• Title/Summary/Keyword: Lithium ion secondary battery

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Novel Synthesis Method and Electrochemical Characteristics of Lithium Titanium Oxide as Anode Material for Lithium Secondary Battery

  • Kim Han-Joo;Park Soo-Gil
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.3
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    • pp.119-123
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    • 2005
  • Lithium titanium oxide as anode material for energy storage prepared by novel synthesis method. Li$_{4}$Ti$_{5}$O$_{12}$ based spinel-framework structures are of great interest material for lithium-ion batteries. We describe here Li$_{4}$Ti$_{5}$O$_{12}$ a zero-strain insertion material was prepared by novel sol-gel method and by high energy ball milling (HEBM) of precursor to from nanocrystalline phases. According to the X-ray diffraction and scanning electron microscopy analysis, uniformly distributed Li$_{4}$ Ti$_{5}$O$_{12}$ particles with grain sizes of 100nm were synthesized. Lithium cells, consisting of Li$_{4}$ Ti$_{5}$O$_{12}$ anode and lithium cathode showed the 173 mAh/g in the range of 1.0 $\~$ 3.0 V. Furthermore, the crystalline structure of Li$_{4}$ Ti$_{5}$O$_{12}$ didn't transform during the lithium intercalation and deintercalation process.

Fabrication of LiNiO2 using NiSO4 Recovered from NCM (Li[Ni,Co,Mn]O2) Secondary Battery Scraps and Its Electrochemical Properties (NCM(Li[Ni,Co,Mn]O2)계 폐 리튬이차전지로부터 NiSO4의 회수와 이를 이용한 LiNiO2 제조 및 전기화학적 특성)

  • Kwag, Yong-Gyu;Kim, Mi-So;Kim, Yoo-Young;Choi, Im-Sic;Park, Dong-Kyu;Ahn, In-Sup;Cho, Kwon-Koo
    • Journal of Powder Materials
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    • v.21 no.4
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    • pp.286-293
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    • 2014
  • The electrochemical properties of cells assembled with the $LiNiO_2$ (LNO) recycled from cathode materials of waste lithium secondary batteries ($Li[Ni,Co,Mn]O_2$), were evaluated in this study. The leaching, neutralization and solvent extraction process were applied to produce high-purity $NiSO_4$ solution from waste lithium secondary batteries. High-purity NiO powder was then fabricated by the heat-treatment and mixing of the $NiSO_4$ solution and $H_2C_2O_4$. Finally, $LiNiO_2$ as a cathode material for lithium ion secondary batteries was synthesized by heat treatment and mixing of the NiO and $Li_2CO_3$ powders. We assembled the cells using the $LiNiO_2$ powders and evaluated the electrochemical properties. Subsequently, we evaluated the recycling possibility of the cathode materials for waste lithium secondary battery using the processes applied in this work.

The Effect of Crystalline Type of Carbonaceous Materials on Performance of the Carbon Anode for Lithium Ion Secondary Battery (리튬이온이차전지에서 결정성 탄소재료가 탄소부극 특성에 미치는 영향)

  • Kim, Hyun-Joong;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1059-1064
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    • 1998
  • We have investigated various kind of graphite and MCMB6-28 to develop carbon negative electrode for lithium ion secondary battery. The interlayer length of them was $3.358{\sim}3.363{\AA}$ and the BET specific surface area was $2.95{\sim}26.15m^2/g$. From this study, When the interlayer of them was large and the BET specific surface area was high, the electrochemical characteristics of them was very excellent. Adding 0, 3, 5, wt% of KJ-Black as conducting agent to various graphitic carbon active materials, interface resistance of electrode and electrolyte was less, but rechargeability was better at 3 wt%. At constant current charge and discharge test, discharge capacity was small according to large current.

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The Polyaniline Electrode Doped with Li Salt and Protonic Acid in Lithium Secondary Battery

  • Ryu, Kwang-Sun;Kim, Kwang-Man;Hong, Young-Sik;Park, Yong-Joon;Jang, Soon-Ho
    • Bulletin of the Korean Chemical Society
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    • v.23 no.8
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    • pp.1144-1148
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    • 2002
  • We prepared the polyaniline (Pani) film and powder by chemical polymerization and doping with different dopants and also investigated the capability of Li//polyaniline cells after assembling. The oxidation/reduction potentials and electrochemical reaction of Li//polyaniline cells were tested by cyclic voltammetry technique. The Li//Pani-HCl cells with 10% and 20% conductors show a little larger specific discharge capacities than that without conductor. The highest discharge capacity of almost 50 mAh/g at 100th cycle is also achieved. However, Li//Pani-LiPF6 with 20% conductor shows a remarkable performance of ~90 mAh/g at 100th cycle. This is feasible value for using as the positive electrode material of lithium ion secondary batteries. It is also proved that the powder type electrode of Pani is better to use than the film type one to improve the specific discharge capacity and its stability with cycle.

Analysis of Secondary Battery Trends Using Topic Modeling: Focusing on Solid-State Batteries

  • Chunghyun Do;Yong Jin Kim
    • Asian Journal of Innovation and Policy
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    • v.12 no.3
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    • pp.345-362
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    • 2023
  • As the widespread adoption and proliferation of electric vehicles continue, the secondary battery market is experiencing rapid growth. However, lithium-ion batteries, which constitute a majority of secondary batteries, present high risks of fire and explosion. Solid-state batteries are thus garnering attention as the next-generation batteries since they eliminate fire hazards and significantly reduce the risk of explosions. Against this background, the study aimed to analyze research trends and provide insights by examining 2,927 domestic papers related to solid-state batteries over the past decade (2013-2022). Specifically, we used topic modeling to extract major keywords associated with solid-state batteries research and to explore the network characteristics across major topics. The changes in research on solid-state batteries were analyzed in-depth by calculating topic dominance by year. The findings provide an overview of the emerging trends in domestic solid-state battery research, and might serve as a valuable reference in shaping long-term research directions.

Development of Battery Temperature Monitoring and Simulation System for Aging Method of Lithium-ion Battery for Electric Vehicles (전기차 리튬이온 배터리의 에이징 공법을 위한 배터리 온도 모니터링 및 시뮬레이션 시스템 개발)

  • Jeong, He-min;Hong, Seong-Wung
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2022.07a
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    • pp.149-152
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    • 2022
  • 최근 전기차의 기술 발전이 급속도로 증가함에 따라 이차전지의 수요가 증가하게 되었다. 그로인해 다량의 고품질 전지를 생산하기 위해 제조 공장이 가동되고 있지만 생산된 전지의 품질의 핵심이 되는 화성공정의 에이징 과정 진행 중 온도 관리에 실패할 경우, 전지의 폭발 및 화재의 위험이 있다. 본 논문은 이차전지를 생산하는 에이징 공정의 효율적인 온도 관리를 위해 목업 모형을 만들어 온도 센서를 통한 온도 수집 및 모니터링 시스템을 개발하고, 공조기 바람을 통해 전지의 온도가 변화하는 속도를 계산하고, 이상온도에 도달해 고온의 상태가 되었을 경우 주변 전지로 전달되는 열을 시뮬레이션 통한 효율적인 공조 대책을 제시하여 이차전지 생산의 품질 향상과 화재 예방을 통해 전기차 생산에 따른 리튬이온 전지의 수요 해결에 기여한다.

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