• Rubber Technology
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• v.6 no.2
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• pp.91-98
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• 2005

Nano-sized cathode materials for high power lithium ion polymer battery are easily and economically prepared using united eutectic self-mixing method without any artificial mixing procedures of reactants and ultra-miniaturization of products. While the micro-sized $LiNi_{0.7}Co_{0.3}O_2$ exhibits the discharge capacities of 167.8 mAh/g at 0.1C and 142.5 mAh/g at 3.0C, those of the nano-sized $LiNi_{0.7}Co_{0.3}O_2$ are 170.8 mAh/g at 0.1C and 159.3 mAh/g at 3.0C. In the case of $LiCoO_2$, the micro-sized $LiCoO_2$ exhibits the discharge capacities of 134.8 mAh/g at 0.1C and 118.6 mAh/g at 5.0C. Differently, the nano-sized $LiCoO_2$ exhibits the discharge capacities of 137.2 mAh/g at 0.1C and 131.7 mAh/g at 5.0C.

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1591-1593
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• 1997

The purpose of this study is to research and develop $Li_xV_3O_8$ composite cathode for lithium polymer battery. We investigated electrochemical, interfacial properties and charge/discharge cycling of $Li_xV_3O_8$/SPE/Li cell. The radius of semicircle associated with the interfacial resistance of $Li_xV_3O_8$/SPE/Li cell increased very slowly during discharge process from 100% SOC to 90% SOC. And then the cell resistance was increased at discharge process from 10% SOC to 0% SOC. The discharge capacity based on $Li_xV_3O_8$ was 212mAh/g at 15th cycle. The $Li_xV_3O_8$/SPE/Li cell has a good properties.

• Journal of the Korean Electrochemical Society
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• v.14 no.2
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• pp.98-103
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• 2011

[ $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ ]cathode material for lithium secondary battery is obtained using co-precipitation method. To determine the optimal metal solution concentration value, the CSTR coprecipitation was carried out at various concentration values(1-2 mol/L). The surface morphology of coated samples was characterization by SEM(scanning electron microscope) and XRD (X-Ray Diffraction)analyses. Impedance analysis and cyclic voltammogram presented that internal resistance of the cell was dependent upon the concentration of metal solution. such data is very helpful in determining the optimal content of metal solution concentration to enhancing electrochemical property by adjusting powder size distribution and crystal structure.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.45 no.6
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• pp.60-66
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• 2008

The operating voltage of Li/SOCl2 battery decrease immediately when we give a load battery stored for long time. It is called voltage delay. We cannot rapidly operate equipment at emergence situation because the voltage delays. So we have to overcome voltage delay. We reported the results improved voltage delay in this paper through the control of the carbon cathode forming density. It is the classic method in order to control of voltage delay that is coating polymer in the lithium surface or put in the additive to electrolyte. If the carbon cathode forming density decreases, the operating voltage of battery becomes to increasing because solution resistance of battery reduce.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.64 no.4
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• pp.231-235
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• 2015

Bimodal Tram developed by KRRI is driven by a series Hybrid propulsion system which has both the CNG engine, generator and LPB(Lithium Polymer Battery) pack. It has three driving modes; Hybrid mode, Engine mode and Battery mode. Even in case of Battery mode, LPB pack to get enough power to drive the vehicle only by itself onsists of 168 LPB cells(80Ah per lcell), 650V. It is important thing to manage LPB pack in a right way, which will extend the lifetime of LPB cells and operate in the hybrid mode effectively. This paper has shown the development of battery management system(12 BMS, 1 BMS per 14cells) to manage LPB pack which is connected with CAN(Controller Area Network) each other and measure the voltage, current, temperature and also control the cooling fan inside of LPB pack. Using the measured data, BMS can show the SOC(State of Charge), SOH(State of Health) and other status of LPB pack including of the cell balancing.

• Journal of Surface Science and Engineering
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• v.54 no.5
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• pp.213-221
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• 2021

In order to improve the energy density and safety of Li-ion batteries, the development of a separator with high thermal stability and electrolyte wettability is an important desire. Thus, the ceramic separator to replace the polymer type is one of the most promising materials that can prevent short-circuit caused by the formation of dendrite and thermal deformation. In this study, we introduce the fabrication of various anodic aluminum oxide membranes for the application of Li-ion battery separators with the advantages of improved mechanical/thermal stability, wettability, and a high rate of Li⁺ migration through the membrane. Two different types of through-holes and branched anodic aluminum oxide membranes are well used in lithium-ion battery separators, however, branched anodic aluminum oxide membranes exhibit the most improved performance with capacity (126.0 mAh g^-1 @ 0.3C), capacity drop at the high C-rate (30.6 %), and low internal resistance (8.2 Ω).

• Journal of the Korean Electrochemical Society
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• v.24 no.4
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• pp.100-105
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• 2021

Recently, all-solid-state batteries have attracted much attention to improve safety of rechargeable lithium batteries, but the solid-state batteries of conductive ceramics or solid polymer electrolytes show poor electrochemical properties because of several problems such as high interfacial resistance and undesired reactions. To solve the problems of the reported all-solid-state batteries, a hybrid solid electrolyte is suggested, in this study, NASICON-type nanoparticle Li_1.5Al_0.5Ti_1.5P₃O₁₂ (LATP) conductive ceramic, PVdF-HFP, and a carbonate-based liquid electrolyte were composited to prepare a quasi-solid electrolyte. The hybrid solid electrolyte has a high voltage stability of 5.6 V and shows an suppress effect of lithium dendrite growth in the stripping-plating test. The LiNi_0.83Co_0.11Mn_0.06O₂ (NCM811)-based battery with the hybrid solid electrolyte exhibits a high discharge capacity of 241.5 mAh/g at a high charge-cut-off voltage of 4.8V and stable electrochemical reaction. The NCM811-based battery also shows 139.4 mAh/g discharge capacity without short circuit or explosion at 90℃. Therefore, the LATP-based hybrid solid electrolyte can be an effective solution to improve the safety and electrochemical properties of rechargeable lithium batteries.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.1.1-1.1
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• 2011

Electrospinning has known to be very effective tool for production of versatile one-dimensional (1D) nanostructured materials such as nanofibers, nanorod, and nanotubes and for easily assembly to two-, three-dimensional(2D, 3D) nanostructures such as thin film, membrane, and nonwoven web, etc. We have studied on the electrospinning technology for novel energy storage and conversion materials such as advanced separator, dye sensitized solar cell, supercapacitor, etc. High heat-resistive nanofibrous membrane as a new separator for future lithium ion polymer battery was prepared by electrospinning of PVdF based composite solution. The novel nanofibrous composite nonwovens have tensile strength of above 50 MPa and modulus of above 1.3 GPa. The internal structure of the electrospun composite nanofiber with a diameter of few hundreds nanometer were composed of core-shell nanostructure. And also electrospun $TiO_2$ nanorod/nanosphere based dye-sensitized solar cells with high efficiency are successfully prepared. Some battery performance will be introduced.

• Proceedings of the Korean Society of Computer Information Conference
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• 2017.07a
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• pp.390-391
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• 2017

본 논문에서는 배터리의 수명을 연장할 수 있는 효율적인 충전방법에 대해 제안하였다. 제안된 방법은 우선 충전하고자 하는 배터리의 전압과 전류를 측정한다. 측정된 배터리의 전압과 같은 값에서 1.5배 값까지 단계적으로 전압을 상승시켜 배터리의 상태를 검사한다. 배터리의 반응 상태들 중에서 충전이 가장 안정적인 전압을 결정한다. 전압이 결정되면 배터리의 전류 값을 배터리 용량의 1/3에서 1/10까지 단계적으로 조율하여 충전을 하도록 한다. 이러한 방법은 배터리를 보호하면서 충전 시간을 축소시켜 효율적으로 배터리를 관리할 수 있는 방법이다. 제안된 방법의 효율성을 입증하기 위해 핸드폰 보조배터리로 가장 많이 사용되고 있는 리튬 폴리머 배터리를 이용하여 실험하였다. 실험 결과 충전시간의 감소와 안전성 등의 효율성이 입증되었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.421-424
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• 2000

We have examined the impedance characteristics and the rate characteristics of LPB. As results, the impedance of LPB decreased with increased pressing rate of electrodes, adding amounts of PVdF and VGCF. And the rate characteristics of LPB increased with the a increase of pressure-rate, PVdF and VGCF contents. The rate characteristics of LPB was improved by pressing of electrode and adding of VGCF content. And specific capacity of anode was increased with adding amounts of PVdF. Higher pressing rate of electrodes, higher adding amounts of PVdF and VGCF was necessitated good rate characteristics for lithium polymer battery.