• 한국물환경학회지
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• 제34권3호
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• pp.316-327
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• 2018

Liquid fertilizers made from livestock manure contain high concentrations of nitrogen and phosphorus and thus are used as a fertilizer. However, excessive use of liquid fertilizer causes eutrophication of agricultural land and nonpoint source pollution. In this study, as a means of lowering the nutrient concentrations, struvite ($MgNH_4PO_4{\cdot}6H_2O$) production from the liquid fertilizer was investigated. When liquid fertilizers produced in Gyeonggido were analyzed, its characteristics differed by region and season, but the phosphorus concentration was commonly lower than that of nitrogen. When $K_2HPO_4$ and $MgCl_2$ were added to the liquid fertilizers, the optimal pH for struvite formation was pH 9.5. For environmentally friendly sources of magnesium and phosphate, ferronickel slag (FNS) and sewage sludge ash (SSA) were suspended in deionized water and extracted by sulfuric acid with various mass ratios. The optimum conditions for extracting FNS and SSA were 4.0 M sulfuric acid and 0.35 mass ratio of sulfuric acid to sewage sludge ash, respectively. For forming struvite, 0.233 L of SSA leachate (SSAL) was added into 0.3 L of liquid fertilizer containing 2,586 mg/L of ammonia and 110 mg/L of phosphate, pH was then adjusted to pH 9.5 using 10 M of NaOH. Afterwards 0.333 L of FNS leachate (FNSL) was added to this mixed solution. After a reaction for 1 hr at room temperature, the remaining concentrations of magnesium, ammonium, and phosphate were less than 50 mg/L, 500 mg/L and 150 mg/L, respectively, and 30 g of precipitates were obtained, most of which were struvite.

• 한국초지조사료학회지
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• 제20권1호
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• pp.55-60
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• 2000

This experiment was carried out to determine the effect of cutting frequency(3rd and 5th cut) and level of nitrogen fertilization(l50 + liquid manure, 300 and 450kgha) on growth characteristics, dry matter yield and nutritive vaule of reed canarygrass(Pha1aris arundinacea L.), at the forage experimental field, College of Agriculture and Life Sciences, SNU, Suweon. Plant height of 3rd cutting(79.2cm) was significantly higher than that of 5th cutting(58.0cm). And dry mattter yield of cutting frequency was observed in 3rd cutting(16,902kgPna) and 5th cutting(l7,833kg/ha) As the nitrogen fertilization was increased, DM yield was significantly increased(p<0.05). When the nitrogen fertilization was applied at the level 150 + liquid manure, 300 and 450kg, dry matter yields were 16,5 12, 17,123 and 18,368kg/ha, respectively. The contents of neutral detergent fiber(NDF), acid detergent fiber(ADF) and in vitro dry matter digestibility(1VDMD) were similar among cutting frequency. However, slightly higher NDF, ADF and IVDMD contents were found in 5th cutting, but there was not affected by nitrigen fertilization. Based on the results of this experiment, it were indicated that to 5th cutting and 450kg nitrogen fertilization could be obtained from the increase of dry matter yield and nutritive value (Key words : Cutting frequency, Nitrogen fertilization, Dry matter yield, Nutritive Value, Reed canarygrass)

• 유기물자원화
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• 제9권4호
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• pp.111-116
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• 2001

남은 음식물에 대한 재활용 방안으로 이용되고 있는 혐기발효공법을 통해 음식물은 가스와 발효액로 분해된다. 본 연구는 발효액을 이용할 목적으로 질소기준으로 시용량과 추비의 분시를 달리하여 작물의 생육과 토양변화를 조사하기 수행되었다. 0.52%를 함유하고 있는 발효액은 처리구의 시용량에 적합하게 처리되었고 처리구는 화학비료를 시비한 대조구, 추비과정에서 발효액을 질소기준으로 추천시비량의 50, 100(4일 간격, 6회), 100%(8일 간격, 3회)를 시용한 발효액 처리구를 두었다. 발효액에는 염류 성분과 수용성 유기물질이 많이 함유되어 있어 높은 EC값을 보였다. 시험 전 후 토양의 화학성 변화는 크지 않았으나 EC와 치환성 Ca 함량이 높아졌다. 8차 까지 수확한 결과 발효액 처리구의 수확량이 대조구보다 우세하였으나 발효액 처리구간에 차이는 거의 없었다. 이는 현재 사용하고 있는 질소의 시비량을 발효액으로 대치할 경우 50% 감소가 가능할 것으로 판단된다.

• 공업화학
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• 제25권3호
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• pp.292-299
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• 2014

본 연구에서는 바나듐 레독스 흐름전지의 효율을 향상시키고자 탄소펠트에 열산화 반응과 암모니아수 처리를 이용하여 질소가 도핑된 탄소펠트 전극을 제조하였다. 또한 제조된 탄소펠트 전극의 전기화학적 특성평가를 위하여 CV 실험 및 충/방전 실험을 실시하였다. 암모니아수 처리온도가 증가함에 따라 탄소펠트 표면의 질소 관능기가 증가함을 XPS를 통하여 확인하였으며, CV 측정 결과 암모니아수 처리된 탄소펠트는 열산화된 탄소펠트에 비하여 산화/환원의 반응성이 우수함을 확인하였다. 충/방전 실험결과 $300^{\circ}C$에서 암모니아수 처리한 탄소펠트 전극은 열산화된 탄소펠트 전극보다 에너지효율, 전압효율, 전류효율이 각각 약 6.93, 1.0, 4.5%씩 향상됨을 알 수 있었다. 이는 질소 관능기가 탄소펠트 전극과 전해질 사이의 전기화학적 성능 향상에 도움을 주었기 때문으로 사료된다.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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• pp.7-11
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• 1999

The recent progress in new cooling techniques of the high Tc superconductor(HTS) systems is reported and discussed with some practical examples. At the beginning stage of the HTS development in research laboratories, liquid nitrogen(LN$_2$) is the standard medium for an effective cooling. The success of HTS in many different application areas, however, has required a variety of need in the cooling temperature and the cooling capacity with specific design restrictions. While the utilization of alternative liquid cryogens such as liquid neon (LNe) or liquid hydrogen (LH$_2$) has been tired in some of them, even solid cryogens such as solid nitrogen (SN$_2$) or solid hydrogen (SH$_2$) may be another option in special applications. The gaseous helium cooled by a cryogenic refrigerator has also been a good candidate in many cases. One of the best cooling methods for the HTS is the direct conduction-cooling by a closed-cycle refrigerator with no cryogen at all. The refrigeration may be based on Joul-Thomson, Brayton, Stirling, Gifford-McMahon, or pulse tube cycles. The pros and cons of the newly proposed cooling methods are described and some significant design issues are presented.

• International Journal of Fluid Machinery and Systems
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• 제3권4호
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• pp.324-331
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• 2010

Cavitation in cryogenic fluids generates substantial thermal effects and strong variations in fluid properties, which in turn alter the cavity characteristics. In order to investigate the cavitation characteristics in cryogenic fluids, numerical simulations are conducted around an axisymmetric ogive in liquid nitrogen and hydrogen respectively. The modified Merkle cavitation model and energy equation which accounts for the influence of cavitation are used, and variable thermal properties of the fluid are updated with software. A good agreement between the numerical results and experimental data are obtained. The results show that vapor production in cavitation extracts the latent heat of evaporation from the surrounding liquid, which decreases the local temperature, and hence the local vapor pressure in the vicinity of cavity becomes lower. The cavitation characteristics in cryogenic fluids are obtained that the cavity seems frothy and the cavitation intense is lower. It is also found that when the fluid is operating close to its critical temperature, thermal effects of cavitation are more obviously in cryogenic fluids. The thermal effect on cavitation in liquid hydrogen is more distinctively compared with that in liquid nitrogen due to the changes of density ratio, vapour pressure gradient and other variable properties of the fluid.

• 센서학회지
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• 제25권1호
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• pp.65-70
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• 2016

We devised a method to control the temperature of a liquid bath as low as $-100^{\circ}C$ using the duty cycle control of a solenoid valve. The solenoid valve controls the flow of liquid nitrogen that we used as a cryogen in this system. By controlling the duty cycle of a solenoid valve using feedback from the measured temperature of the liquid bath, we were able to achieve temperature stability within ${\pm}19mK$ around $-100^{\circ}C$. We also demonstrated that by taking average values of the temperature readings for sequence of measurements from more than one thermometer, it is possible to use this system for the calibration of thermometers within 3 mK. This system and the control method can be used for the precise temperature control in the range between $0^{\circ}C$ and $-100^{\circ}C$, where commercially available precision baths are much expensive and hard to be built in customized configurations.

• 콘크리트학회지
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• 제9권2호
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• pp.57-62
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• 1997

• 대한기계학회논문집B
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• 제34권4호
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• pp.391-397
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• 2010

액체질소를 작동유체로 한 극저온 시험설비를 이용하여 산화제펌프의 성능시험을 수행하였다. 설계회전수의 30~55%영역에서 시험을 수행하였으며, 그 결과를 작동유체로 물을 이용한 상온수류시험의 결과와 비교/분석하였다. 수력성능에 있어서는 회전수에 대한 상사성을 만족시킴으로써, 설계회전수인 20000rpm에서의 성능예측을 가능하게 했다. 펌프의 극저온 흡입성능에서는 설계유량에서 극저온 임계 캐비테이션 수가 0.012으로 나타났으며, 상온수류시험의 경우는 0.024를 보이면서, 모든 시험회전수와 시험유량영역에서 수류시험의 경우보다 향상된 결과를 보였다. 이러한 향상된 극저온 환경에서의 흡입성능은 극저온 유체에서 펌프의 열역학적인 효과로부터 기인하는 것으로 판단된다.

• 항공우주시스템공학회지
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• 제13권6호
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• pp.9-16
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• 2019

초음속 유동이 흐르는 후향 계단에서 액체 제트가 수직으로 분사되는 유동의 혼합 특성에 대한 실험적 연구를 수행하였다. 작동 유체는 질소와 물을 사용하였다. 쉐도우그래프 기법을 사용하여 유동을 가시화하였으며, 초고속 카메라로 촬영된 영상은 시간 평균화 처리를 통해 분석에 사용하였다. 액체 제트의 주입구는 초음속 질소가스 유동에 의해 생성되는 재순환 영역 내부에 위치하며 유동방향에 수직하게 분사된다. 실험 조건은 질소가스 챔버와 액체 가압탱크의 압력에 따라 나누었다. 각 실험 조건에서 분사된 액체 제트의 침투 깊이와 마하 디스크의 생성 위치의 변화를 관찰하였으며, 운동량비에 따른 유동의 구조 변화에 대해 고찰하였다.