• Title/Summary/Keyword: Light-activated

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Evaluation of Oxidation Efficiency of Aromatic Volatile Hydrocarbons using Visible-light-activated One-Dimensional Metal Oxide Doping Semiconductor Nanomaterials prepared by Ultrasonic-assisted Hydrothermal Synthesis (초음파-수열합성 적용 가시광 활성 일차원 금속산화물 도핑 반도체 나노소재를 이용한 방향족 휘발성 탄화수소 제어효율 평가)

  • Jo, Wan-Kuen;Shin, Seung-Ho;Choi, Jeong-Hak;Lee, Joon Yeob
    • Journal of Environmental Science International
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    • v.27 no.11
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    • pp.967-974
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    • 2018
  • In this study, we evaluated the photocatalytic oxidation efficiency of aromatic volatile hydrocarbons by using $WO_3$-doped $TiO_2$ nanotubes (WTNTs) under visible-light irradiation. One-dimensional WTNTs were synthesized by ultrasonic-assisted hydrothermal method and impregnation. XRD analysis revealed successful incorporation of $WO_3$ into $TiO_2$ nanotube (TNT) structures. UV-Vis spectra exhibited that the synthesized WTNT samples can be activated under visible light irradiation. FE-SEM and TEM images showed the one-dimensional structure of the prepared TNTs and WTNTs. The photocatalytic oxidation efficiencies of toluene, ethylbenzene, and o-xylene were higher using WTNT samples than undoped TNT. These results were explained based on the charge separation ability, adsorption capability, and light absorption of the sample photocatalysts. Among the different light sources, light-emitting-diodes (LEDs) are more highly energy-efficient than 8-W daylight used for the photocatalytic oxidation of toluene, ethylbenzene, and o-xylene, though the photocatalytic oxidation efficiency is higher for 8-W daylight.

Noni Inhibits Neuronal Damage Caused by the Immune Reaction of Microglial Cells Activated by Doxorubicin (Doxorubicin에 의해 활성화된 미세 아교세포의 면역반응으로 인한 신경손상에 Noni가 미치는 영향)

  • Jung, Se-Hwa;Lee, Seong-Min;Ha, Ji-Sun;Yang, Seung-Ju;Kim, Pyung-Hwan
    • Korean Journal of Clinical Laboratory Science
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    • v.52 no.4
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    • pp.389-397
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    • 2020
  • Microglial cells function as major immune cells in the brain, playing an important role in the protection and damage of neurons. BV2 microglia, activated by drug stimulation, secrete inflammatory cytokines by activating the nuclear factor kappa-light-chain-enhancer of the activated B cells pathway and are involved in neuroinflammatory and immune responses. The overactivation of microglia by stimuli can cause neuronal damage, leading to brain disease. Noni, a natural product, reduces the activity of microglia to prevent neuronal damage and is a potential natural medicine because it exerts excellent regeneration and anti-inflammatory effects on damaged cells. In this study, when noni was used to treat BV2 cells stimulated by the anti-cancer drug doxorubicin, it reduced the release of pro-inflammatory cytokines from BV2. On the other hand, neuronal damage is a side effect of doxorubicin. Therefore, the cytokines released from doxorubicin-stimulated BV2 cells treated with noni had a positive effect on the neuronal viability compared to those released from doxorubicin-stimulated BV2 cells not treated with Noni. Thus, Noni increases neuronal viability. These results suggest that noni inhibits the release of cytokines by regulating the nuclear factor kappa-light-chain-enhancer of the activated B cells pathway of BV2, thereby inhibiting neuronal damage.

Development of Window Filters Using an Electrospinning Technique to Block Particulate Matter and Volatile Organic Compound (미세입자, 휘발성유기화합물 차단을 위한 전기방사 창문 필터)

  • Soon-Ho Kim;Sang-Il Han
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.401-406
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    • 2023
  • With the development of industry, fine dust is causing difficulties in various fields such as environment, health, and life, and a large amount of pollutants generated from human social activities are emerging as a serious environmental problem due to air pollution. Therefore, in this study, activated carbon was added to remove fine dust and volatile organic compounds by spinning cellulose acetate polymer fibers on a silicon support using the electrospinning method. By varying the activated carbon ratio and electrospinning time, the fine dust blocking effect and toluene adsorption performance were confirmed according to the activated carbon ratio and filter thickness. As a result, it was shown that the particles were effectively blocked with the increase in the electrospinning time due to the filter thickness increase. Adsorbed amount of toluene was increased with increase in activated carbon amount. Light transmittance was decrease with increase in electrospinning time, showing that there were light transmittance in filters electrospun for 20~30 minutes.

Effect of Light Quality on the Photorespiration in Pisum sativum L. (완두에서 광호흡에 미치는 광질의 영향)

  • 이순희
    • Journal of Plant Biology
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    • v.33 no.3
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    • pp.203-210
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    • 1990
  • Effects of blue and red light on photorespiration in the leaf disks of pea were studied. The rate of total 14CO2 fixation was more or less higher under red light than blue light irradiation of the same quantum (94.8 $\mu$Em-2.S-1/mV). The release of 14CO2 by photorespiration was more stimulated under blue than red light. Among the photorespiratory intermediates, 14C was more incorporated ito serine under blue light than red light. However, 14C was more incorporated into glycine under red light than blue light. The incorporation of 14C into glycolate was very low under both light qualities, but higher under red light than blue light. Among the enzymes related to photorespiration, only glycolate oxidase was activated and/or synthesized by blue light irradiation. Moreover, more 14C2 was released from glycoate-1-14C under blue light than red light irradiation, but 14C2 release from glyoxylate-1-14C and glycine-1-14C showed no difference by the either light qualities. These results suggest that blue light is more effective in the photorespiratory CO2 evolution than red light. The reason is considered that glycolate is easily metabolized under blue light due to the stimulation of the glycolate oxidase activity.

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The Study of $Eu^{2+}$-activated Calcium Aluminium Silicate Phosphors for White UV-LED (백색 UV-LED를 위한 $Eu^{2+}$-활성화 칼슘 알루미늄 실리케이트 형광체 연구)

  • Hwang, Jung-Ha;Jang, Bo-Yun;Park, Joo-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.32-35
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    • 2006
  • For the white UV-LED applications, $Eu^{2+}$-activated calcium aluminium silicate phosphors were synthesized for the first time and the structures and luminescence characteristics of these phosphors were investigated. The phosphors in this study emitted blue. green or blue-green light depending on the starting materials for synthesis. In addition, the structure was also changed when the different starting materials were used. When CaO and $CaCO_3$ was used as a starting material. tetragonal $Ca_2Al_2SiO_7$ was formed and blue-green and pure green light was emitted. respectively. However. in the case of $CaSiO_3$, triclinic $CaAl_2Si2O_8$ was formed and only pure blue emission was detected. The maximum emission intensity was obtained from $CaAl_2Si_2O_8:Eu^{2+}$ phosphors, which intensity was about 1.4 times higher than that of YAG:$Ce^{3+}$ phosphor used for blue LED.

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Blue light signaling in stomatal guard cells

  • Shimazaki, Ken-ichiro;Michio Doi;Toshinori Kinoshita
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.86-89
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    • 2002
  • Blue light activates proton pump, and creates electrical gradient across the plasma membrane and drives $K^{+}$ uptake in stomatal guard cells. In this presentation, we provide evidence for regulatory mechanisms of the pump and the identification of blue light receptor. The pump is shown to be the plasma membrane H$^{+}$- ATPase and is activated through phosphorylation of the C-terminus. Phosphorylation occurred and 14-3-3 protein bound to the phosphorylation site. The binding of 14-3-3 protein was required for the H$^{+}$-ATPase activation. We also found that phot1 phot2 double mutant does not respond to blue light but other mutants respond to blue light by stomatal opening. However, all these mutants are capable of stomatal opening in the presence of fusicoccin, an activator of the H$^{+}$-ATPase. These results suggest that both photl and phot2 act as blue light receptors in guard cells.d cells.

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Effect of Steam Activation Parameters on Characteristics of Pine Based Activated Carbon

  • Manocha, S.M.;Patel, Hemang;Manocha, L.M.
    • Carbon letters
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    • v.11 no.3
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    • pp.201-205
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    • 2010
  • Activated carbons are well known as adsorbents for gases and vapors. Micro porous carbons are used for the sorption/separation of light gases, whereas, carbon with bigger pore size are applied for removal of large molecules. Therefore, the control of pore size of activated carbon plays a vital role for their use in specific applications. In the present work, steam activation parameters have been varied to control pore size of the resulting activated carbon. It was found that flow rate of steam has profound effect on both surface characteristic and surface morphology. The flow rate of steam was optimized to retain monolith structure as well as higher surface area.

UV Actions in Plant Photomorphogenesis -Induction and Amplification of Anthocyanin Synthesis in Broom Sorghum-

  • Shichijo, Chizuko;Yatsuhashi, Hiroko;Hashimoto, Tohru
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.338-340
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    • 2002
  • In broom sorghum, Sorghum bicolor Moench, UV causes anthocyanin synthesis having action peaks in UVA and UVB regions. We previously reported that UV induces anthocyanin synthesis through UVB photoreceptor and phytochrome activated by UV. Furthermore, UVA and UVB amplify phytochrome-induced anthocyanin synthesis (PIAS). Our action- spectroscopic research indicated that a UV -receptor for amplification of PIAS is likely to be the same or same type of UVB photoreceptor for induction of anthocyanin synthesis. UVA-amplification of PIAS can be explained by the action of a cryptic red light signal (CRS), an amplification factor for PIAS produced by a distinct phytochrome-species activated by UVA. We suggest that UVA photoreceptors are not involved in anthocyanin synthesis in the broom sorghum.

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Effects of Nitric Oxide on Inhibitory Receptors of Rod Bipolar Cells of Rat Retina

  • Park, No-Gi;Bai, Sun-Ho;Jung, Chang-sub;Chun, Mynng-Hoon
    • The Korean Journal of Physiology and Pharmacology
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    • v.9 no.6
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    • pp.347-352
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    • 2005
  • The effects of nitric oxide (NO) on inhibitory neurotransmitter receptors and some types of inhibitory receptors in dissociated rod bipolar cell (RBC) were investigated. In the whole cell voltage-clamping mode, the gamma-aminobutyric acid (GABA) activated current showed both sustained and transient components. GABA activated transient current was fully blocked by bicuculine, a $GABA_A$ receptor antagonist. The cis-4-aminocrotonic acid (CACA), a $GABA_C$ receptor agonist, evoked the sustained current that was not blocked by bicuculline (BIC). Glycine activated the transient current. These results indicate that the RBCs possess $GABA_A$, $GABA_C$, and glycine inhibitory receptors. Sodium nitroprusside (SNP), a NO analogue, reduced the currents activated by $GABA_A$ receptor only, however, did not reduce the currents activated by either $GABA_C$ or glycine receptors. This study signifies further that only NO depresses the fast inhibitory response activated by $GABA_A$ receptor in RBC. We, therefore, postulate that NO might depress the light-on/off transient inhibitory responses in RBCs in the rat retina.

Thermostable Adsorption Filter Immobilized with Super Activated Carbons by Quinoline Soluble Isotropic Pitch Binder (I-a Novel Adsorption Filter)

  • Park, Yeong-Tae;Im, Chul-Gyou;Kim, Yeong-Tae;Rhee, Bo-Sung
    • Carbon letters
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    • v.10 no.3
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    • pp.198-201
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    • 2009
  • Among other filters such as light filter, wave filter, air filter, ultra filter and filter paper, a novel adsorption filter from thermostable polyester nonwoven fabrics immobilized with functional super activated carbon by means of quinoline soluble, activateable isotropic pitch binder were developed in this study. The activated carbon precursor is available in the market branded as coconut shell based activated carbon(CCS-AC) produced by Dongyang Carbon Co. Ltd. BET-surface area of this precursor was $1,355\;m^2/g$, after KOH-activation it increased over $2,970\;m^2/g$ and was named as super activated carbon. In the preliminary research, this precursor was impregnated with $PdCl_2$(0.188 wt%) $KMnO_4$(3 wt%) and redox-agent(CuCl2, 0.577 wt%) in order to promote TOF up to 100/h and Selectivity up 99% and patented as a functional AC for the ethylene adsorption. The enhancement of the isotropic pitch binder to the AC-immobilized adsorption filter was BET-surface area upgraded by $266\;m^2/g$ and promoted the Iodine- and MB-adsorption by 1.4 times, respectively and also micro pore wide ranges < $5{\AA}{\sim}30\;{\AA}$ >.