• 제목/요약/키워드: Lithium secondary battery

검색결과 362건 처리시간 0.032초

저급 탄산리튬의 재결정화를 통한 고순도 탄산리튬 제조에 대한 연구 (A study on the fabrication of high purity lithium carbonate by recrystallization of low grade lithium carbonate)

  • 김보람;김대원;황성옥;정수훈;양대훈
    • 한국결정성장학회지
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    • 제31권1호
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    • pp.16-23
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    • 2021
  • 리튬이차전지 제조 공정 중 발생한 폐액으로부터 회수된 탄산리튬의 경우, 이차전지 양극재의 원료인 코발트, 니켈 및 망간의 중금속이 함유되어 있다. 본 연구에서는 탄산리튬의 재결정화를 통하여 순도 98.28 %의 저급 탄산리튬 분말에 함유된 중금속을 제거하고 탄산리튬의 순도를 높이고자 하였다. 먼저 염산 수용액을 이용하여 탄산리튬의 침출 효율을 살펴보았으며, pH 5 조건으로 침출 후 탄산나트륨의 당량 및 농도의 탄산리튬 재결정에 대한 영향을 확인하였다. 리튬의 함량 기준 대비 탄산나트륨 1 당량에서 1.5로 증가할수록, 농도 1.4 M에서 2.8 M로 증가할수록 회수율은 향상되었으며, 탄산나트륨의 투입 조건이 달라짐에 따라 결정 형상이 달라지는 것을 SEM 분석을 통해 확인할 수 있었다. 재결정된 탄산리튬 분말은 수세하여 순도 99.9 % 이상의 고순도 탄산리튬을 회수할 수 있었다.

Current Collectors for Flexible Lithium Ion Batteries: A Review of Materials

  • Kim, Sang Woo;Cho, Kuk Young
    • Journal of Electrochemical Science and Technology
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    • 제6권1호
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    • pp.1-6
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    • 2015
  • With increasing interest in flexible electronic devices and wearable appliances, flexible lithium ion batteries are the most attractive candidates for flexible energy sources. During the last decade, many different kinds of flexible batteries have been reported. Although research of flexible lithium ion batteries is in its earlier stages, we have found that developing components that satisfy performance conditions under external deformation stress is a critical key to the success of flexible energy sources. Among the major components of the lithium ion battery, electrodes, which are connected to the current collectors, are gaining the most attention owing to their rigid and brittle character. In this mini review, we discuss candidate materials for current collectors and the previous strategies implemented for flexible electrode fabrication.

리튬 2차전지용 전해액의 초성 및 비교 분석 (Mixture of the Lithium Secondary Batteries and Analyses)

  • 임동규;김영호;조봉희;우병원;나두찬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.395-397
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    • 1999
  • There are many efforts to improve electrolytes to satisfy the requirements of a lithium rechargeable battery. We have investigated a binary solvent mixture containing the electrolyte lithium salt($LiBF_4$, $LiPF_6$), that is conductive and electrochemically stable. Ionic conductivities were measured between -5 and $80^{\circ}C$, and cyclic voltammetry between 2.5 and 4.3 V were measured by SUS or platinum electrode.

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고용량 리튬이온이차전지용 고내열성 분리막 코팅장비 연구 (A Study on High Thermal Stable Separator Coating Machine for High-Capacity Lithium Ion Secondary Battery)

  • 노진희;손화진;이호철;박정현
    • 한국기계가공학회지
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    • 제18권12호
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    • pp.45-51
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    • 2019
  • As the separator becomes thinner, the role of thermal stability becomes more important in ensuring the high capacity of medium- and large-sized lithium-ion secondary batteries. In this study, we researched coating technology to improve the separator's thermal stability. We minimized the coating time by optimizing the design of a vertical two-stage coater that was thin, uniform, and capable of coating on both sides at the same time with a maximum 2㎛ thickness coating layer of fluorinated polymer (PVdF-HFP) on the bare polyethylene (PE) separator, which increased the thermal stability. In addition, during the coating process, a dual-jacket-roll method of drying was developed that increased the drying effectiveness without thermal damage to the separator. We also investigated the thermal stability of the separator manufactured from a coating machine, and studied the battery-applied performance by making a lithium-ion pouch battery.

Preparation and Characterization of Pitch/Cokes Composite Anode Material for High Power Lithium Secondary Battery

  • Yu, Lan;Kim, Ki-Jung;Park, Dae-Yong;Kim, Myung-Soo;Kim, Kab-Il;Lim, Yun-Soo
    • Carbon letters
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    • 제9권3호
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    • pp.210-217
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    • 2008
  • Petroleum pitch and coke with wet mixture method or with dry mixture method were investigated to develop the composite anodic carbon material of high power lithium ion battery. Cokes coated with pitch were obtained by the heat treatment of mixture of cokes and pitch with different weight ratios at $800{\sim}1200^{\circ}C$. The charge and discharge characteristic of the consequent composite anodic carbon material assembled in batteries was tested. Cokes with wet mixture method have a smooth surface and their capacity changed little with changing temperature and content as compared to the cokes with dry mixture method. Although the reversible capacities showed different values by the anode manufacturing method, the composite anode with the mixture of 20 wt% of petroleum pitch and 80 wt% of coke showed the higher power capability and initial efficiency than the pitch based anode. However, the reversible capacity of the composite anode showed the reduced value as compared with the pitch based anode.

나트륨을 활용한 이차전지 연구동향 (Research Review of Sodium and Sodium Ion Battery)

  • 유철휘;강성구;김진배;황갑진
    • 한국수소및신에너지학회논문집
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    • 제26권1호
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    • pp.54-63
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    • 2015
  • The secondary battery using sodium is investigating as one of power storage system and power in electric vehicles. The secondary battery using sodium as a sodium battery and sodium ion battery had merits such as a abundant resources, high energy density and safety. Sodium battery (sodium molten salt battery) is operated at lower temperature ($100^{\circ}C$) compared to NAS and ZEBRA battery ($300{\sim}350^{\circ}C$). Sodium ion battery is investigating as one of the post lithium ion battery. In this paper, it is explained for the principle and recent research trends in sodium molten salt and sodium ion battery.