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http://dx.doi.org/10.5322/JESI.2018.27.11.967

Evaluation of Oxidation Efficiency of Aromatic Volatile Hydrocarbons using Visible-light-activated One-Dimensional Metal Oxide Doping Semiconductor Nanomaterials prepared by Ultrasonic-assisted Hydrothermal Synthesis  

Jo, Wan-Kuen (Department of Environmental Engineering, Kyungpook National University)
Shin, Seung-Ho (Department of Health Environment, Daegu Health College)
Choi, Jeong-Hak (Department of Environmental Engineering, Catholic University of Pusan)
Lee, Joon Yeob (Life Environmental R&D Center, Chemtopia Co. Ltd.)
Publication Information
Journal of Environmental Science International / v.27, no.11, 2018 , pp. 967-974 More about this Journal
Abstract
In this study, we evaluated the photocatalytic oxidation efficiency of aromatic volatile hydrocarbons by using $WO_3$-doped $TiO_2$ nanotubes (WTNTs) under visible-light irradiation. One-dimensional WTNTs were synthesized by ultrasonic-assisted hydrothermal method and impregnation. XRD analysis revealed successful incorporation of $WO_3$ into $TiO_2$ nanotube (TNT) structures. UV-Vis spectra exhibited that the synthesized WTNT samples can be activated under visible light irradiation. FE-SEM and TEM images showed the one-dimensional structure of the prepared TNTs and WTNTs. The photocatalytic oxidation efficiencies of toluene, ethylbenzene, and o-xylene were higher using WTNT samples than undoped TNT. These results were explained based on the charge separation ability, adsorption capability, and light absorption of the sample photocatalysts. Among the different light sources, light-emitting-diodes (LEDs) are more highly energy-efficient than 8-W daylight used for the photocatalytic oxidation of toluene, ethylbenzene, and o-xylene, though the photocatalytic oxidation efficiency is higher for 8-W daylight.
Keywords
$TiO_2$ nanotube; $WO_3$; Photocatalytic oxidation efficiency; Light source;
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1 Ao, C. H., Lee, S. C., 2003, Enhancement effect of $TiO_2$ immobilized on activated carbon filter for the photodegradation of pollutants at typical indoor air level, Applied Catalysis B: Environmental, 44, 191-205.   DOI
2 Ao, C. H., Lee, S. C., Mak, C. L., Chan, L. Y., 2003b, Photocatalyst $TiO_2$ supported on glass fiber for indoor air purification: effect of NO on the photodegradation of CO and $NO_2$, Journal of Photochemistry and Photobiology A: Chemistry, 156, 171-177.   DOI
3 Chen, J., Qiu, F., Xu, W., Cao, S., 2015, Recent progress in enhancing photocatalytic efficiency of $TiO_2$-based materials, Applied Catalysis A, 495, 131-140.   DOI
4 Deosarkar, P., Pawar, S. M., Sonawane, S. H., Bhanvase, B.A., 2013, Process intensification of uniform loading of $SnO_2$ nanoparticles on graphene oxide nanosheets using a novel ultrasound assisted in situ chemical precipitation method, Chemical Engineering and Processing, 70, 48-54.   DOI
5 Deosarkar, M. P., Pawar, S. M., Bhanvase, B. A., 2014, In-situ sonochemical synthesis of $Fe_3O_4$ graphene nanocomposite for lithium rechargeable batteries, Chemical Engineering and Processing, 83, 49-55.   DOI
6 Feng, H., Yu, L. E., Zhang, M. H., 2013, Ultrasonic synthesis and photocatalytic performance of metal-ions doped $TiO_2$ catalysts under solar light irradiation, Materials Research Bulletin, 48, 672-681.   DOI
7 IARC (International Agency for Research on Cancer), 2018, Monographs on the Evaluation of the Carcinogenic Risks to Human, http://monographs.iarc.fr/ENG/Classification/index.php.
8 Kumar, S. G., Rao, K. S. R. K., 2015, Tungsten-based nanomatrials($WO_3&Bi_2WO_6$): Modifications related to charge carrier transfer mechanisms and photcatalytic applications, Applied Surface Science, 355, 939-958.   DOI
9 Kasuga, T., Hiramatsu, M., Hoson, A., Sekino, T., Niihara, K., 1999, Titania nanotubes prepared by chemical processing, Advanced Materials, 11, 1307.   DOI
10 Larson, S. A., Falconer, J. L., 1997, Initial reaction steps in photocatalytic oxidation of aromatics, Catalysis Letters, 44, 57-65.   DOI
11 Lee, J. Y., Hong, W. H., Kim, W., Park, S. H., Jo, W. K., 2017, Visible light-driven decomposition of ${\alpha}$-pinene and toluene over N and Fe dual-doped one-dimensional titania nanostructures with improved efficiency, Materials Research Bulletin, 94, 313-321.   DOI
12 Ochiai, T., Fujishima, A., 2012, Photoelectrochemical properties of $TiO_2$ photocatalyst and its applications for environmental purification, Journal of Photochemistry and Photobiology C, 13, 247-262.   DOI
13 Patel, M. A., Bhanvase, B. A., Sonawane, S. H., 2013, Production of cerium zinc molybdate nano pigment by innovative ultrasound-assisted approach, Ultrasonics Sonochemistry, 20, 906-913.   DOI
14 Remskar, M., 2004, Inorganic Nanotubes, Advanced Materials, 16, 1497.   DOI
15 Riboni, F., Bettini, L. G., Bahnemann, D. W., Selli, E., 2013, $WO_3-TiO_2$ vs. $TiO_2$ photocatalyst: Effect of th W precursors and amount on the photocatalytic activity of mixed oxides, Catalysis Today, 209, 28-34.   DOI
16 Yao, B. D., Chan, Y. F., Zhang, X. Y., Zhang, W. F., Yang, Z. Y., Wang, N., 2003, Applied Physics Letters, 82(2), 281.   DOI
17 SU, F. C., Mukherjee, B., Batterman, S., 2013, Determinations of personal, indoor and outdoor VOC concentrations: An analysis of the RIOPA data, Environmental Research, 126, 192-203.   DOI
18 Wei, X., Wang, H., Zhu, G., Chen, J., Zhu, L., 2013, Iron-doped $TiO_2$ nanotubes with high photocatalytic activity under visible light synthesized by an ultrasonic-assisted sol-hydrothermal method, Ceramics International, 39, 4009-4016.   DOI