• 제목/요약/키워드: Liquid-Phase Length

검색결과 185건 처리시간 0.031초

알킬 사슬 길이에 따른 러빙 처리된 자기 조립 단분자막의 액정 배향 연구 (Liquid crystal alignment on rubbed self-assembled monolayers according to alkyl chain length)

  • 박홍규;박무훈
    • 한국정보전자통신기술학회논문지
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    • 제14권5호
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    • pp.362-368
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    • 2021
  • 본 논문에서는 알킬 사슬 길이에 따른 러빙 처리된 불소화 자기 조립 단분자막(fluorinated self-assembled monolayers; FSAM)의 수직 액정 배향 상태를 보고한다. FSAM의 증착을 위해 간단한 공정인 기체-상 방법이 사용되었다. FSAM의 가시광선 영역대 광학 평균 투과율은 77.63%~78.21%로 75.89%의 투과율을 갖는 기존의 폴리이미드막보다 우수하였다. 또한 프리틸트각 측정과 편광현미경 사진을 통해 FSAM의 우수한 수직 배향 특성을 관찰하였다. 접촉각과 FSAM의 표면에너지 측정을 통해 알킬 사슬 길이에 따른 프리틸트각이 증가하는 것을 확인하였다. FSAM의 높은 광학 투과율과 균일한 수직 배향 특성은 FSAM이 액정 배향막으로서의 가능성을 보여주었다.

양식묘단 토양의 물리성이 묘삼생육 및 수량에 미치는 영향 (Effect of Physical Properties of Soil on Ginseng Seedling Growth in Nursery Bed)

  • 이종철;변정수
    • Journal of Ginseng Research
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    • 제19권3호
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    • pp.287-290
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    • 1995
  • This study was conducted to elucidate the effect of physical properties of soil in nursery bed with different densities on growth of ginseng seedling. Stem length, leaf length and leaf width of ginseng seedling showed the decreasing tendency with increasing the hardness of the nursery soil. Fresh root weight per seedling and number of available seedlings were increased significantly with decrease of the soil hardness. For solid, liquid phases, bulk density and hardness of soil, negative correlations were shown in stem length, leaf length, leaf width, root weight per seeding, and number t of available seedlings. On the other hand, gas phase, air permeability and porosity of soil had positive correlations with stem length, leaf length, leaf width, root weight per seedling and number of available seedlings. Key words Yang-Jik nursery, ginseng seedling, soil physical properties.

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Effects of Column Length and Particle Diameter on Phospholipid Analysis by Nanoflow Liquid Chromatography-Electrospray Ionization-Mass Spectrometry

  • Lee, Ju-Yong;Lim, Sang-Soo;Moon, Myeong-Hee
    • Mass Spectrometry Letters
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    • 제2권3호
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    • pp.65-68
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    • 2011
  • The effects of column length and particle size on the efficiency of separation and characterization of phospholipids (PLs) are investigated using nanoflow liquid chromatography-electrospray ionization-tandem mass spectrometry (nLC-ESI-MS-MS). Since PLs are associated with cell proliferation, apoptosis, and signal transduction, it is of increasing interests in lipidomics to establish reliable analytical methods for the qualitative and quantitative profiling of PLs related to biomarker development in adult diseases. Due to the complexity of PLs, the preliminary separation of PLs is necessary prior to MS analysis. In this study, length of capillary column and the particle size of reversed phase ($C_{18}$) packing materials are varied to find a reliable condition for the high speed and high resolution separation using 8 PL standard mixtures. From experiments, it was found that a capillary column of nLC-ESI-MS-MS analysis for PL mixtures can be minimized to a 5 cm long pulled tip column packed with 3 ${\mu}m$ $C_{18}$ particles without losing resolution.

단열식 오리피스를 적용한 고속회전 분무노즐의 미립화 특성 (Atomization Characteristics of the High Speed Rotating Injection System with Single Column Orifice)

  • 장성호;최성만
    • 한국분무공학회지
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    • 제14권3호
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    • pp.97-102
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    • 2009
  • The spray characteristics of the high speed rotating fuel injection system were studied. The five variants of rotating fuel nozzle were used by spray test. The diameter of single column injection orifices are varied from 1 mm, 2 mm, 3 mm, 4 mm and 5 mm. We constructed high speed rotating test rig and measured droplet size by PDPA (Phase Doppler Particle Analyzer) system. Also spray was visualized by using high speed camera. In the test results, we could understand that length of liquid column from the injection orifice is mainly controlled by the rotational speeds. SMD is decreased with increasing injection orifice diameter and rotational speeds. Furthermore, from the comparison to the theoritical calculation, we confirmed that SMD is influenced by the liquid film thickness which is formed inner surface of injection orifice.

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Studies on the Ternary Blends of Liquid Crystalline Polymer and Polyesters

  • Kim, Seong-Hun;Kang, Seong-Wook
    • Fibers and Polymers
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    • 제1권2호
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    • pp.83-91
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    • 2000
  • Thermotropic liquid crystalline polymer made up of poly(p-hydroxybenzoate) (PHB)-poly(ethylene terephthalate)(PET) 8/2 copolyester, poly(ethylene 2,6-naphthalate) (PEN) and PET were mechanically blended to pursue the liquid crystalline phase of ternary blends. Complex viscosities of blends decreased with increasing temperature and PHB content. DSC thermal analysis indicated that glass transition temperature (Tg) and melting temperature (Tm) of blends increased with increasing PHB content. Both tensile strength and initial modulus increased with raising PHB content and take-up speed of monofilaments. In the WAXS diagram, only PEN crystal reflection at 2Θ=$15.5^{\circ}C$ appeared but PET crystal reflection was not shown in all compositions. The degree of transesterification and randomness of blends increased with blending time but sequential length of both PEN and PET segment decreased.

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액상분사식 LPG엔진 인젝터의 후적 및 아이싱 특성에 관한 연구 (A Study of Droplets and Icing Characteristics on Injector in a Liquid Phase LPG Injection Engine)

  • 김창업;최교남;강건용;박철웅
    • 한국분무공학회지
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    • 제12권1호
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    • pp.38-44
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    • 2007
  • Since the Liquid Phase LPG injection (LPLI) system has Advantages in power generation and emission characteristics compared to the mixer-type fuel-supply system, a variety of studies regarding LPLi system has been conducted and its applications are made in automobile industry. However, the heat extraction due to the evaporation of liquid fuel, causes not only a post-accumulation of fuel but also an icing phenomenon which is a frost of moisture in the air around the nozzle tip. Since there exists a difficulty in the accurate control of air fuel ratio in both fuel supply systems, it can result in poor engine performance and a large amount of harmful emissions. This research examines the characteristics of icing phenomenon and develops anti-icing bushing to prevent an icing on the surface of the injection tip. It was found that n-butane, which has a relatively high boiling point ($-0.5^{\circ}C$), was a main species of post-accumulation. Also the results show that the post-accumulation problem was allevaited the utilization of a large inner to outer bore ratio and smooth surface roughness. In addition, an icing phenomenon and its formation process were found to be mainly affected by the humidity and the temperature of inlet air in an inlet duct. Also, it was observed that an icing phenomenon is lessened using aluminum bushing whose end coincides with the end of fuel injection tip in length.

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상 분리법을 이용한 Poly(L-lactic acid) Scaffold제조에 미치는 Pluronics의 영향 (Effect of Added Pluronics on fabrication of Poly(L-lactic acid) Scaffold via Thermally-Induced Phase Separation)

  • 김고은;김현도;이두성
    • 폴리머
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    • 제26권6호
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    • pp.821-828
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    • 2002
  • 미량의 Pluronics가 첨가된 PLLA/l,4-dioxane/water의 삼성분계상을 온도 변화로 유도된상 분리법을 이용하여 10~300 $\mu\textrm{m}$의 공극 크기를 가지며 공극 간의 연결성이 우수한 PLLA 다공성 지지체를 제조하였다. 순수한 PLLA 용액에 Pluronics를 첨가하면 상 분리 온도가 P-123< F-68< F-127 순서로 순차적으로 상승한다. 이는 Pluronics의 양 말단 사슬인 PEO의 영향으로 상분리 진행이 촉진되기 때문이다. 상 분리 온도의 상승으로 스피노달 영역을 증가시켜 높은 온도에서 상 분리 유도가 가능하게 된다. 또한 상 분리 진행 시간 동안에는 계면에 흡수된 Pluronics가 거대 구조를 안정화시켜 상 분리 진행 속도를 지연시키게 된다.

A Study on the Mixture Formation Process of Diesel Fuel Spray in Unsteady and Evaporative Field

  • Yeom, Jeong-Kuk;Park, Jong-Sang;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
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    • 제19권12호
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    • pp.2253-2262
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    • 2005
  • The focus of this work is placed on the analysis of the mixture formation mechanism under the evaporative diesel spray of impinging and free conditions. As an experimental parameter, ambient gas density was selected. Effects of density variation of ambient gas on liquid and vapor-phase inside structure of evaporation diesel spray were investigated. Ambient gas density was changed between ${\rho}a=5.0\;kg/m^3$ and $12.3\;kg/m^3$. In the case of impinging spray, the spray spreading to the radial direction is larger due to the decrease of drag force of ambient gas in the case of the low density than that of the high density. On the other hand, in the case of free spray, in accordance with the increase in the ambient gas density, the liquid-phase length is getting short due to the increase in drag force of ambient gas. In order to examine the homogeneity of mixture consisted of vapor-phase fuel and ambient gas in the spray, image analysis was conducted with statistical thermodynamics based on the non-dimensional entropy (S) method. In the case of application of entropy analysis to diesel spray, the entropy value always increases. The entropy of higher ambient density is higher than that of lower ambient gas density during initial injection period.

스월 동축형 분사기의 리세스 길이에 따른 혼합특성에 관한 수치적 연구 (A Numerical Study on Mixing Characteristics for Recess Length of Swirl Coaxial Injector)

  • 김영준;홍문근;이수용;손채훈
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2011년도 제37회 추계학술대회논문집
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    • pp.74-77
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    • 2011
  • 고성능 다단연소방식 액체 로켓엔진에 사용되는 기체 중심 스월 동축형 분사기의 리세스 길이 변화에 따른 혼합특성을 수치해석을 통해 연구를 수행하였다. 실제 추진제의 상(phase)은 기체(산화제)-액체(연료)형이지만, 모사조건을 통해 기체-기체로 고려하였다. 추진제의 확산각도를 측정하기 위해 분사기 출구에서의 속도 분포 및 추진제의 분무형상을 분석하였다. 리세스 길이가 증가함에 따라 축방향 속도는 증가하는 반면, 탄젠셜 방향 속도는 감소하였다. 이 결과 확산각도가 감소하는 정성적인 특징을 확인하였다.

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달걀 단백질 분석을 위한 HPLC 연구 (HPLC Study for Egg White Analysis)

  • 전영주;이은;김인호
    • KSBB Journal
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    • 제22권2호
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    • pp.119-122
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    • 2007
  • RP-HPLC에서 주요 변수인 이동상의 조성과 컬럼의 종류를 변화시켜 난백 단백질을 실험하였다. C4, C8 C18 컬럼을 비교 실험하여 C18 컬럼에서 가장 많은 피크를 보여 C18 컬럼을 선택하였다. 등용매 용리에서 ACN : water의 조성이 50 : 50에서 가장 많은 피크를 보여 이 결과를 토대로 기울기 용리를 하여 실험하였다. 기울기 용리에서 얻어진 4가지 피크를 확인하기 위하여 단일성분인 lysozyme와 ovalbumin의 체류시간을 측정하여 확인하였고 논문을 통해 2가지 피크를 예측할 수 있었다.