• Title/Summary/Keyword: Limit Gas

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Effects of Different Averaging Operators on the Urban Turbulent Fluxes (평균 방법이 도시 난류 플럭스에 미치는 영향)

  • Kwon, Tae Heon;Park, Moon-Soo;Yi, Chaeyeon;Choi, Young Jean
    • Atmosphere
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    • v.24 no.2
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    • pp.197-206
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    • 2014
  • The effects of different averaging operators and atmospheric stability on the turbulent fluxes are investigated using the vertical velocity, air temperature, carbon dioxide concentration, and absolute humidity data measured at 10 Hz by a 3-dimensional sonic anemometer and an open-path $CO_2/H_2O$ infrared gas analyzer installed at a height of 18.5 m on the rooftop of the Jungnang KT building located at a typical residential area in Seoul, Korea. For this purpose, 7 different averaging operators including block average, linear regression, and moving averages during 100 s, 300 s, 600 s, 900 s, and 1800 s are considered and the data quality control procedure such as physical limit check and spike removal is also applied. It is found that as the averaging interval becomes shorter, turbulent fluxes computed by the moving average become smaller and the ratios of turbulent fluxes computed by the 100 s moving average to the fluxes by the 1800 s moving average under unstable stability are smaller than those under neutral stability. The turbulent fluxes computed by the linear regression are 85~92% of those computed by the 1800 s moving average and nearly the same as those computed by 900 s moving average, implying that the adequate selection of an averaging operator and its interval will be very important to estimate more accurate turbulent fluxes at urban area.

Seismic Performance of a Knee-Braced Moment Resisting Frame (Knee brace가 설치된 모멘트저항골조의 내진성능)

  • Choi, Hyun-Hoon;Kim, Jin-Koo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.1
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    • pp.171-180
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    • 2005
  • In this study the seismic performance of a three-story knee-braced moment-resisting frame (KBMRF), which is typically employed to support pipelines for oil or gas, was investigated. Nonlinear static pushover analyses were performed first to observe the force-displacement relationship of KBMRF under increasing seismic load. The results show that, when the maximum inter-story drift reached 1.5% of the story height, the main structural members, such as beams and columns, still remained elastic. Then nonlinear dynamic time-history analyses were carried out using eight earthquake ground motion time-histories scaled to at the design spectrum of UBC-97. It turned out that the maximum inter-story drift was smaller than the drift limit of 1.5 % of the structure height, and that the columns remained elastic. Based on these analytical results, it can be concluded that the seismic performance of the structure satisfies all the requirements regulated in the seismic code.

A Study on the Characteristics and Utilization of Ash from Sewage Sludge Incinerator (하수(下水)슬러지 소각재의 특성(特性) 평가(評價) 및 재활용(再活用)을 위한 기초연구(基礎硏究))

  • Lee, Hwa-Young
    • Resources Recycling
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    • v.17 no.3
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    • pp.3-9
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    • 2008
  • The measurement of physicochemical properties and chemical composition of SSA(sewage sludge ash) has been carried out and the preparation of lightweight material has also been performed using SSA for reuse as building or construction materials. For this aim, lightweight material has been prepared by forming the mixture of SSA, lightweight filler and inorganic binder followed by calcination at elevated temperature and characterized in terms of density and compressive strength. The pH of fly ash was found to be slightly alkaline, pH 8.69, due to the addition of caustic soda in order to neutralize the acidic gas while the pH of bottom ash was 6.48 Heavy metal leachability based on the standard leach test was also found to be below the detection limit for Cd, Cu, Pb, As and Cr of SSA. As far as the compressive strength of lightweight material was concerned, the compressive strength of lightweight material using fly ash was higher than that of lightweight material using bottom ash.

Continuous Automated Determination of Urea Using a New Enzyme Reactor (새로운 효소반응기를 이용한 요소의 연속·자동화 정량)

  • Heung Lark Lee;Seung Tae Yang
    • Journal of the Korean Chemical Society
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    • v.36 no.3
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    • pp.393-404
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    • 1992
  • The response properties of continuous automated system using an enzyme reactor for determination of urea were investigated. The enzyme reactor was constructed to packed-bed form which filled with nylon-6 beads (42∼48 mesh), which immobilized urease with glutaraldehyde, in teflon tube (2 mm I.D., 20 cm length). The system was composed of the enzyme reactor, gas dialyzer, and tublar PVC-nonactin membrane ammonium ion-selective electrode as an indicator electrode in serial order. The response characteristics of this system were as follows. That is, the concentration range of linear response, slope of linear response, detection limit, and conversion percentage were $5.5{\times}10^{-6}$$2.4{\times}10^{-3}M$, 57.8 mV/decade, $1.5{\times}10^{-6}$, and 80.8%, respectively. The optimum buffer and life time of urease reactor were 0.01M Tris-HCl buffer solution (pH 7.0∼7.8) and 0.01M phosphate buffer solution (pH 6.9∼7.5) and about 150 days, respectively. And the urease reactor had no interferences of the other physiological materials.

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Determination of oestrone, $17{\alpha}$-and $17{\beta}$-oestradiol in bovine aqueous humor using gas chromatography-negative ion chemical ionization mass spectrometry

  • Zafar-Iqbal;Midgley, John-M;Watson, David-G
    • Archives of Pharmacal Research
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    • v.20 no.3
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    • pp.247-252
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    • 1997
  • Perfluorotolyl (PFT)-ether and perfluorotoly-trimethylsilyl (PFT-TMS) ether derivatives of oestrone, $17{\alpha}$- and $17{\beta}$oestradiol were prepared under phase transfer conditons. The former derivatives under negative ion chemical ionization conditions gave significant ions in the mass spectrometer but $17{\alpha}$- and $17{\beta}$ -oestradiol gave poor resolution. However, the PFT-TMS derivatives of 17.${\alpha}$- and$17{\beta}$-oestradiol showed good resolution. These derivatives were used for the analysis of oestrogens in bovine aqueous humour, vitreous humour and retina. The mean $({\pm}SEM)$ concentrations of oestrone in bovine aqueous humour (n=18), vitreous humour (n=18) and bovine retina (n=4) were $0.47{\pm}0.11$, $0.46{\pm}0.14$ and $1.10{\pm}0.24 ng.ml^{-1}$, respectively. $17{\alpha}$-Oestradiol was detected in 16 out of 18 samples of bovine aqueous humour and vitreous humour and the mean $({\pm}SEM)$ concentrations were $0.30{\pm}0.10$ and $0.08{\pm}0.02 ng.ml^{-1}$, respectively. The mean $({\pm}SEM)$ concentration of 17.betha.-oestradiol in aqueous humour (n=7) and vitreous homour (n=11) $0.83{\pm}0.26 ng ml^{-1}$ and $0.39{\pm}0.09 ng ml^-1$, respectively. In retina the concentrations of both steroids were below the detection limit.

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The Effect Analysis of One-side Walking Behavior Using MDPM(Multi-directional Pedestrian Model) (다방향보행자모형(MDPM)을 이용한 편측보행 효과분석)

  • Lee, Jun;Cho, Han-Seon;Hyun, Kyung;Chung, Jin-Hyuk
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.8 no.5
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    • pp.151-159
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    • 2009
  • Network models for pedestrian flows have been studied in various ways. However, because of the simplicity and application, a number of researchers prefer the CA Model to analyze pedestrian's complicated behavior. These kinds of models based on Agent are being used as a microscopic analyzing method since it can easily adapt individuals' various characters and movement types. However, because pedestrians' movement can be (easily) effected by where they are and where they head, some models using the same rules have limit when considering pedestrians' every different movement. In this research, homogeneous section is defined as a similar movement type of individuals. With MDPM, we suggest simulation method explaining one-way walk and side-walk which could not be done in past.

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Purity Assessment of Organic Reference Materials with a Mass Balance Method: A Case Study of Endosulfan-II

  • Kim, Seung-Hyun;Lee, Joonhee;Ahn, Seonghee;Song, Young-Sin;Kim, Dong-Kyum;Kim, Byungjoo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.531-538
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    • 2013
  • A mass balance method established in this laboratory was applied to determine the purity of an endosulfan-II pure substance. Gas chromatography-flame ionization detector (GC-FID) was used to measure organic impurities. Total of 10 structurally related organic impurities were detected by GC-FID in the material. Water content was determined to be 0.187% by Karl-Fischer (K-F) coulometry with an oven-drying method. Non-volatile residual impurities was not detected by Thermal gravimetric analysis (TGA) within the detection limit of 0.04% (0.7 ${\mu}g$ in absolute amount). Residual solvents within the substance were determined to be 0.007% in the Endosulfan-II pure substance by running GC-FID after dissolving it with two solvents. The purity of the endosulfan-II was finally assigned to be ($99.17{\pm}0.14$)%. Details of the mass balance method including interpretation and evaluating uncertainties of results from each individual methods and the finally assayed purity were also described.

An Investigation on the Technical Background for Carbon-14 Monitoring in Radioactive Effluents (원자력시설의 Carbon-14 방사성유출물에 대한 감시배경의 조사)

  • Kim, Hee-Geun;Kong, Tae-Young;Jeong, Woo-Tae;Kim, Seok-Tae
    • Journal of Radiation Protection and Research
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    • v.34 no.4
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    • pp.195-200
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    • 2009
  • effluents to the environment. The activity of carbon-14, one of the radioactive effluents, in the environment is already high level and its effect on radiation exposure to the public and the environment is insignificant; thus, NPPs did not perform the carbon-14 monitoring in effluents in the past. By the way, effluents of noble gas and particulate radioactive materials originated from nuclear fuels has been continuously reduced due to both the advancement of manufacturing and integrity technology for nuclear fuels and the improvement of operation methods of NPPs. Futhermore, the portion of dose assessment by tritium and carbon-14 to the public has been relatively increased because the lower limit of detection for low-energy beta sources, such as tritium and carbon-14, is low due to the advancement of radiation detection technology. In this paper, the technical background for carbon-14 monitoring in nuclear facilities was investigated using United States technical reports and papers. This paper also reviews whether carbon-14 monitoring is necessary or not based on the investigated documents.

Gas-Sensing Membrane Electrodes for the Determination of Dissolved Gases (III). Continuous-Automated Determination of Nitrite Ion Using a New Tubular PVC Membrane Type of Selective Electrode Nitrate (溶解氣體 分析用 氣體感應膜 이온選擇性 電極 (第 3 報). 새로운 管形 PVC膜 질산이온 選擇性 電極을 이용한 아질산이온의連續·自動化 定量)

  • Lee Heung Lark;Yun Jong-Hoon
    • Journal of the Korean Chemical Society
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    • v.35 no.1
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    • pp.51-58
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    • 1991
  • A new tubular poly(vinyl chloride) membrane type of nitrate selective electrode was prepared and its characteristics were evaluated. The response slope, detection limit, and response time (t$_{99}$) under the optimum membrane composition (5${\%}$ aliquat-NO$_3$ solution + 32${\%}$ poly(vinyl chloride) + 63${\%}$ dibutyl sebecate) of the electrode were 58.5 ${\pm}$ 0.1 mV/decade, 2.0 ${\times}$ 10$^{-5}$ M, and 25 seconds, respectively. The nitrite ion was determined by the continuous-automated method using the new electrode. 10$^{-2}$ M phosphate buffer solution (pH 7.6) was used as a recipient solution. And also hydrogen peroxide (0.3${\%}$) was added to the recipient as an oxidant. The linear response range and response range and response slope for the standard nitrite solution under the optimum condition of this electrode system were 8.0 ${\times}$ 10$^{-5}$ M ∼ 5.0 ${\times}$ 10$^{-2}$ M and 56.8 ${\pm}$ 0.2 mV/decade, respectively.

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Revenue Analysis of Taxi According to Moving Speed (택시의 최대 수익을 위한 최적의 운행 속도 분석)

  • Park, Bo-Yeol;Lee, Goo-Yeon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.38B no.3
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    • pp.222-228
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    • 2013
  • In this paper, we analyze the optimum moving speed of taxi for maximum revenue. In the analysis, we assume that passengers are distributed exponentially along with the direction as taxi moves. When the taxi arrives at the location of a passenger within the predetermined time limit, the passenger gets in the taxi. Otherwise, we assume that the passenger leaves the location and the taxi does not meet the passenger. We vary taxi speed from 0km/h through 80km/h to see how revenue of a taxi varies, applying the average gas mileage of LPG taxis in Korea. From the results of the analysis, we see that the probability that a taxi meets passengers goes high as taxi speed gets fast, however the revenue starts to fall after the maximum point of revenue at the optimum speed, since fuel cost gets dominant.