• Title/Summary/Keyword: Liquid-coupled

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Characteristics of High-Frequency Combustion Instabilities Occurring in Combustion Devices (연소장치에서 발생하는 고주파 연소 불안정 특성)

  • Seo, Seong-Hyeon
    • Journal of the Korean Society of Combustion
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    • v.17 no.1
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    • pp.30-36
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    • 2012
  • Dynamic characteristics of combustion occurring in various combustion devices have been extensively studied since most of high-performance combustion devices are susceptible to hazardous, unstable combustion that deteriorates combustor's lifetime. One of the most severe unstable combustion phenomena is high-frequency combustion instability in which heat release fluctuations from combustion are coupled to resonant modes of the combustor. Here in this study, characteristics of high-frequency combustion instabilities observed in three different combustion devices have been presented. Lean-premixed combustion instability occurs mainly due to equivalence ratio fluctuations which induce large heat release oscillations at lean conditions. Liquid-fueled combustion also shows high-frequency instability from energy coupling between pressure and heat release oscillations.

Determination of dextromethorphan and its metabolite dextrorphan in human urine by High-performance liquid chromatography

  • Son, Haeng-Ja;Park, Mee-Jung;Choi, Sang-Kil;Lim, Mi-Ae;Chung, Hee-Sun
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.279.2-280
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    • 2003
  • A simple and accurate reverse-phase high performance liquid chromatography (HPLC) coupled with photodiode array was developed for the determination of dextromethorphan(DM) and its metabolite dextrorphan(DX) in human urine. Chromatographic separation was accomplished on a cyano analytical column at 220 nm using a mobile phase containing 25 mM triethylammonium phosphate buffer(PH 3.0) in a 0-70% ACN gradient and triazolam(TZ) was used as internal standard(I.S). (omitted)

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FLUCTUATION INDUCED CRYSTALLIZATION: IN A SIMULTANEOUSLY PHASE SEPARATION AND CRYSTALLIZATION POLYOLEFIN BLEND SYSTEM

  • Zhang Xiaohua;Han, Charles C.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.158-158
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    • 2006
  • The correlation between liquid-liquid phase separation (LLPS) and crystallization at several compositions in statistical copolymer blends of poly (ethylene-co-hexene) (PEH) and poly (ethylene-co-butene) (PEB) has been examined. In this case, the LLPS is coupled with the other ordering process, i.e. crystallization. The overwhelming change in the crystallization kinetics due to the composition fluctuation caused by the spontaneous spinodal LLPS is observed. This coupling mechanism suggests a new mechanism in the nucleation-crystallization process.

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Dehydrogenation of 2-propanol as a chief reaction for the chemical heat pump (화학적 열 펌프의 주 반응으로서의 2-propanol 반응)

  • 김태경;여영구;송형근
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10a
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    • pp.1085-1090
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    • 1991
  • Chemical heat pump is a system to upgrade the low level energy such as industrial waste heat and solar energy by using coupled endothermic and exothermic chemical reactions. Dehydrogenation of 2-propanol can absorb heat near 80.deg. C and is transformed into acetone and hydrogen. Hydrogenation of acetone can liberate heat near 200.deg. C. Dehydrogenation of 2-propanol is difficult around 80.deg. C because .DELTA.G has positive value, but dehydrogenation reaction in liquid phase can overcome this problem because vaporized acetone and hydrogen can be rapidly eliminated. In this work, dehydrogenation of 2-propanol was investigated in liquid phase with Raney nickel catalyst. The energy efficiency of the chemical heat pump was estimated by computer simulation.

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Coupled Heat and Mass Transfer during the Absorption of Water Vapor into LiBr-H2O Liquid Solution Flowing down the Outside of the Horizontal Cylinder (수평원관상의 LiBr-수용액에 수증기가 흡수될때의 열 및 물질전달)

  • Lee, K.S.;Seo, S.C.;Kim, Y.I.;Park, D.K.
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.2
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    • pp.140-149
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    • 1988
  • The problem of heat and mass transfer accompanying the absorption of water vapor into LiBr-$H_2O$ liquid solution flowing over the outside of the horizontal cylinder was theoretically studied to understand the absorption process occuring in the absorber of the absorption heat pump. Numerical results are presented for various quantities of interest relating to temperature, concentration, heat flux and mass flux. Also, the effects of mass flowrate, initial average velocity, and the radius of the cylinder were investigated.

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Fluid Effects on the Core Seismic Behavior of a Liquid Metal Reactor

  • Koo, Gyeong-Hoi;Lee, Jae-Han
    • Journal of Mechanical Science and Technology
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    • v.18 no.12
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    • pp.2125-2136
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    • 2004
  • In this paper, a numerical application algorithm for applying the CFAM (Consistent Fluid Added Mass) matrix for a core seismic analysis is developed and applied to the 7-ducts core system to investigate the fluid effects on the dynamic characteristics and the seismic time history responses. To this end, three cases such as the in-air condition, the in-water condition without the fluid coupling terms, and the in-water condition with the fluid coupling terms are considered in this paper. From modal analysis, the core duct assemblies revealed strongly coupled out-of-phase vibration modes unlike the other cases with the fluid coupling terms considered. From the results of the seismic time history analysis, it was also verified that the fluid coupling terms in the CFAM matrix can significantly affect the impact responses and the seismic displacement responses of the ducts.

Simulation of Liquid Crystals Considering Flow Effect (흐름효과를 고려한 액정의 시뮬레이션)

  • Kim Hoon;Park Woo-Sang
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.3
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    • pp.260-266
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    • 2006
  • In this paper, We coupled fluid balance and director balance equation from Ericksen-Leslie's continuum theory and observed the motion of Liquid Crystal molecular. We simulated flow velocity and director distribution in which flow effect is considered in switching on and switching off state. We interpreted the dynamic response characteristic caused by the flow. As the result of the simulation, We could see the flow effect. In the case of Twisted Nematic(TN) cell, this flow caused abnormal twist temporarily in switching off state. We could prove that this abnormal twist is a direct cause of optical bounce phenomenon known well until now with the result of simulation. In addition, We analyzed the mechanism of the fast response due to flow in the case of Optically Compensated Bend(OCB) cell.

Rapid Analysis of Melamine Content in Powdered and Liquid Milk Using Fourier Transform Infrared Spectroscopy

  • Wang, Jun;Jun, Soo-Jin;Li, Qing X.
    • Food Science and Biotechnology
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    • v.18 no.5
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    • pp.1199-1203
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    • 2009
  • Melamine is a chemical intermediate to manufacture amino resins and plastics, which cannot be used as food additive since it can cause kidney stones. A qualitative determination method of melamine residue in powdered and liquid milk was developed using Fourier transform infrared (FTIR) spectroscopic technique. The calibration sets consisted of 21 standard melamine solutions, in which 1% trichloroacetic acid aqueous solution and acetonitrile (3:1, v/v) were used as solvent. The model was validated using 10 standard melamine solutions which were unused to build up the calibration set. Infrared (IR) absorbance peaks specific to almost all chemical groups in melamine molecule were shown in the spectral range between 1,100 and 1,800/cm. Combined partial least squares (PLS)-$2^{nd}$ derivative calibration model coupled with mean centering (MC) mathematical enhancement showed the highest correlation coefficients ($R^2$>0.99). In brief, the FTIR technique can be used for quantitative analysis of melamine in milk samples.

Computer Simulation of Liquid-Fuelled Combustor in Hot Vitiated-Air Stream (고온.저산소 농도영역중의 분무연소해석)

  • 김태한;최병륜
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.12
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    • pp.3187-3195
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    • 1993
  • Combustion of liquid-fuelled combustion in a high-temperature vitiated-air stream was studied. The mathematical formulation comprise the application of Eulerian conservation equation to the gas phase and Lagrangian equation of droplet motion. The latter is coupled with a droplet-tracking technique (PSI-CELL Model) which regard the droplet phase as a source of mass, momentum, and energy to the gaseous phase. Reaction rate is determined by taking into account the Arrhenius reaction rate based on a single-step reaction mechanism. The calculated profiles show somewhat uncertainess at the upstream, but bases data for designing the combustor followed by 2-phase flow were obtained.

Integration of Headspace Solid Phase Micro-Extraction with Gas Chromatography for Quantitative Analysis of Formaldehyde

  • Lo, Kong Mun;Yung, Yen Li
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.139-142
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    • 2013
  • A study was carried out to evaluate the solid phase micro-extraction (SPME) for formaldehyde emission analysis of uncoated plywood. In SPME, formaldehyde was on-fiber derivatized through headspace extraction and analyzed by gas chromatography coupled with mass spectrometry (GC/MS). The SPME was compared with desiccators (DC-JAS 233), small-scale chamber (SSC-ASTM D6007) and liquid-liquid extraction (LLE-EPA 556) methods which were performed in accordance with their respective standards. Compared to SSC (RSD 4.3%) and LLE (RSD 5.0%), the SPME method showed better repeatability (RSD 1.8%) and not much difference from DC (RSD 1.4%). The SPME has proven to be highly precise (at 95% confidence level) with better recovery (REC 102%). Validation of the SPME method for formaldehyde quantitative analysis was evidenced. In addition, the SPME by air sampling directly from plywood specimens (SPME-W) correlated best with DC ($r^2$ = 0.983), followed by LLE ($r^2$ = 0.950) and SSC ($r^2$ = 0.935).