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http://dx.doi.org/10.4150/KPMI.2014.21.4.286

Fabrication of LiNiO2 using NiSO4 Recovered from NCM (Li[Ni,Co,Mn]O2) Secondary Battery Scraps and Its Electrochemical Properties  

Kwag, Yong-Gyu (Dept. of Materials Engineering and Convergence Technology & RIGET, Gyeongsang National University)
Kim, Mi-So (Dept. of Materials Engineering and Convergence Technology & RIGET, Gyeongsang National University)
Kim, Yoo-Young (Dept. of Mechanical Engineering, Gyeongnam National University of Science and Technology)
Choi, Im-Sic (R&D center, Metal Chemistry Corp.)
Park, Dong-Kyu (LINC & School of Materials Science and Engineering, Gyeongsang National University)
Ahn, In-Sup (Dept. of Materials Engineering and Convergence Technology & RIGET, Gyeongsang National University)
Cho, Kwon-Koo (Dept. of Materials Engineering and Convergence Technology & RIGET, Gyeongsang National University)
Publication Information
Journal of Powder Materials / v.21, no.4, 2014 , pp. 286-293 More about this Journal
Abstract
The electrochemical properties of cells assembled with the $LiNiO_2$ (LNO) recycled from cathode materials of waste lithium secondary batteries ($Li[Ni,Co,Mn]O_2$), were evaluated in this study. The leaching, neutralization and solvent extraction process were applied to produce high-purity $NiSO_4$ solution from waste lithium secondary batteries. High-purity NiO powder was then fabricated by the heat-treatment and mixing of the $NiSO_4$ solution and $H_2C_2O_4$. Finally, $LiNiO_2$ as a cathode material for lithium ion secondary batteries was synthesized by heat treatment and mixing of the NiO and $Li_2CO_3$ powders. We assembled the cells using the $LiNiO_2$ powders and evaluated the electrochemical properties. Subsequently, we evaluated the recycling possibility of the cathode materials for waste lithium secondary battery using the processes applied in this work.
Keywords
Electrochemical property; $LiNiO_2$ Recycling; Cathode material; Waster lithium secondary battery;
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1 D. Darvishi, D. F. Haghshenas, E. K. Alamdari, S. K. Sadrnezhaad and M. Halali: Hydrometallurgy, 77 (2005) 227.   DOI   ScienceOn
2 H. C. Lee: M. S. Thesis, Title of Dissertation, Dankook University, Seoul (1987) (Korean).
3 H. R. Park: J. Ind. Eng. Chem., 16 (2010) 698 (Korean).   DOI   ScienceOn
4 B. H. Kim, J. H. Kim, I. H. Kwon and M. Y. Song: Ceram. Int., 33 (2007) 837.   DOI   ScienceOn
5 Z. Yang, D. Choi, S. Kerisit, K. M. Rosso, D. Wang, J. Zhang, G. Graff and J. Liu: J. Power Sources, 192 (2009) 588.   DOI   ScienceOn
6 M. Arakawa, S. Tobishima, Y. Nemoto and M. Ichimura: J. Power Sources, 43 (1993) 27.   DOI   ScienceOn
7 C. K. Lee and K. I. Rhee: Hydrometallurgy, 68 (2003) 5.   DOI   ScienceOn
8 D. Y. Kim, J. I. La, E. H. Kim and C. S. Choi: KiChE., 17 (2001) 5059.
9 N. Ding, X. W. Ge and C. H. Chen: Mater. Res. Bull., 40 (2005) 1451.   DOI   ScienceOn
10 M. K. Jeong, C. S. Hwang and C. S. Choi: CLEAN TECHNOLOGY, 12 (2006) 101.
11 J. Khanderi and J. J. Schneider: Eur. J. Inorg. Chem. (2010) 4591.
12 C. K. Lee, D. H. Yang and C. Y. Suh: J. KSMER., 39 (2002) 157.
13 Cathode material for Li-ion secondary battery technology trend and market forecast (2011).
14 H. Yang, J. H. Pee, H. T. Kim and Y. J. Kim: J. Ceram. Process. Res., 13 (2012) 319.
15 S. M. Shin, N. H. Kim, J. S. Sohn, D. H. Yang and Y. H. Kim: Hydrometallurgy, 79 (2005) 172.   DOI   ScienceOn
16 J. G. Kang, G. Senanayake, J. S. Sohn and S. M. Shin: Hydrometallurgy, 100 (2010) 168.   DOI   ScienceOn
17 J. H. Moon, J. E. Ahn, H. J. Kim, S. H. Sohn, H. W. Lee and H. S. Kim: Applied Chemistry, 16 (2012) 73.
18 B. Swain, J. Jeong, J. C. Lee, G. H. Lee and J. S. Sohn: J. Power Sources., 167 (2007) 536.   DOI   ScienceOn
19 X. R. Deng, G. R. Hu, K. Du, Z. D. Peng, X. G. Gao and Y. N. Yang: Mater. Chem. Phys., 109 (2008) 469.   DOI   ScienceOn
20 K. H. Park, S. H. Jung, C. W. Nam, S. M. Shin and D. S. Kim: J. Kor. Inst. Met. &Mater., 42 (2004) 947.
21 F. Veglio, R. Quaresima, P. Fornari and S. Ubaldini: Waste Manage., 23 (2003) 245.   DOI   ScienceOn