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Photocatalytic and Sonophotocatalytic degradation of alachlor using different photocatalyst

  • Bagal, Manisha V.;Gogate, Parag R.
    • Advances in environmental research
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    • v.2 no.4
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    • pp.261-277
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    • 2013
  • The degradation of alachlor has been investigated using sonolysis (US), photocatalysis (UV) and sonophotocatalysis (US/UV) using three photocatalyst viz. $TiO_2$ (mixture of anatase and rutile), $TiO_2$ (anatase) and ZnO. The effect of photocatalyst loading on the extent of degradation of alachlor has been investigated by varying $TiO_2$ (both types) loading over the range of 0.01 g/L to 0.1 g/L and ZnO loading over the range of 0.05 g/L to 0.3 g/L. The optimum loading of the catalyst was found to be dependent on the type of operation i.e., photocatalysis alone or the combined operation of sonolysis and photocatalysis. All the combined processes gave complete degradation of alachlor with maximum rate of degradation being obtained in the case of sonophotocatalytic process also showing synergistic effect at optimized loading of photocatalyst. About 50% to 60% reduction in TOC has been obtained using the combined process of sonophotocatalysis depending on the operating conditions. The alachlor degradation fitted first order kinetics for all the processes under investigation. It has been observed that the $TiO_2$ (mixtrure of anatase and rutile) is the most active photocatalyst among the three photocatalysts studied in the current work. The effect of addition of radical enhancers and scavengers on sonophotocatalytic degradation of alachlor has been investigated in order to decipher the controlling mechanism. The alachlor degradation products have been identified using LC-MS method.

Characteristics of Anaerobic Digestion using Food waste leachate under Increased Organic Loading rate (유기물부하량 증가에 따른 음폐수 혐기성소화의 특성 분석)

  • Jae-Hoon Jeung;Woo-Jin Chung;Soon-Woong Chang;Jin-Tea Kim;Seong-Yeob Jeong;Seung-Youn Yang
    • Journal of Environmental Science International
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    • v.31 no.12
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    • pp.1127-1134
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    • 2022
  • Herein , the effect of changes in the organic loading rate in anaerobic digestion was evaluated. The experiment was carried out by a laboratory -scale semi-continuous stirred tank reactor, and feedstock was food-waste leached. The organic loading rate was increased by 0.5 kgVS/m3 in each phase from 1.0 kgVS/m3 to 4.0 kgVS/m3. At the end of the operation, to check the failure of the reactor, the organic loading rate was increased by 1.0 kgVS/m3 in each phase and reached 6.0 kgVS/m3. This shows that the biogas yield decreased as organic loading rate increased. Biogas production seemed to be unstable at 3.5-6.0 kgVS/m3. Moreover, biogas production dramatically fell to approximately 0 mL at 6.0 kgVS/m3, which was decided as the operation failure on the 16th day of the las tphase. The result of the reactor analysis shows that the cumulation of volatile fatty acid increased as the organic loading rate increased. This seems to occur due to the decreasein pH in the reactor and led to extinction of anaerobic bacteria, which were the biogas products. Although the buffer compound (alkalinity) could prevent the decline in pH, the concentration of alkalinity was found to be lacking at a high organic loading rate

Operation evaluation of DAF pilot plant for water treatment process in Hoedong Reservoir (회동수원지의 정수처리 공정을 위한 DAF pilot plant 운영 성능평가)

  • Maeng, Minsoo;Shahi, Nirmal Kumar;Kim, Donghyeun;Shin, Gwyam;Dockko, Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.6
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    • pp.463-471
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    • 2020
  • A 1,000 ㎥/d DAF(dissolved air flotation) pilot plant was installed to evaluate the performance of the floating process using the Nakdong River. Efficiency of various DAF operations under different conditions, such as hydraulic loading rate, coagulant concentration was evaluated in the current research. The operation conditions were evaluated, based on the removal or turbidity, TOC(total organic carbon), THMFP(trihalomethane formation potential), Mn(manganese), and Al(aluminum). Also, particle size analysis of treated water by DAF was performed to examine the characteristics of particles existing in the treated water. The turbidity removal was higher than 90%, and it could be operated at 0.5 NTU or less, which is suitable for the drinking water quality standard. Turbidity, TOC, and THMFP resulted in stable water quality when replacing the coagulant from alum to PAC(poly aluminum chloride). A 100% removal of Chl-a was recorded during the summer period of the DAF operations. Mn removal was not as effective as where the removal did not satisfy the water quality standards for the majority of the operation period. Hydraulic loading of 10 m/h, and coagulant concentrations of 40 mg/L was determined to be the optimal operating conditions for turbidity and TOC removal. When the coagulant concentration increases, the Al concentration of the DAF treated water also increases, so coagulant injection control is required according to the raw water quality. Particle size distribution results indicated that particles larger than 25 ㎛ showed higher removal rates than smaller particles. The total particel count in the treated water was 2,214.7 counts/ml under the operation conditions of 10 m/h of hydraulic loading rate and coagulant concentrations of 60 mg/L.

Design and Operation of a Multipath Reservation-Based Remote Crane Control System (다중경로 예약 기반 크레인 원격 운전시스템 설계 및 운용)

  • Choi Dae-Woo;Lho Tae-Jung;Kim Jin-Young
    • Journal of Institute of Control, Robotics and Systems
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    • v.11 no.9
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    • pp.816-821
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    • 2005
  • The remote operation of $4\~5$ cranes for container loading/unloading at a port by one operator will dramatically improve loading/unloading efficiency through productivity increase, cost reduction, and so on. This study develops a remote crane control system for container loading/unloading yard cranes. First, a wireless video and audio system to transmit views and sounds of the working field is designed by using 3 web cameras and a microphone. Next, a RSVP-based multi-path reservation method is presented with a view to improving the quality of service in the communication network for remote control. Simulation results show that a RSVP-based multi-path reservation can enhance the reservation success rate in the TCP/IP network.

SOIL FAILURE AND ITS APPLICATION TO VIBRATING TILLAGE TOOL

  • Niyamapa, Tanya
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1993.10a
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    • pp.1053-1062
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    • 1993
  • The effect of loading speed on soil failure was studied by using a high speed triaxial compression test. Tests were conducted at 0.35-6.2m/s loading speed to compress soil specimens of sandy loam at different moisture contents. The axial stress at fracture increased with increase in loading speed up to certain critical speeds, however they decreased as the speed up to certain critical speeds, however they decreased as the speed increased further. Experiments were also conducted in the field of sandy loam soil with the vibrating tillage tool. Tests were done at 0.33-0.85m/s tractor speed oscillating frequency 13.7hz and oscillating amplitude 59mm. The maximum oscillating velocity of tillage tool was 2.5m/s. It was observed that for the oscillating operation, initially draft slightly increased with increase in forward speed and then it decreased .For the non-oscillating operation, draft increased continuously with increase in forward speed. Approach of studying soil failure in the laboratory test can be related to the field experiments.

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The Cooling Characteristics for Circular Irradiation Hole under Suppressing Jet Flow at Guide Tube in HANARO (안내관 제트유동 억제시의 하나로 원형 조사공의 냉각특성)

  • Wu S. I.;Park P. C.
    • 한국전산유체공학회:학술대회논문집
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    • 2004.03a
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    • pp.208-213
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    • 2004
  • The HANARO, multi-purpose research reactor, 30 MWth open-tank-in- pool type, is under normal operation since it reached the initial critical in February 1995. The HANARO is planning to produce a fission moly-99 of radio isotopes, a mother nuclide of Tc-99m, a medical isotope and is under developing a target handling tool for loading and unloading it in a circular flow tube (OR-5). A guide tube is extended from the reactor core to the top of the reactor chimney for easily un/loading a target under the reactor normal operation. But active coolant through the core can be quickly raised up to the top of the chimney through the guide tube by jet flow. This paper is described an analytical analysis to calculate the hole size of a orifice inserted in the circular irradiation hole and to study the flow characteristics through the guide tube under reactor normal operation and loading the target. As results, the results show that the hole size of orifice was 31 mm of the inner diameter to suppress the guide tube jet flow and the coolant safely cooled the target of fission moly after inserting the orifice to the flow tube.

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Seismic analysis of turbo machinery foundation: Shaking table test and computational modeling

  • Tripathy, Sungyani;Desai, Atul K
    • Earthquakes and Structures
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    • v.12 no.6
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    • pp.629-641
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    • 2017
  • Foundation plays a significant role in safe and efficient turbo machinery operation. Turbo machineries generate harmonic load on the foundation due to their high speed rotating motion which causes vibration in the machinery, foundation and soil beneath the foundation. The problems caused by vibration get multiplied if the soil is poor. An improperly designed machine foundation increases the vibration and reduces machinery health leading to frequent maintenance. Hence it is very important to study the soil structure interaction and effect of machine vibration on the foundation during turbo machinery operation in the design stage itself. The present work studies the effect of harmonic load due to machine operation along with earthquake loading on the frame foundation for poor soil conditions. Various alternative foundations like rafts, barrette, batter pile and combinations of barrettes with batter pile are analyzed to study the improvements in the vibration patterns. Detailed computational analysis was carried out in SAP 2000 software; the numerical model was analyzed and compared with the shaking table experiment results. The numerical results are found to be closely matching with the experimental data which confirms the accuracy of the numerical model predictions. Both shake table and SAP 2000 results reveal that combination of barrette and batter piles with raft are best suitable for poor soil conditions because it reduces the displacement at top deck, bending moment and horizontal displacement of pile and thereby making the foundation more stable under seismic loading.

The package loading equipment development cutting both ends in the process of packaging lumber for improving the working environments (작업환경개선을 위한 목재포장공정에 있어서의 양끝절단포장적재장치 개발)

  • Kang, Ji-Ho;Hong, Dong-Pyo
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.29 no.1
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    • pp.135-142
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    • 2006
  • The package loading process of tile lumbering industry is an operation that after a pair of workers binds three or six lumber into a unit and cut the both ends of the lumber, carry and pack and load the weight cargo of 30-50kg. The package loading process causes lots of noise and wood dust when the lumber are cut and brings about the main cause of the musculoskeletal disorder when workers carry the heavy goods. Therefore, we developed the monolithic package loading equipment cutting both ends that is enable to improve the working method and environments of the existing package loading process. The noise and wood dust were reduced by developing the device and the main cause of shirking duties on working place was solved by preventing the musculoskeletal disorder and improving the working environments as excluding the work of carrying heavy goods.

An Emprical Study of TPM Application for Loading and Unloading Equipments of Incheon Port (인천항(仁川港) 항만하역장비(港灣荷役裝備)에 대한 TPM 적용을 위한 실증적 연구)

  • Park Sang-Ki;Lee Chang-Ho
    • Journal of the Korea Safety Management & Science
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    • v.8 no.2
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    • pp.169-184
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    • 2006
  • We analyzed the questionnaire survey for the current maintenance of Incheon port's loading and unloading equipments and the possibility of TPM(Total Productive Maintenance) application. Results of the survey indicated that the current maintenance of Incheon port's loading and unloading equipments was not good. So we suggest TPM as the future maintenance methodology of equipments. Using TPM to the loading and unloading equipments we will expect to improve the productivity of the loading and unloading operation and to increase the life time of equipment. And also it will raise the safety of Incheon port.

Numerical Analysis and Comparision of Train Loading Diagram (열차하중선도의 수치적 분석 및 비교)

  • Oh, Ji-Taek;Choi, Jin-Yu;Kim, Hyun-Min;Park, Chan
    • Proceedings of the KSR Conference
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    • 2002.10b
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    • pp.1029-1034
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    • 2002
  • Object of this paper are numerical and experimental evaluation of Korean Standard Train Loading(L-loading scheme) with respect to UIC's and real train loading, quantitative formulation of the real train types in South Korea. These objects are require to changing environment of train operation, for example, high density traffic and gradual train speed increase. For the reasonable repair, reinforcement and rehabilitation of existing railway infrastructures, statistical analysis of the loading effect during the long term experiment in conventional lines have to conduct. Statistical quantitative formulation of the loading case need to consistency numerical evaluation of the railway safety. Hereafter, those results will be core technical data for the economy enhancement of international line construction. Further, these results are using to make track maintenance criterions for transcontinental, speed up railway and revision of standard train leading diagram.

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