• Bulletin of the Korean Chemical Society
• /
• v.31 no.11
• /
• pp.3190-3194
• /
• 2010

Mixed electrolytes formed by the combination of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (BMP-TFSI) ionic liquid and standard liquid electrolyte are prepared and characterized. Linear sweep voltammetry measurements demonstrate that these mixed systems exhibit a wide electrochemical stability window, allowing them to be suitable electrolyte for carbonaceous anode-based lithium-ion batteries. Lithium-ion cells composed of graphite anode and $LiCoO_2$ cathode are assembled using the mixed electrolytes, and their cycling performances are evaluated. The cell containing proper content of BMP-TFSI shows good cycling performance comparable to that of a cell assembled with organic electrolyte. The presence of BMP-TFSI in the mixed electrolyte contributes to the reduction of the flammability of electrolyte solution and the improvement of the thermal stability of charged $Li_{1-x}CoO_2$ in the electrolyte solution.

• Carbon letters
• /
• v.15 no.3
• /
• pp.187-191
• /
• 2014

This study reports on the influence of N-butyl-N-methylpyrrolidinium tetrafluoroborate ($PYR_{14}BF_4$) ionic liquid additive on the conducting and interfacial properties of organic solvent based electrolytes against a carbon electrode. We used the mixture of ethylene carbonate/dimethoxyethane (1:1) as an organic solvent electrolyte and tetraethylammonium tetrafluoroborate ($TEABF_4$) as a common salt. Using the $PYR_{14}BF$ ionic liquid as additive produced higher ionic conductivity in the electrolyte and lower interface resistance between carbon and electrolyte, resulting in improved capacitance. The chemical and electrochemical stability of the electrolyte was measured by ionic conductivity meter and linear sweep voltammetry. The electrochemical analysis between electrolyte and carbon electrode was examined by cyclic voltammetry and electrochemical impedance spectroscopy.

• Journal of the Korean Applied Science and Technology
• /
• v.37 no.6
• /
• pp.1591-1596
• /
• 2020

The solid-state electrolyte based on polymer has great attention to develop its ionic conductivity from conventional polymer electrolyte by using wide range of ionic liquids with remarkable processability, flexibility and is applicable to various electrochemical devices including batteries, supercapacitor. Polymer electrolyte based on Ionic liquid with high conductivity, wide electrochemical stability, thermal stability is used in various electronic devices. In this work, we have investigated and developed solid-state electrolyte based on ionic liquid and polymer with enhanced ionic conductivity and electrochemical performances to conduct to various electronic devices including secondary battery. The ionic conductivity of polymer based solid state electrolyte with optimized ratio of the ionic liquid was 1.46-2 S/cm. The ionic liquid and polymer based electrolyte with enhanced ionic conductivity is promising candidates to utilize in wide range of secondary batteries.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.23 no.2
• /
• pp.168-174
• /
• 2009

In this paper Gel polymer electrolyte using Poly(Vdf-HFP) was fabricated and compared with liquid type electrolyte. The chemical structure and ingredients of fabricated gel electrolyte was investigated and identified to gel polymer electrolyte by FTIR, gel electrolyte was verified to polymer state by SEM From the experiment result, the better component ratio of Propylene carbonate and Diethyl carbonate for gel type electrolyte was 5 : 5. The conversion efficiency of fabricated DSCs using gel electrolyte was $3{\sim}4[%]$, expected to alternate with liquid type electrolyte.

• Korean Journal of Materials Research
• /
• v.29 no.2
• /
• pp.121-128
• /
• 2019

Supercapacitors are attracting much attention in sensor, military and space applications due to their excellent thermal stability and non-explosion. The ionic liquid is more thermally stable than other electrolytes and can be used as a high temperature electrolyte, but it is not easy to realize a high temperature energy device because the separator shrinks at high temperature. Here, we report a study on electrochemical supercapacitors using a composite electrolyte film that does not require a separator. The composite electrolyte is composed of thermoplastic polyurethane, ionic liquid and fumed silica nanoparticles, and it acts as a separator as well as an electrolyte. The silica nanoparticles at the optimum mass concentration of 4wt% increase the ionic conductivity of the composite electrolyte and shows a low interfacial resistance. The 5 wt% polyurethane in the composite electrolyte exhibits excellent electrochemical properties. At $175^{\circ}C$, the capacitance of the supercapacitor using our free standing composite electrolyte is 220 F/g, which is 25 times higher than that at room temperature. This study has many potential applications in the electrolyte of next generation energy storage devices.

• Bulletin of the Korean Chemical Society
• /
• v.29 no.4
• /
• pp.731-735
• /
• 2008

The fluid ensemble in the liquid lens, which is composed of electrolyte and silicone oil, is the key material system to vary the focal length processing of the electrochemical desorption. In order to characterize the capability of the liquid lens according to response time and optical range, we prepared a fluid ensemble comprising the electrolyte and oil. To elucidate the physical mechanism of the effective response time, we examined the viscosity dependency while satisfying the requirements for the density and refractive index of the electrolyte and oil, respectively. The characterization results indicated that the response time (up and down) is influenced by the viscosity of the electrolyte and oil. On this basis, we prepared a fluid ensemble capable of reversibly adjusting for the focal length of the liquid lens, as well as the response time. The ensemble is applicable to various systems such as micro-lens and optical sensors.

• Macromolecular Research
• /
• v.16 no.2
• /
• pp.134-138
• /
• 2008

A novel acrylol borate was designed and synthesized by reacting acrylate monomer and boric acid. The obtained acrylol borate was used as both gelator and anion receptor for the liquid electrolyte in a lithium secondary battery. It was found that the ionic conductivity of the gel polymer electrolyte (GPE) was as high as that of the liquid electrolyte, and the thermal stability of GPE was increased when only 2 wt% acrylol borate was incorporated into the liquid electrolyte. These results suggest that acrylol borate can be used as an effective additive to enhance the thermal stability of the electrolyte without adversely affecting its conductivity. It is believed that the strong complex formation between boron in the gelator and the anion of the salt is responsible for the enhanced thermal stability of the electrolyte solution and the increased ionic conductivity.

• Journal of Information Display
• /
• v.11 no.2
• /
• pp.84-90
• /
• 2010

This paper presents the effects of a dielectric layer and an electrolyte on the driving performance of an electrowetting on dielectric (EWOD)-based liquid lens. The range of tunable focal length of the EWOD-based liquid lens was highly dependent on the conditions of the dielectric layer, which included an inorganic oxide layer and an organic hydrophobic layer. Moreover, experiments on the physical and optical durability of electrolyte by varying temperature conditions, were conducted and their results were discussed. Finally, the lens with a truncated-pyramid silicon cavity having a sidewall dielectrics and electrode was fabricated by anisotropic etching and other micro-electromechanical systems (MEMS) technologies in order to demonstrate its performance. The lens with $0.6-{\mu}m$-thick $SiO_2$ layer and 10 wt% LiCl-electrolyte exhibited brilliant focal-length tunability from infinity to 3.19 mm.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.5
• /
• pp.1480-1484
• /
• 2012

We report a series of novel imidazolium iodides based ionic liquids (NMIPHI, NAIPHI, and NBIPHI) with different functional groups for the development of a quasi-solid type electrolyte for dye-sensitized solar cells (DSSCs). The diffusion coefficients of redox ions ($I^-$ and $I_3{^-}$) are dependent on the molecular weight and it was higher for lighter salts. Among the three ionic liquids, NMIPHI showed highest efficiency of 4.18% when it was used in a liquid electrolyte of a DSSC with $ca$. 6 ${\mu}m$ thick $TiO_2$ mesoporous film. Even though the efficiency was $ca$. 19% lower than that obtained from a liquid electrolyte composed of PMII. When NMIPHI was mixed with PMII with a molar ratio of 1:1 in a solvent free electrolyte, the efficiency of the DSSCs was enhanced compared to that based on pristine PMII.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.382-382
• /
• 2009

In this study, we prepared electrodes containing ionic liquid for high temperature polymer electrolyte fuel cells. Effects of ILs on electrochemical properties of the electrodes were investigated carrying out measurement of cyclic voltammograms of the various electrodes with the content of IL in a strong supporting electrolyte. As the ILs content increased in electrodes, electrochemical surface area(ESA) decreased due to the leakage of ILs from Nafion ionomer. In addition, two case of cyclic voltammograms under two simulated environment, i.e. IL leakage from Nafion ionomer in I) electrode and ii) polymer electrolyte, were investigated. As a result, IL leakage from polymer electrolyte showed worse results in electrochemical properties of the electrode.