refrigeration (CR). Quality properties was including aging loss, pH, water holding capacity (WHC), cooking loss, color, warner-bractzler shear force (WBSF), total plate count (TPC), and thiobarbituric acid reactive substances (TBARS). Aging loss of wk 1 EFR was significantly lower than CR (p<0.05). pH of EFR was slow change tendency compared CR. WHC of both aging methods were higher with increase in aging duration. Cooking loss of wk 1, 2, 4, and 10 EFR were significantly lower than CR (p<0.05). Lightness and redness of EFR was slow change tendency compared CR. However, yellowness of EFR was increased until wk 2, 3, and significantly decreased at wk 10 (p<0.05), but yellowness of CR was decreased until wk 3 and significantly increased with an increasing aging weeks (p<0.05). Both aging methods of WBSF was decreased with increase in aging weeks; however, wk 10 of CR was significantly lower than EFR (p<0.05). TPC after wk 3 EFR groups were significantly lower than CR groups (p<0.05), and TBARS of EFR groups were significantly lower than CR (p<0.05). The present results show that application of the EFR system for dry aging beef loin can extends its shelf life and induce changes of several aging properties in similar to commercial aging.

Petroleomic Characterization of Bio-Oil Aging using Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry

  • Smith, Erica A.;Thompson, Christopher;Lee, Young Jin
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.811-814
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    • 2014
  • Bio-oil instability, or aging, is a significant problem for the long-term storage of fast pyrolysis oils. We investigated bio-oil aging at the molecular level using Fourier-transform ion cyclotron resonance mass spectrometry. Petroleomic analysis suggests that bio-oil aging is resulted from the oligomerization of phenolic lignin products whereas 'sugaric' cellulose/hemicellulose products have negligible effect.

가속 열시효에 따른 308 및 316L 스테인리스강 용접부의 기계적 물성 및 미세구조 평가 (Evaluation of Mechanical Properties and Microstructure of Thermally Aged 308 and 316L Stainless Steel Welds)

  • 공병서;홍성훈;장창희;김만원
    • 한국압력기기공학회 논문집
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    • 제13권1호
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    • pp.92-100
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    • 2017
  • Due to the presence of ferrite phase in the finished welds, austenitic stainless steel welds (ASSWs) are considered susceptible to the thermal aging embrittlement during long-term service in light water reactor environment. In this study, the thermal aging embrittlement of typical ASSWs, E308 and ER316L welds, were evaluated after the long-term exposure up to 20,000 h at $400^{\circ}C$, which is considered as an accelerated thermal aging condition. After thermal aging, the decrease of tensile ductility and fracture toughness was observed. The microstructure observation with high resolution transmission electron microscopy revealed that spinodal decomposition in ferrite phase of both E308 and ER316L welds would be the main cause of the degradation of mechanical properties. Also, it was shown that the difference of thermal ageing embrittlement between ER316L and E308 welds was significant, such that the reduction of fracture resistance for ER316L weld was much larger than that of E308 weld.

Bass 확산모형을 활용한 국내 주택연금의 중·장기 수요예측 (Long-Term Projection of Demand for Reverse Mortgage Using the Bass Diffusion Model in Korea)

  • 양진아;민대기;최형석
    • 한국경영과학회지
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    • 제42권1호
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    • pp.29-41
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    • 2017
  • Korea is expected to become a super-aged society by 2050. Given an aging population and the increasing pressure for the early retirement, a sufficient social safety net for elderly population becomes important. The Korean government introduced public reverse mortgage program in 2007, which is a product for aging seniors and the elderly, The number of reverse mortgage subscribers has also steadily grown. The demand continues to grow, but the reverse mortgage over a long period of time is a highly uncertain and risky product in the position of guarantee or lending institution. Thus, suitable demand prediction of the reverse mortgage subscribers is necessary for stable and sustainable operation. This study uses a Bass diffusion model to forecast the long-term demand for reverse mortgage and provides insight into reverse mortgage by forecasting demand for stability and substantiality of the loan product. We represent the projections of new subscribers on the basis of the data obtained from Korea Housing Finance Corporation. Results show that potential market size of Korean reverse mortgage reaches approximately 760,000-1,160,000 households by 2020. We validate the results by comparing the estimate of the cumulative number of subscribers with that found in literature.

원자로시설의 경년열화 종합관리에 관한 규정개발 방향 (Development of Regulation on the Integrated Materials Aging Management for Nuclear Facilities)

  • 신호상;홍진기;김진수;정연기;정명조;정해동;최영환
    • 한국압력기기공학회 논문집
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    • 제7권4호
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    • pp.12-18
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    • 2011
  • The renewed global interest in nuclear power has arisen from the need to reduce greenhouse gas emissions and to provide sufficient electricity for a growing global population. Many countries with nuclear power plants (NPPs) are still implementing license extensions of 10~20 years, and even consideration is being given to the concept of life-beyond-60, a further period of license extension from 60 to 80 years. To solve the materials aging problem is integral to its success. A foundation for effective aging management of nuclear power plants is that aging is properly taken into account at each stage of a plant's lifetime, i.e. in design, manufacture, construction and operation including long term operation and decommissioning. To evaluate the plant aging phenomena, a lot of background information such as materials and environment of the parts of the reactor and plant systems is needed by the experts. Information on degradation mechanisms is also used. In this paper, a regulation on the integrated materials aging management for nuclear facilities is proposed. The proposed regulation identifies key elements of effective aging management for nuclear power plants and provides the requirements on aging management for nuclear facilities throughout all stages of the lifetime of the plant.

일본 개호인재 확보 정책동향 및 시사점 (Review of Healthcare Specialist Training Programs in Japan and Policy Implications)

  • 권주영
    • 한국융합학회논문지
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    • 제11권3호
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    • pp.237-244
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    • 2020
  • 초고령사회에 진입한 일본은 의료 및 복지에 대한 수요증가에 대응하기 위해서 정부의 다양한 정책적 방안들이 논의되고 있다. 특히 개호인력 확보 및 인력양성을 위해 일본정부와 지자체가 1) 인프라 구축, 2) 개호복지사 수학자금 등 대출제도, 3)외국인 유학생 개호인력유입 등 다양한 방면으로 전문 인력 확보 대책을 추진하고 있다. 또한, 교육기관인 대학에서도 커뮤니티케어 교육연구센터를 설립하여 의료, 복지, 교육에 관한 전문인재 육성의 질적 향상을 도모하고, 직업교육을 통해 개호전문인력을 지속적으로 육성하고 있다. 한국도 급속한 고령화와 의료기술의 진보 등 보건의료를 둘러싼 환경이 크게 변화하면서 고령자에 대한 개호 수요가 증가할 것으로 전망되고 있다. 개호요구의 급증에 비해 노동 인구의 감소로 심각한 인력부족을 겪고 있는 일본의 선 경험에 비추어 보건인력 확보에 대한 정책방안의 논의가 이루어져 할 것이다.

온도편차가 한우고기의 장기간 숙성 중 보수력, 연도, 지방산화 및 육색안전성에 미치는 영향 (Effect of Temperature Deviation on the Water-holding Capacity, Tenderness, Lipid Oxidation, and Color Stability of Korean Hanwoo (韓牛) Beef during Long-term Aging)

  • 강선문;안달래;성필남;김진형;조수현;박범영;김윤석
    • 한국식생활문화학회지
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    • 제34권6호
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    • pp.771-778
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    • 2019
  • This study investigated the effect of temperature deviation on the water-holding capacity, tenderness, lipid oxidation, and color stability of Korean Hanwoo (韓牛) beef during long-term aging. The striploins (M. longissimus lumborum) were aged for 56 days at 2±1℃ (T1), 2±2℃ (T2), or 2±3℃ (T3). Drip loss and cooking loss were higher (p<0.05) in T3 than in T1 on day 56. The Warner-Bratzler shear force value was similar for all treatments during aging times. On day 56, the content of 2-thiobarbituric acid reactive substances was higher (p<0.05) in T3 as compared to T1. The CIE L* and b* values were similar for all treatments, but the a* value was lower (p<0.05) in T3 than in T1 on the last day. These findings indicate that high temperature deviation adversely affects the water-holding capacity, lipid oxidation stability, and color stability of Hanwoo beef during long-term aging.

인구 변동에 따른 119 구급 서비스의 장기 추계 (Long-Term Estimation of 119 Ambulance Services by Demographic Changes in Korea)

  • 강경희
    • 한국화재소방학회논문지
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    • 제32권5호
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    • pp.105-111
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    • 2018
  • 본 연구에서는 소방청의 119 구급서비스 통계연보와 통계청의 인구동향조사 및 장래추계인구를 활용하여 저출산 고령화와 같은 인구 변동이 미래의 구급 이송 서비스 이용에 미치는 영향을 분석하였다. 우리나라의 인구는 2031년 정점에 이룬 후 인구 감소가 시작될 것으로 추계되나 70세 이상 노인 인구는 계속 증가할 것으로 전망하고 있다. 본 연구 결과에 따르면, 인구 변동을 반영한 이송률, 즉 인구 1,000명 당 이송 환자 수는 최근 추이와 비교해 큰 폭의 변화는 없으나 70세 이상 노인 인구에 대한 구급 서비스는 기하급수적으로 늘어날 전망이다. 따라서 저출산, 고령화에 따른 인구 변동은 구급 서비스의 양적, 질적 변화를 수반하게 되며, 장기적인 관점에서의 대응이 요구된다. 특히 고령화에 따른 구급 서비스의 효과적 대응은 물론 인구 변화에 따른 기존 관할 영역의 조정과 인력, 자원의 재배치 등이 고려되어야 할 것이다.