• Transactions of Materials Processing
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• v.32 no.3
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• pp.136-144
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• 2023

This study analyzed the mechanical behavior of lithium-ion battery pouch material and predicted its formability. A homogenization method was used to evaluate the physical properties of the pouch, and a new hardening model was developed. The yield function for the plastic model was optimized, and the anisotropic property was determined. Also, the forming limits were measured and predicted using the M-K forming limit diagram. Finally, a square cup drawing experiment confirmed the accuracy of the measured mechanical properties and the formability calculation.

• Resources Recycling
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• v.14 no.6 s.68
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• pp.37-43
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• 2005

[ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.3
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• pp.60-67
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• 2014

The battery cells in lithium-ion battery pack assembled with high-capacity and high-power pouch cells, are commonly cooled with thin aluminum cooling plates in contact with the cells. For HEV/EV lithium-ion battery systems assembled with high-capacity, high-power pouch cells, the cells are commonly cooled with thin aluminum cooling plates in contact with the cells. Thin aluminum cooling plates are cooled by cold plate with coolant flow paths. In this study, the effect of the battery cooling system design including aluminum cooling plate thickness and various position of cold plate on the cooling performance are investigated by using finite element methods (FEM). Optimal cooling plate and cold plate design are proposed for improving the uniformity in temperature distributions as well as lowering average temperature for the cells with large capacities based on the simulation results.

• Bulletin of the Korean Chemical Society
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• v.30 no.7
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• pp.1607-1610
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• 2009

The carbon-coated Si/Cu powder has been prepared by mechanical ball milling and hydrocarbon gas decomposition methods. The phase of Si/Cu powder was analyzed using X-ray diffraction (XRD), dispersive Raman spectroscopy, electron probe microanalysis (EPMA) and transmission electron microscope (TEM). The carbon-coated Si/Cu powders were used as anode active material for lithium-ion batteries. Their electrochemical properties were investigated by charge/discharge test using commercial LiCo$O_2$ cathode and lithium foil electrode, respectively. The surface phase of Si/Cu powders consisted of carbon phase like the carbon nanotubes (CNTs) with a spacing layer of 0.35 nm. The carbon-coated Si/Cu/graphite composite anode exhibited a higher capacity than commercial graphite anode. However, the cyclic efficiency and the capacity retention of the composite anode were lower compared with graphite anode as cycling proceeds. This effect may be attributed to some mass limitations in LiCo$O_2$ cathode materials during the cycling.

• Journal of Electrochemical Science and Technology
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• v.2 no.2
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• pp.97-102
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• 2011

Different amounts of excess lithium in the range of x = 0~0.3 were added to $Li_{1+x}[Mn_{0.720}Ni_{0.175}Co_{0.105}]O_2$ cathode materials synthesized using the co-precipitation method to investigate its microstructure and electrochemical properties. Pure layered structure without impurities was confirmed in the XRD pattern analysis and increasing peak intensity of $Li_2MnO_3$ was observed along with the addition of over 0.2 mol Li. The initial discharge capacity of the stoichiometric composition was determined to be 246 mAh/g, while the discharge capacity of the addition of 0.1 mol Li was obtained to be 241 mAh/g, which was not significantly different from that of the stoichiometric composition. However, the discharge capacities decreased dramatically after the addition of 0.2 and 0.3 mol Li to 162 mAh/g and 146 mAh/g, respectively. In the rate capability test, the active $Li_{1+x}[Mn_{0.720}Ni_{0.175}Co_{0.105}]O_2$ cathode material of the stoichiometric composition showed a dramatic decrease in its discharge capacity with increasing C-rate, as evidenced by the result that the discharge capacity at 5C was 13% compared with 0.1C. On the other hand, the discharge capacity of compositions containing excess lithium was improved at higher current rates. The cycling test showed that the composition containing an excess of 0.1 mol Li had the most outstanding capacity retention.

• Journal of Electrochemical Science and Technology
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• v.7 no.2
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• pp.170-178
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• 2016

Composited molybdenum oxide and amorphous carbon (MoO₃/C) as anode material for lithium ion batteries has been successfully synthesized by calcining polyaniline (PANI) doped with ammonium heptamolybdate tetrahydrate (AMo). The as prepared electrode material was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and field emission scanning electron microscopy (FE-SEM). The electrochemical performance of the anode was investigated by galvanostatic charge/discharge, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The MoO₃/C shows higher specific capacity, better cyclic performance and rate performance than pristine MoO₃ at room temperature. The electrochemical of MoO₃/C properties at various temperatures were also investigated. At elevated temperature, MoO₃/C exhibited higher specific capacity but suffered rapidly declines. While at low temperature, the electrochemical performance was mainly limited by the low kinetics of lithium ion diffusion and the high charge transfer resistance.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.598-598
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• 2012

Rechargeable lithium-ion batteries have been considered the most attractive power sources for mobile electronic devices. Although graphite is widely used as the anode material for commercial lithium-ion batteries, it cannot fulfill the requirement for higher storage capacity because of its insufficient theoretical capacity of 372 mAh/g. For the sake of replacing graphite, Sn-based materials have been extensively investigated as anode materials because they can have much higher theoretical capacities (994 mAh/g for Sn, 875 mAh/g for SnO, 783 mAh/g for $SnO_2$). However, these materials generate huge volume expansion and shrinkage during $Li^+$ intercalation and de-intercalation and result in the pulverization and cracking of the contact between anode materials and current collector. Therefore, there have been significant efforts of avoiding these drawbacks by using nanostructures. In this study, we present the CVD growth of SnO branched nanostructures on Cu current collector without any binder, using a combinatorial system of the vapor transport method and resistance heating technique. The growth mechanism of SnO branched nanostructures is introduced. The SnO nanostructures are evaluated as an anode for lithium-ion battery. Remarkably, they exhibited very high discharge capacities, over 520mAh/g and good coulombic efficiency up to 50 cylces.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.17 no.4
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• pp.46-58
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• 2021

As accidents with thermal runaway (TR) of lithium-ion batteries occur sporadically, the safety concern is the main obstacle that hinders the large-scale applications of lithium ion batteries. In most accidents, the TR of a single cell occurred first, and then dissipated the heat to the surroundings and triggered the TR of adjacent cells, resulting in TR propagation. Therefore, it is important to understand the mechanism of TR propagation and determine the key parameters during TR propagation in a battery pack. In this study, we performed a numerical analysis on the thermal runaway phenomenon by cathode active materials and appearance sizes in cylindrical lithium-ion batteries using a two-dimensional analysis model. The model results showed that the TR propagation of 21700 type cells (21 mm diameter, 70 mm height) occurs more rapidly than 46800 type cells (46 mm diameter, 80 mm height) and the LFP cell has higher thermal safety than the NCM cell. Especially, we found that the effect of the separator on the occurrence of TR is negligible.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.42 no.4
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• pp.855-863
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• 2017

Because Li-ion battery and Li-Polymer battery have high-energy storage density, they are used for various electronic devices such as electronic cigarette, electronic bicycle, drone, second battery, even golf cart and electronic car. Recently, however, battery explosion is sometimes occurring on electronic devices using Li-ion battery and is becoming serious as bodily harm is breaking out due to explosion. For this, this paper described the Li-ion Battery's operating principles and verified the cause of explosion by overload tests caused by the high-energy storage density. According to the these experiments, we conducted a study to develope scanning techniques of fire and safety measures.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.340-341
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• 2005

Lithium titanium oxide as anode material for energy storage prepared by novel synthesis method. $Li_4Ti_5O_{12}$ based spinel-framework structures are of great interest material for lithium-ion batteries. We describe here $Li_4Ti_5O_{12}$ a zero-strain insertion material was prepared by novel sol-gel method and by high energy ball milling (HEBM) of precursor to from nanocrystalline phases. According to the X-ray diffraction and scanning electron microscopy analysis, uniformly distributed $Li_4Ti_5O_{12}$ particles with grain sizes of 100nm were synthesized. Lithium cells, consisting of $Li_4Ti_5O_{12}$ anode and lithium cathode showed the 173 mAh/g in the range of 1.0 $\sim$ 3.0 V. Furthermore, the crystalline structure of $Li_4Ti_5O_{12}$ didn't transfer during the lithium intercalation and deintercalation process.