• Title/Summary/Keyword: Liquid Conductivity

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Improved Conversion Efficiency of Dye-sensitized Solar Cells Based on TiO2 Porous Layer Coated TiO2 Nanotubes on a Titanium Mesh Substrate as Photoanode

  • Lim, Jae-Min;He, Weizhen;Kim, Hyung-Kook;Hwang, Yoon-Hwae
    • Current Photovoltaic Research
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    • v.1 no.2
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    • pp.90-96
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    • 2013
  • We report here flexible dye-sensitized solar cells (DSSC) based on Ti-mesh electrodes that show good mechanical flexibility and electrical conductivity. $TiO_2$ nanotube arrays prepared by electrochemical anodizing Ti-mesh substrate were used as photoanode. A Pt-coated Ti-mesh substrate was used as counter electrode. The photoanodes were modified by coating a $TiO_2$ porous layer onto the $TiO_2$ nanotubes in order to increase the specific surface area. To increase the long term stability of the DSSCs, a gel type electrolyte was used instead of a conventional liquid type electrolyte. The DSSC based on $33.2{\mu}m$ long porous $TiO_2$ nanotubes exhibited a better energy conversion efficiency of ~2.33%, which was higher than that of the DSSCs based on non-porous $TiO_2$ nanotubes.

Measurement of an Ion Concentration in Drinking Water by lon Chromatography (Ion Chromatography에 의한 음료수중 음이온 함량에 관한 연구)

  • Kim Hyung-Suk
    • Journal of environmental and Sanitary engineering
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    • v.4 no.1 s.6
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    • pp.7-15
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    • 1989
  • According to the increase of population and development of industrialization air and water pollution problems are still keeping going to great nuisance to human activities. Specially man should drink 2l clean water to maintain our health every day, but we afraid of drink the city tap water because of the contaminants like heavy metals, bacteria trihalomethane, etc. In the analysis of the anions in potable water, we usually adapt the Standard methods for the Examination of Water and Wastewater. But this method is tedious and time consuming, so the Ion Chromatography method is now used in research of water quality. Author worked with Ion Chromatography in measuring the anions in drinking water by attaching conductivity dector to normal High Performance Liquid Chromatograph. Low-capacity ion-exchange coulmn and dilute eluents, 0.00M phthalic aic was used in this study. The concentration of chloride ion was 1.55 ppm$\~$3 8.81ppm, nitrate ion was 5.45 ppm$\~$18.27ppm, and sulfate ion was 19.64 ppm$\~$28.86 ppm. The phosphate ion was detected only in Apt. tap water as 167.99 ppm whose amount was supposed to be used as a water pipe cleaner.

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Femtosecond laser pattering of ITO film on flexible substrate (펨토초 레이저를 이용한 플렉시블 ITO 패터닝 연구)

  • Sohn, Ik-Bu;Kim, Young-Seop;Noh, Young-Chul
    • Laser Solutions
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    • v.13 no.1
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    • pp.11-15
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    • 2010
  • Indium tin oxide (ITO) provides high electrical conductivity and transparency in the visible and near IR (infrared) wavelengths. Thus, it is widely used as a transparent electrode for the fabrication of liquid crystal displays (LCDs) and organic light emitting diode displays (OLRDs), photovoltaic devices, and other optical applications. Lasers have been used for removing coating on polymer substrate for flexible display and electronic industry. In selective removal of ITO layer, laser wavelength, pulse energy, scan speed, and the repetition rate of pulses determine conditions, which are efficient for removal of ITO coating without affecting properties of the polymer substrate. ITO coating removal with a laser is more environmentally friendly than other conventional etching methods. In this paper, pattering of ITO film from polymer substrates is described. The Yb:KGW femtosecond laser processing system with a pulse duration of 250fs, a wavelength of 1030nm and a repetition rate of 100kHz was used for removing ITO coating in air. We can remove the ITO coating using a scanner system with various pulse energies and scan speeds. We observed that the amount of debris is minimal through an optical and a confocal microscope, and femtosecond laser pulses with 1030nm wavelength are effective to remove ITO coating without the polymer substrate ablation.

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A REVIEW OF INHERENT SAFETY CHARACTERISTICS OF METAL ALLOY SODIUM-COOLED FAST REACTOR FUEL AGAINST POSTULATED ACCIDENTS

  • SOFU, TANJU
    • Nuclear Engineering and Technology
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    • v.47 no.3
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    • pp.227-239
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    • 2015
  • The thermal, mechanical, and neutronic performance of the metal alloy fast reactor fuel design complements the safety advantages of the liquid metal cooling and the pool-type primary system. Together, these features provide large safety margins in both normal operating modes and for a wide range of postulated accidents. In particular, they maximize the measures of safety associated with inherent reactor response to unprotected, doublefault accidents, and to minimize risk to the public and plant investment. High thermal conductivity and high gap conductance play the most significant role in safety advantages of the metallic fuel, resulting in a flatter radial temperature profile within the pin and much lower normal operation and transient temperatures in comparison to oxide fuel. Despite the big difference in melting point, both oxide and metal fuels have a relatively similar margin to melting during postulated accidents. When the metal fuel cladding fails, it typically occurs below the coolant boiling point and the damaged fuel pins remain coolable. Metal fuel is compatible with sodium coolant, eliminating the potential of energetic fuel-coolant reactions and flow blockages. All these, and the low retained heat leading to a longer grace period for operator action, are significant contributing factors to the inherently benign response of metallic fuel to postulated accidents. This paper summarizes the past analytical and experimental results obtained in past sodium-cooled fast reactor safety programs in the United States, and presents an overview of fuel safety performance as observed in laboratory and in-pile tests.

Transport Properties of Lennard-Jones Mixtures: A Molecular Dynamics Simulation Study

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.641-646
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    • 2008
  • Equilibrium molecular dynamics simulations in a canonical ensemble are performed to evaluate the transport coefficients of several Lennard-Jones (LJ) mixtures at a liquid argon states of 94.4 K and 1 atm via modified Green-Kubo formulas. Two component mixture of A and B is built by considering the interaction between A and A as the attractive (A) potential, that between A and B as the attractive potential (A), and that between B and B as the repulsive potential (R), labelled as AAR mixture. Three more mixtures - ARA, ARR, and RAR are created in the same way. The behavior of the LJ energy and the transport properties for all the mixtures is easily understood in terms of the portion of attractive potential (A %). The behavior of the thermal conductivities by the translational energy transport due to molecular motion exactly coincides with that of diffusion constant while that of the thermal conductivities by the potential energy transport due to molecular motion is easily understood from the fact that the LJ energy of AAR, ARR, and RAR mixtures increases negatively with the increase of A % from that of the pure repulsive system while that of ARA changes rarely.

Preliminary Works of Contact via Formation of LCD Backplanes Using Silver Printing

  • Yang, Yong Suk;You, In-Kyu;Han, Hyun;Koo, Jae Bon;Lim, Sang Chul;Jung, Soon-Won;Na, Bock Soon;Kim, Hye-Min;Kim, Minseok;Moon, Seok-Hwan
    • ETRI Journal
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    • v.35 no.4
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    • pp.571-577
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    • 2013
  • The fabrication of a thin-film transistor backplane and a liquid-crystal display using printing processes can eliminate the need for photolithography and offers the potential to reduce the manufacturing costs. In this study, we prepare contact via structures through a poly(methyl methacrylate) polymer insulator layer using inkjet printing. When droplets of silver ink composed of a polymer solvent are placed onto the polymer insulator and annealed at high temperatures, the silver ink penetrates the interior of the polymer and generates conducting paths between the top and bottom metal lines through the partial dissolution and swelling of the polymer. The electrical property of various contact via-hole interconnections is investigated using a semiconductor characterization system.

Improvement in Long-Term Stability and Photovoltaic Performance of UV Cured Resin Polymer Gel Electrolyte for Dye-Sensitized Solar Cell

  • Park, Geun Woo;Hwang, Chul Gyun;Jung, Jae Won;Jung, Young Mee
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.4093-4097
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    • 2012
  • We introduced a new UV-cured resin polymer gel as an electrolyte for dye-sensitized solar cells (DSSCs) that is cured with UV irradiation to form a thin film of UV-cured resin polymer gel in the cells. The gel film was characterized and its potential for use as an electrolyte in DSSCs was investigated. This new UV-cured resin polymer gel was successfully applied as a gel polymer electrolyte in DSSCs overcoming the problems associated with the liquid electrolytes in typical DSSCs. The effect of ${\gamma}$-butylrolactone (GBL) on the long-term stability and photovoltaic performance in DSSCs using this UV-cured resin polymer gel electrolyte was also investigated. The results of the energy conversion efficiency, ionic conductivity and Raman spectra of the UV-cured resin polymer gel electrolyte with the addition of 6 wt % GBL to the UV-cured resin polymer electrolyte showed good long-term stability and photovoltaic performance for the DSSCs with the UV-cured polymer gel electrolyte.

Measurement errors of the EIT systems using a phantom and conductive yarns (전기임피던스 단층촬영법을 이용한 외란위치 계측오차)

  • Park, Ji Su;Koo, Sang-Mo;Kim, Choong Hyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.8
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    • pp.1430-1435
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    • 2016
  • Electrical impedance tomography (EIT) has been applied to measure the location of external disturbance using a phantom and conductive yarns. According to the test results, the addition of carbon nanotube particles into the phantom does not show remarkable improvement in location errors. On the other hand combined fabric, conductive yarns with fabric, and non-woven fabric, were added to evaluate its performance as a fabric sensor. The combined fabric resulted in a decrease of 21.5% in the circumferential location error and a decrease of 50% in the radial location error, compared to those of the yarns. Additionally, it was revealed that the measurement error is almost linearly proportional to the conductivity of the phantom liquid and resistance of the conductive yarns. The combined fabric can be a promising material for fabric sensors in sports utilities and medical devices.

Preparation of Porous Gold for Sensor Applications (센서 응용을 위한 다공성 골드의 제조)

  • Kim, Young-Hun;Kim, He-Ro;Ko, Jae-Wook
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.32-37
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    • 2008
  • For a development of U-safety system, liquid/gas-sensors that are easy to carry and install in any place are needed. Therefore, in this work, we prepared porous gold using a templating method with nanoporous alumina, and it was used as sensing materials and electrode. The resulting materials showed high purity macroporous structure with $200{\sim}300\;nm$ of window-pore and $4.8\;m^2/g$ of surface area. Because porous gold had good electric conductivity, convenience to measure the change of electric resistivity and good reproducibility, it could be used as potential sensing materials. As a proof-of-concept test, the detection test for mercury ion was carried out.

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MODELLING OF PYROLYSIS PROCESSES OF POLYACRYLONITRILE

  • Lipanov, A.M.;Kodolov, V.I.;Ovchinnikova, L.N.;Savinsky, S.S.;Khokhriakov, N.V.;Sarakula, V.L.
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.112-119
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    • 1997
  • The modelling of carbon substances obtaining, for instance, carbon fibers which have high fire resistance, has been realized on the example of the polyacrylonitrile pyrolysis modelling. The pyrolysis is considered as a double step process when the formation of a liquid phase and the oxidation of substance are excluded. Three main reactions are considered: a) with the evolution of ammonia; b) with the evolution of hydrogen cyanide; c) with the evolution of hydrogen. Reactions b) and c) are sequential, and a) and b) are parallel. The problem is formulated as one-dimensional. The equations of energy, masses or concentrations, porosity and thermal conductivity are proposed. The mathematical model of the carbonization process is designed using tile kinetic characteristics of the above reactions and the thermodynamic parameters of reagents and products in these reactions. The equations received are calculated by Runge-Cutta method and by Adams method of the fourth order accuracy.

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