• Journal of Mechanical Science and Technology
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• v.19 no.5
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• pp.1216-1225
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• 2005

$CO_{2}$ ocean sequestration is one of the promising options to reduce $CO_{2}$ concentration in the atmosphere because the ocean has vast capacity for $CO_{2}$ absorption. Therefore, in the present investigation, calculations for solubility and dissolution behavior of liquid $CO_{2}$ droplets released at 1000 m and 1500 m deep in the ocean from a moving ship and a fixed pipeline have been carried out in order to estimate the $CO_{2}$ dissolution characteristics in the ocean. The results show liquid $CO_{2}$ becomes bubble at around 500 m in depth, and the solubility of seawater is about $5{\%}$ less than of pure water. Also, it is shown that the injection of liquid from a moving ship is a more effective method for dissolution than from a fixed pipeline, and the presence of hydrate on liquid $CO_{2}$ acts as a resistant layer in dissolving liquid $CO_{2}$.

• Bulletin of the Korean Chemical Society
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• v.21 no.11
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• pp.1133-1137
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• 2000

Gibbs ensemble Monte Carlo simulations were performed to calculate the vapor- liquid coexistence properties for the binary mixtures $CO_2/C_3H8$, $CO_2/CH_3OCH_3$, and $CO_2/CH_3COCH_3.$ For all the molecules the potential between sites in different molecules was simply calculated by the Lennard-Jones potential. Density of the mixture, composition of the mixture, the pressure-composition diagram, the chemical potential of component, and the radial distribution function were calculated at vapor- liquid equilibrium. The composition and the density of both vapor and liquid from simulation agreed considerably well with the experimental values over a wide range of pressures. The radial distribution functions in the liquid mixtures showed that $CO_2$ molecules tended to form cluster with each other and $C_3H8$ molecules also aggregated each other due to the weak interaction between $CO_3$ and $C_3H8$ molecule. However the interaction potentials between the same components were similar to those between the different components in the liquid mixtures $CO_2/CH_3OCH_3$ and $CO_2/CH_3COCH_3$.

• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.811-817
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• 2002

Gibbs ensemble Monte Carlo simulations were performed to calculate the vapor-liquid coexistence properties for the binary mixtures $CO_2/CH_3OH$, $CO_2/C_2H_5OH$, and $CO_2/CH_3CH_2CH_2OH.$ The configurational bias Monte Carlo method was used in the simulation of alcohol. Density of the mixture, composition of the mixture, the pressure-composition diagram, and the radial distribution function were calculated at vapor-liquid equilibrium. The composition and the density of both vapor and liquid from simulation agree considerably well with the experimental values over a wide range of pressures. The radial distribution functions in the liquid mixtures show that $CO_2$ molecules interact more stogly with methyl group than methylene group of $C_2H_5OH$ and $CH_3CH_2CH_2OH$ due to the steric effects of the alcohol molecules.

• New & Renewable Energy
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• v.4 no.2
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• pp.12-20
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• 2008

Calculations for the dissolution behavior of liquid CO2 droplets released in the East Sea and the Clipperton Clarion from a moving ship and a fixed pipeline have been carried out in order to estimate the CO2 dissolution characteristics in the ocean. The results show that the injection of liquid CO2 from a moving ship in a high temperature point is an effective method for dissolution. Also, it is noted that the ultimate plume generated from CO2 bubbles repeatsand shrinking due to the peeling from a fixed pipeline, and the presence of hydrate layer on a liquid CO2 droplet acts as a resistant layer in dissolving liquid CO2.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.597-601
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• 2008

Calculations for the dissolution behavior of liquid $CO_2$ droplets released in the East Sea and the Clipperton Clarion from a moving ship and a fixed pipeline have been carried out in order to estimate the $CO_2$ dissolution characteristics in the ocean. The results show that the injection of liquid $CO_2$ from a moving ship in a high temperature point is an effective method for dissolution. Also, it is noted that the ultimate plume generated from $CO_2$ bubbles repeatsand shrinking due to the peeling from a fixed pipeline, and the presence of hydrate layer on a liquid $CO_2$ droplet acts as a resistant layer in dissolving liquid $CO_2$.

• Membrane Journal
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• v.31 no.1
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• pp.1-15
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• 2021

The membrane-based CO2 capture is a fast-growing branch in gas separating field. Ionic liquid assisted mixed matrix membrane (MMM), which consists of organic fillers with dispersed ionic liquid, shows high potentiality as a candidate for CO2 separation medium. In MMM, various kinds of ionic liquid and inorganic filler are incorporated into polymer to enhance gas separating performance. Especially, the strong interaction between ionic liquid and organic filler gives huge influence on enhancing the separating performance by increasing affinity, selectivity and adsorption of CO2 into the framework. Also the mechanical properties of metal organic framework are positively tuned by input of ionic liquid to improve CO2 permeability and selectivity. In this review, study of various combinations of ionic liquid and metal organic framework (MOF) in the polymeric membrane for carbon dioxide separation is discussed.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.257-257
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• 2015

Carbon Capture and Storage with ocean sequestration is being considered as one of the most effective option for reducing the $CO_2$ net flux from atmosphere nowadays. But it is still possible for $CO_2$ substance to leaks out from transport pipeline or from the under seabed storage sites and causing damage to ambient environment. The behavior of liquid $CO_2$ under droplet shape would be strongly affected by the presence of other contaminants such as $SO_2$ comes from processing processes. This presentation shows the behavior in the sea water of pure liquid $CO_2$ droplets as well as droplets that consist of $SO_2$ substances. The study uses computational fluid dynamic models in comparison with experimental data from other previous researchers. Droplet of liquid $CO_2$ is assumed to be released at several depths in deep ocean, with other environmental conditions are set up respectively. All calculations are conducted with many different ratio of contaminant $SO_2$ to provide fundamental data of those particles rising characteristics. The effect of contaminants on the behavior of $CO_2$ droplets would be clearly shown through the results of particle deformation, terminal rising velocity happen due to buoyancy force driving from the difference in density of $CO_2$ substance and ocean water around.

• Journal of the Korean Applied Science and Technology
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• v.33 no.2
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• pp.232-238
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• 2016

In this study, a liquid carbonation method was applied for producing precipitate calcium carbonate by liquid-liquid reaction. Also a shuttle mechanism of wet chemical absorption using MEA was utilized. The high concentration $CO_2$(A) and exhaust gas(B) was used for collecting carbon dioxide in the 30% MEA aqueous solution, and $CO_2$ was fixed with rate of 0.35 mg of $CO_2$ per mg of sludge through the liquid carbonation process. It was found from SEM data that calcium carbonate was mainly made up with spherical vaerite with the mixing of a small quantity of calcite.

• Membrane and Water Treatment
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• v.7 no.5
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• pp.463-476
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• 2016

In this study, application of polypropylene hollow fiber membrane contactors for $CO_2$ removal from water in liquid-liquid extraction (LLE) mode was simulated. For this purpose, a steady state 2D mathematical model was developed. In this model axial and radial diffusion was considered to $CO_2$ permeation through the hollow fibers. $CO_2$ laden water is fed at a constant flow rate into the lumen side, permeated through the pores of membrane and at the end of this process, $CO_2$ solution in the lumen side was extracted by means of aqueous diethanolamine (DEA) and chemical reaction. The simulation results were validated with the experimental data and it was found a good agreement between them, which confirmed the reliability of the proposed model. Both simulation and experimental results confirmed the reduction in the percentage of $CO_2$ removal by increment of feed flow rate.

• Membrane Journal
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• v.22 no.4
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• pp.280-283
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• 2012

The study is aiming to prepare supported ionic liquid membranes for carbon dioxide separation efficiently. The ionic liquid, [bmim][${PF_6}^-$] (1-butyl-3-methyl-imidazolium hexafluorophosphate) was fixed in the pores of PVDF micro-filtration membrane with a nominal pore size 0.1 ${\mu}m$. The permeabilities of $N_2$, $H_2$ and $CO_2$ gases through the prepared ionic liquid membrane were 0.075, 0.203 and 1.380 GPU, respectively. The selectivities of $CO_2/N_2$, $H_2/N_2$ were 14.2 and 2.69, respectively. Also, the supported ionic liquid membrane could be operated stably up to 2.0 bar with the immobilization of ionic liquid in the pores.