• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.90-90
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• 2006

Mesogen-Jacketed Liquid Crystalline Polymers, MJLCPs, are polymers with mesogenic side groups directly attached to main-chains without using flexible connecting spacers and are able to form liquid crystalline structures. Later work on structure-property of the polymers revealed that the side groups are not necessarily mesogenic for the polymers to form a mesophase so long as that the side groups are directly attached to the backbones and the side groups are large enough. Because of its inherent chain stiffness and that the monomers of MJLCPs are readily polymerizable by "living" free radical polymerizations, MJLCP offered a unique handy tool for making block copolymers. In addition, MJLCP offered also new opportunities for novel functional materials.

• 대한기계학회논문집A
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• 제24권7호
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• pp.1703-1711
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• 2000

Microstructural morphology of molded composites of thermotropic liquid crystalline polymer(LCP) and polyamide 6 (PA6) has been studied as a function of epoxy fraction. Injection-moulding of a thin composite plaque at a temperature below the melting point of the LCP fibrils by suing the extruded LCP/PA6 pellets produced multi-layered structures: 1) the surface skin layer with thickness of 65-120 ym exhibiting a transverse orientation, 2) the sub-skin layer with an orientation perpendicular to the surface skin, i.e. in the flow direction, 3) the core layer with arc-curved flow patterns. Similar microstructural orientations were observed in the respective layers for the composite plaques with different fractions of epoxy.

• Composites Research
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• 제33권1호
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• pp.25-29
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• 2020

Diglycidyl ether of 4,4'-biphenol을 기지로 사용하고, tin(IV) oxide를 filler로, sulfanilamide를 경화제로 사용하여 액정성 열경화성 에폭시 기반 복합재료를 제작하였다. TGA와 LFA를 이용하여 3.0-7.0 wt%의 tin(IV) oxide를 분산시켜 제작한 복합재료의 열적 거동을 조사한 결과, 열분해 활성화 에너지와 열전도성이 filler의 첨가량에 비례하는 것으로 나타났다.

• 한국자기공명학회논문지
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• 제15권1호
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• pp.14-24
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• 2011

We have performed Liquid Chromatography-Solid Phase Extraction-NMR (LC-SPE-NMR) analysis for liquid crystalline mixture and elucidated the structures of selected components by NMR spectra. Combining the results of one-dimensional 1H experiments as well as homonuclear and heteronuclear two-dimensional experiments, we could analyze the molecular structure of the liquid crystal singles whose structure had not been interpretable by mass spectrometry alone.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.571-574
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• 2003

Three ring type liquid crystalline compounds having 4-alklycyclohexyl group, 1,2-difluorobenzene and phenylisothiocyanate moieties as main skeleton were designed to have negative dielectricity. However, the compounds with 2,3,2'-trifluoro-3'-isothiocyanated biphenylcyclohexane core did not exhibit the nematic liquid crystalline phase because of two conformers by interaction of isothiocyanate and adjacent fluorine atoms. Also, 4-alkyl-2,2',3'-trifluoro-3-isothiocyanated biphenylcyclohexane core was designed expecting to have uniform conformers of isothiocyanate group. In the course of developing polyimides for VA mode LCD, we synthesized alkyl-3,5-diaminobenzene efficiently with various length of alkyl chains from commercially available di-t-butyl malonate and 3,5-dinitrobenzoyl chloride as starting material.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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• pp.471-474
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• 2002

Three-ring types liquid crystalline compounds having fluoro and isothiocyanate substituent were synthesized and their physical and electro-optical properties were measured to evaluate the applications to active matrix VA liquid crystal displays. The tetrakis(triphenylphosphine)palladium(0) catalyzed cross coupling of aryl boronic acids with aryl halides is used to prepare trans-4'-Alkoxy-2,3-difluoro-3'-isothiocyanato-4-(4-alkylcyclohexyl}-biphenyl series. The synthesized compounds showed the nematic liquid crystalline phase and the negative dielectric anisotropy. The prepared mixtures showed faster response time and lower threshold voltage than their host mixture.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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• pp.433-435
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• 2005

We have studied the realigning behavior of liquid crystal molecules in liquid crystalline polymer/liquid crystal(LCP/LC) system when they are exposed to external stimulation such as bending and pressing. The birefringence of the LCP/LC in a flexible display device was measured as a function of bending or pressing deformation. The microscopic dynamic behavior of main chain, side chain, and the LC were characterized by FTIR and polarization optical microscopy. When the device is deformed in scattering memory state, liquid crystal(LC) director is found to align from randomly oriented domain state(scattering state) to homeotropic state.

• Bulletin of the Korean Chemical Society
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• 제32권10호
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• pp.3571-3574
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• 2011

Nano-scaled metal oxides have been attractive materials for sensors, photocatalysis, and dye-sensitization for solar cells. We report the controlled synthesis and characterization of single crystalline $TiO_2$ nanowires via a catalyst-assisted vapor-liquid-solid (VLS) and vapor-solid (VS) growth mechanism during TiO powder evaporation. Scanning electron microscope (SEM) and transmission electron microscope (TEM) studies show that as grown $TiO_2$ materials are one-dimensional (1D) nano-structures with a single crystalline rutile phase. Also, energy-dispersive X-ray (EDX) spectroscopy indicates the presence of both Ti and O with a Ti/O atomic ratio of 1 to 2. Various morphologies of single crystalline $TiO_2$ nano-structures are realized by controlling the growth temperature and flow rate of carrier gas. Large amount of reactant evaporated at high temperature and high flow rate is crucial to the morphology change of $TiO_2$ nanowire.

• Macromolecular Research
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• 제13권2호
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• pp.81-87
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• 2005

Blends of silicone rubber (VMQ) and liquid crystalline polymer (LCP) were prepared by the melt mixing technique. Mechanical, XRD, thermal and dynamic mechanical investigations are reported for the pure silicone rubber and blends. The mechanical properties, viz. the tensile strength, tear strength and elongation at break, of the silicone rubber decreased with the addition of LCP. The SEM study on the tensile fractured surface of the blends revealed that they had a two phase structure, and that the failure was mainly due to fiber pull out, which suggests that the VMQ and LCP are incompatible in all of the proportions examined in this study. However, the FTIR study shows that there was a partial interaction between the VMQ and LCP, but which may not be sufficient to grip the fibrils under the applied load. In the XRD analysis, it was observed that the crystalline structure of the silicone rubber deteriorated in the presence of LCP. The DMA study suggested that the storage modulus of the silicone rubber was improved with the addition of LCP, due to the high modulus of the LCP phase. The thermal stability of the silicone rubber was greatly reduced by the addition of LCP, due to the latter having a thermal stability lower than that of silicone rubber.

• Bulletin of the Korean Chemical Society
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• 제28권2호
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• pp.299-302
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• 2007