• Title/Summary/Keyword: Liquid Crystals

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No-bias-bend pi cell using the rubbed polyimide mixture

  • Kim, Dae-Hyeon;Park, Hong-Gyu;Kim, Yeong-Hwan;Kim, Byeong-Yong;Ok, Cheol-Ho;Han, Jeong-Min;Seo, Dae-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.186-186
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    • 2009
  • Most liquid crystal display modes, including the twisted nematic (TN) $mode^1$, the in-plane switching (IPS) $mode^2$, the fringe field switching (FFS) $mode^3$, and the vertically aligned (VA) $mode^4$ are based on either a horizontal or a vertical alignment. However, for some applications, such as no-bias-bend (NBB) pi cell or bistable bend-splay display, an intermediate pretilt angle is essential$^5$. NBB pi cells have been a focus of interest because of their fast response time; however, the reliable control of the intermediate pretilt angle of liquid crystals that is required for the fabrication of NBB pi cells is challenging. The controllable pre-tilt angle of liquid crystals was investigated using a blend of horizontal and vertical polyimide prepared by a rubbing method. Various pretilt angles in the range from 0^{\circ}$ to 90^{\circ}$ were achieved as a function of the vertical polyimide content. We observed uniform liquid crystal alignment on the rubbing-treated blended polyimide layer. A NBB pi cell with an intermediate pretilt angle of 47.8^{\circ}$ was manufactured. This cell had no initial bias voltage and a low threshold voltage, which indicates that it has low power consumption. In addition, the response time of the NBB pi cell was rapid.

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Non-Newtonian Flow Mechanism for Thixotropic and Dilatant Flow Units of Sodium bis-(2-ethylhexyl)sulfosuccinate-water Micelles (Sodium bis-(2-ethylhexyl)sulfosuccinate-water 미셀의 틱소트로 피와 다일레턴시 유동단위에 대한 비뉴톤 유동메카니즘)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.540-548
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    • 2016
  • The non-Newtonian flow curves of sodium bis-(2-ethylhexyl)sulfosuccinate-water lamellar liquid crystals were obtained in various concentrations and temperatures by using a cone-plate rheometer. By applying non-Newtonian flow equation to the flow curves for AOT-water lamellar liquid crystal samples, the rheological parameters were obtained. Particular attention is given to the hysteresis loop detected when the liquid crystal samples are shear under increasing-decreasing shear stress modes which result in thixotropic and dilatant behavior. Sodium bis-(2-ethylhexyl)sulfosuccinate-water lamellar liquid crystals behave as weak gels when they are subjected to shear flow, but when the applied stress surpasses the yield stress, they exhibit non-linear viscoelasticity. Upon decreasing shear rate, the dispersion still preserves much of its structure and consequently its shear stress remains higher than the values measured in the increasing shear rate mode.

Synthesis and Photopolymerization of Discotic Liquid Crystals Containing Hydrogen Bondings and Two Polymerizable Groups (두 종류의 중합기와 수소결합을 가지는 원반형 액정의 합성과 광중합)

  • Lee Jun-Hyup;Lee Seung-Jun;Jang Ji-Sun;Jho Jae-Young
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.373-379
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    • 2006
  • Polymerizable discotic liquid crystals containing diacetylene and acryloyl groups were formed through hydrogen bonding between phloroglucinol core and polymerizable pyridine derivatives, and their photopolymerization behavior was investigated. The discotic complexes exhibited discotic columnar and rectangular columnar mesophases depending on the number of aromatic rings. Photopolymerization of the discotic complexes was carried out by UV irradiation in the liquid crystalline state. IR and UV-Vis spectroscopy affirmed that diacetylene and acryloyl groups were selectively Polymerized, and that crosslinked polymers containing short conjugated diacetylene oligomers were produced by 1,4-addition. X-ray diffraction experiment showed that the columnar order in the discotic complex containing phenyl-pyridine moiety was maintained after photopolymerization, and that the rectangular columnar order in he discotic Complex with biphenyl units was changed to the lamellar order.

Effect of Residual Droplet on the Solution-Grown SiC Single Crystals (상부종자 용액 성장에 있어 성장결정상 잔류액적의 영향)

  • Ha, Minh-Tan;Shin, Yun-Ji;Bae, Si-Young;Yoo, Yong-Jae;Jeong, Seong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.516-521
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    • 2019
  • The top seeded solution growth (TSSG) method is an alternative technique to grow high-quality SiC crystals that has been actively studied for the last two decades. However, the TSSG method has different issues that need to be resolved when compared to the commercial SiC crystal growing method, i.e., physical vapor transport (PVT). A particular issue of the TSSG method of results from the presence of liquid droplets on the grown crystal that can remain even after crystal growth; this induces residual stress on the crystal surface. Hence, the residual droplet causes several unwanted effects on the crystal such as the initiation of micro-cracks, micro-pipes, and polytype inclusions. Therefore, this study investigated the formation of the residual droplet through multiphysics simulations and lead to the development of a liquid droplet removal method. As a result, we found that although residual liquid droplets significantly apply residual stress on the grown crystal, these could be vaporized by adopting thermal annealing processes after the relevant crystal growing steps.

Electro-Optical Characterization of Polymer Dispersed Liquid Crystals for Various Concentrations of Prepolymer (전폴리머 조성에 따른 고분자 분산형 액정의 전기 광학 특성 평가)

  • Yang, Kee-Jeong;Yoon, Do-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.11
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    • pp.891-895
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    • 2010
  • Polymer dispersed liquid crystal (PDLC) films were prepared by the phase separation method using the liquid crystal (E7) and prepolymers. This work investigated the electro-optical characteristics of various PDLC films. In order to have good contrast ratio, the polymer refractive index must be adjusted to the ordinary refractive index of the liquid crystal. The driving voltage of PDLC films were mainly affected by elastic deformation. E7-Ebecryl810-IOA-TMPTA-HMPPO system had good threshold voltage and driving voltage and E7-Ebecryl810-EHA-PEGDA-HMPPO system had good contrast ratio.

Reflective Variable Optical Attenuator using Liquid Crystals (액정을 이용한 반사형 가변 광 감쇠기)

  • Lee, Yong-Min
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.2
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    • pp.15-18
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    • 2014
  • This work studies a variable optical attenuator using a reflective type liquid crystal cell for optical switches. The proposed architecture is capable of comprising a compact and low voltage driving variable optical attenuator. The usefulness of the proposed architecture is demonstrated by showing characterization of the liquid crystal cell, temperature effects, and response characteristics of the architecture.

Fast Response Characteristics in Liquid Crystal Display using Operating Mode of the Nematic Liquid Crystal (네마틱 액정 동작 모드를 이용한 액정소자의 고속 응답 특성)

  • Bae, Yu-Han;Hwang, Jeoung-Yeon;Kim, Kang-Woo;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.206-209
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    • 2004
  • We investigated response characteristics of liquid crystal display(LCD) with different operating mode of nematic liquid crystals (NLCs) such as $45^{\circ}$twist nematic (TN), $67.3^{\circ}$TN and ECB(electrical controlled birefringence) on a rubbed polyimide (PI) surface. The three kinds of LCD operating mode obtain stable EO performance. Low transmittances of the $45^{\circ}$TN and $67.3^{\circ}$TN cell on the rubbed PI surface were achieved by using low cell gap d. The fast response time of ECB cell among the three kinds of LCD operating mode was measured.

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Imaging the Enzymatic Reaction of Urease Using Liquid Crystal-Based pH Sensor

  • Hu, Qiong-Zheng;Jang, Chang-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4377-4381
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    • 2011
  • In this study, real-time and label-free methods for monitoring the enzymatic reaction of urease, which releases ammonia through the hydrolysis of urea in an aqueous solution, were developed using a liquid crystal (LC)-based pH sensor. Nematic liquid crystal 4-cyano-4'-pentylbiphenyl (5CB), doped with 4'-pentyl-biphenyl-4-carboxylic acid (PBA), exhibited a shift in optical appearance from bright to dark when it was in contact with ammonia generated from the enzymatic reaction between urease and urea. This optical change was attributed to the anchoring transitions of LCs caused by hydrophobic interactions between the tails of deprotonted PBA ($PBA^-$) molecules and the LCs at the aqueous/LC interface. This novel technique holds great promise for the sensitive detection of urease along with its substrates and inhibitors.