• Bulletin of the Korean Chemical Society
• /
• v.21 no.7
• /
• pp.685-689
• /
• 2000

The complexation reaction between Pb2+,TI and Cd2+ions and macrocyclic ligands, 18-crown-6 ( 18C6) and dibenzo- 18-crown-6 (DB 18C6), was studied in dimethylsulfoxide (DMSO)-nitromethane (NM) and dimethyl-formamide (DMF)-nitromethane binary system s by square wave polarography (SWP) technique. The stoichiometry and stability of the complexes were determined by monitoring the shifts in half-waves or peak potentials of the polarographic waves of metal ions against the Iigand concentration. In most cases, the stability constants of complexes increase with increasing amounts of the nitromethane in mixed binary solvents used in this study. The complexes formed between 18C6 and DB18C6 and these metal cations in all cases had a stoichiometry of 1 : 1. The results obtained show that there is an inverse relationship between the formation constant of complexes and the donor number of solvents based on a Gatmann donocity scale and the stability constants show a high sensitivity to the composition of the mixed solvent systems. A linear behavior was observed for variation of log Kf of I8C6 complexes vs the composition of the mixed solvent systems in NM/DMSO and NM/DMF,but a non-linear behavior was observed in the case of DB 18C6 complexes in these binary systems. In most of the systems investigated, the Pb2+ cation forms a more stable complex with the 18C6 than other two cations and the order of selectivity of this Iigand for cations is: Pb2+ > TI+,Cd2+.

• Journal of the Korean Statistical Society
• /
• v.28 no.4
• /
• pp.415-433
• /
• 1999

This paper considers the design of step-stress accelerated life tests for the Weibull distribution with a nonconstant shape parameter under Type I censoring. It is assumed that scale and shape parameters are log-linear functions of (possibly transformed) stress and that a cumulative exposure model holds for the effect of changing stress. The asymptotic variance of the maximum likelihood estimator of a stated quantile at design stress is used as an optimality criterion. The optimum three step-stress plans are presented for selected values of design parameters and the effects of errors in pre- estimates of the design parameters are investigated.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2010.03a
• /
• pp.971-980
• /
• 2010

Evaluation of permeability and coefficient of consolidation of clayey sand is critical to analyze ground stability or environmental problems such as diffusion and dispersion in groundwater flow. Permeability tests using a flexible wall permeameter were performed to derive the coefficient of consolidation and permeability of reconstituted soil samples with various mixing ratios of kaolin clays and two different types of sands, Jumunjin sand and Ottawa sand. The test results indicated that coefficient of consolidation and permeability in log scale have linear relationships with clay contents in low clay mixing ratio. It is also recognized that coefficient of consolidation and permeability of sand and clay mixture are also dependent on the soil structure.

• Journal of Korean Society for Quality Management
• /
• v.36 no.1
• /
• pp.31-39
• /
• 2008

This paper proposes a method of estimating the lifetime distribution at use condition for constant stress accelerated life tests when an infant-mortality failure mode as well as wear-out one exists. General limited failure population model is introduced to describe these failure modes. It is assumed that the log lifetime of each failure mode follows a location-scale distribution and a linear relation exists between the location parameter and the stress. An estimation procedure using the expectation and maximization algorithm is proposed. Specific formulas for Weibull distribution are obtained. An illustrative example and the simulation results are given.

• Journal of Korean Society on Water Environment
• /
• v.28 no.4
• /
• pp.538-550
• /
• 2012

This study suggests a general methodology which is designed for assessing RDOC behavior at the catchment scale by coupling properly a series of steam flow and water quality simulation models and actual monitoring data set. The modified TANK model in which a river routing function is incorporated to the conventional one is applied to simulate the long-term daily stream flow data, and the simulated stream flow data is combined with the 7-parameter log-linear model coupled to the minimum variance unbiased estimator to simulate the long-term daily water quality (BOD, COD and TOC) loads. Finally, the regression analysis between the usually monitored water quality data (BOD, COD and TOC) and RDOC is combined with the simulated water quality data to manifest the spatio-temporal variability of RDOC flux behavior at the Korean TMDL catchment scale.

• Geophysics and Geophysical Exploration
• /
• v.14 no.3
• /
• pp.185-190
• /
• 2011

In marine controlled-source electromagnetic (CSEM) modeling, it may be difficult to evaluate primary fields accurately using conventional linear filters because they decay very rapidly with distance. However, since there exists a closed-form solution to the Hankel transform in TM mode for a homogeneous half space, we can assess the accuracy of linear filters for evaluating the Hankel transform. As a result, only nine out of 36 source-receiver pairs show that EM fields decrease linearly in semi-log scale with an increase of source-receiver distance, while EM fields are either 0 or not reduced significantly due to an effect of the air layer. There also exist closed-form solutions for the nine pairs, and the others can be evaluated accurately with a relatively short filter. This paper proposes a method which uses closed-form solutions for TM-mode Hankel transforms and a filter with 61 coefficients for TE-mode ones.

• Journal of Korea Water Resources Association
• /
• v.42 no.7
• /
• pp.525-535
• /
• 2009

In this paper a heuristic method for identifying individual pipes in water pipe networks to determine specific sections of the pipes that need to be replaced due to deterioration. An appropriate minimum pipe length is determined by selecting the pipe length that has the greatest variance of the average cumulative break number slopes among the various pipe lengths used. As a result, the minimum pipe length for the case study water network is determined as 4 m and a total of 39 individual pipe IDs are obtained. The economically optimal replacement times of the individual pipe IDs are estimated by using the threshold break rate of an individual pipe ID and the pipe break trends models for which the General Pipe Break Prediction Model(Park and Loganathan, 2002) that can incorporate the linear, exponential, and in-between of the linear and exponetial failure trends and the ROCOFs based on the modified time scale(Park et al., 2007) are used. The maximum log-likelihoods of the log-linear ROCOF and Weibull ROCOF estimated for the break data of a pipe are compared and the ROCOF that has a greater likelihood is selected for the pipe of interest. The effects of the social costs of a pipe break on the optimal replacement time are also discussed.

• Journal of the Korean Society of Hazard Mitigation
• /
• v.9 no.5
• /
• pp.15-21
• /
• 2009

The design of the stud shear connector of a bridge structure is mostly controlled by the fatigue resistance not by the strength, if it is followed by AASHTO LRFD Bridge Design Specification. This fatigue design code in AASHTO LRFD is based on the research work done by Slutter and Fisher in 1966. These tests seemingly underestimated the fatigue resistance of connectors because of the inherent eccentricity of the one-face test setup which results additional tension forces to the stud. In addition, the stress ranges were not plotted in the log scale, because it was not known at that time that the fatigue resistance of the welded steel structures has a linear relationship of log scales of stress range and number of loading cycles. This study evaluates the test data produced by the Slutter and Fischer, and plot the data on the proper manner. The fatigue push-out test data produced recently by many other researches all around the world are gathered and analyzed, furthermore a design curve is recommended.

• Geophysics and Geophysical Exploration
• /
• v.18 no.3
• /
• pp.125-132
• /
• 2015

The water saturation ($S_w$), which is very important to estimate hydrocarbon reserves in the reservoir, has been determined from resistivity index (RI) by using the Archie's formula. However, in many cases, it has been reported that n is not constant for a given formation and it could be varied with water saturation. In addition, it frequently happens that the line obtained by linear regression analysis on log-log scale does not pass through the origin. In order to overcome these drawbacks, we suggested a modified Archie's formula, which can handle almost all the RI vs. $S_w$ cross-plots whether the trend is straight or curved and whether it passes through the origin or not. We also demonstrated that how to determine conductivity exponent ${\mu}$, critical water saturation $S_c$, and saturation distribution factor b in the laboratory to use the modified Archie's formula. Since the modified Archie's formula takes into account pore structure, pore water distribution, and wettability of reservoir such as clean sandstone and carbonate rocks, it might improve field applicability.

• Journal of the Korean Society of Industry Convergence
• /
• v.21 no.1
• /
• pp.17-27
• /
• 2018

We propose a new approach to control a biped robot motion based on iterative learning of voice command for the implementation of smart factory. The real-time processing of speech signal is very important for high-speed and precise automatic voice recognition technology. Recently, voice recognition is being used for intelligent robot control, artificial life, wireless communication and IoT application. In order to extract valuable information from the speech signal, make decisions on the process, and obtain results, the data needs to be manipulated and analyzed. Basic method used for extracting the features of the voice signal is to find the Mel frequency cepstral coefficients. Mel-frequency cepstral coefficients are the coefficients that collectively represent the short-term power spectrum of a sound, based on a linear cosine transform of a log power spectrum on a nonlinear mel scale of frequency. The reliability of voice command to control of the biped robot's motion is illustrated by computer simulation and experiment for biped walking robot with 24 joint.