• 한국가스학회지
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• 제2권4호
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• pp.47-52
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• 1998

수냉식 흡수식 냉동기에 주로 사용되고 있는 LiBr/water 흡수용액을 대체할 수 있는 신흡수 용액으로 제안된 흡수용액중 4성분계 흡수용액($LiBr+LiNO_3+LiC1+H_2O$)의 수증기 흡수성능을 수직관 흡수기를 사용하여 시험하였다. 시험변수로는 입구농도, 입구온도, 냉각수 입구온도, 용액유량을 변경하였다. 수증기 흡수특성 시험 결과 4성분계 용액이 LiBr/water용액보다 $2\%$ 높은 농도에서 대둥한 흡수력을 가짐을 알 수 있었다. 그러나 4성분계 흡수용액이 LiBr/water용액보다 $3\%$정도 용해도가 높으므로 실제 흡수식 냉동기에 적용시 LiBr용액보다 우수한 흡수능력을 가질 수 있어 소형, 공냉형 흡수식 냉동기에 적용이 가능하다.

• 설비공학논문집
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• 제8권4호
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• pp.463-472
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• 1996

Experiments were carried out to study the operation characteristics of a regenerator with a thermo-syphon pump and a surface-flame burner for a lithium bromide (LiBr)-water absorption heat pump. A cylindrical-shape metal-fiber burner and commercial grade propane were used. The emission of carbon monoxide and nitric oxide was measured by a combustion gas analyzer. Ther regeneration rate of water vapor as a refrigerant was measured. It could be as a reference value showing the performance of the regenerator. The circulation rate of the LiBr-water solution was also measured from both the tanks for the weak-and the strong-solution. Using a refractometer, the LiBr concetration in the solution was calculated from the measured refractory index of the solution. Temperature of the solution and the condensed water was recorded at several points in the experimental apparatus with thermocouples, using a personal computer. This data collecting system for measuring temperature was calibrated with a set of standard thermometers. The generating rate of water vapor as refrigerant increased linearly with heat supplied. It was about 4.0g/s with the heat supplied at a rate of 16,500kcal/h. The circulation rate of LiBr solution also increases with the heat supplied. The difference in LiBr concentrations between the weak and the strong solution was in the range of 1 to 5% when the concentration of the strong solution was about 60%. It was dependent upon both the heat supplied and the circulation rate of the solution. The initial concentration and the level of the LiBr solution in the regenerator were measured and recorded before experiments. The effect of them on the generating rate of water vapor and the circulation rate of the solution was also studied. The generating rate of water vapor was not strongly dependent upon both the level of the LiBr solution and the initial LiBr concentration. However, the concentration difference of the solution increases with the initial level of the LiBr solution.

• 대한기계학회논문집B
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• 제26권9호
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• pp.1241-1248
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• 2002

Performance extension of the absorption refrigerator with LiBr solution is often faced to operate very close to the crystallization limit. Especially in the development of an air-cooled cycle, the crystallization of working solution in the system is a very difficult problem to overcome. This paper describes the cycle of hot water driven absorption system using a new working absorption solution instead of LiBr solution to improve the efficiency. In this study, we found out the characteristics of new working absorption solution through the cycle simulation and compared LiBr solution to evaluate. The effect of cooling water temperature, weak solution flow rate, hot water temperature and hot water flow rate were also examined. The COP is increased 22% higher in the case of LiBr＋Li1＋LiC1＋LiNO$_3$＋$H_2O$, 2% LiBr＋HO(CH$_2$)$_3$OH＋$H_2O$ than that of LiBr solution for the same operation condition.

• 설비공학논문집
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• 제7권2호
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• pp.196-206
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• 1995

Experimental investigations on heat and mass transfer characteristics in a vertical tube absorber have been carried out. Three different copper tubes with a length of 1.5m have been tested using LiBr solution and LiBr-$CaCl_2$ solution. The effects of solution flow rate, cooling water temperature, solution inlet temperature and evaporation temperature have been investigated in detail. It is found that heat transfer coefficient increases gradually with the increase of solution flow rate, but decreases rapidly for the flow rates less than 0.02kg/ms. The grooved tube generally shows better heat transfer performances than the smooth tube. LiBr solution shows almost no absorption capability for the cooling water temperatures over $40^{\circ}C$. LiBr-$CaCl_2$ gives less decreasing rate in absorption capability at these temperatures and the heat transfer coefficient becomes less dependent on the types of tubes in use. Considering heat and mass transfer rates, LiBr-$CaCl_2$ solution is found to be more suitable than LiBr solution for air cooled absorber, which operates at higher temperature than water cooled absorber.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2001년도 춘계학술대회 논문집
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• pp.95-99
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• 2001

As a way to use energy effectively, the present study is aimed at investigating the performance characteristics of a Single Effect LiBr/Water Absorption Refrigerator using a low temperature driving heat-source. It was carried out by changing the driving heat-source temperature, the cold water outlet temperature(the refrigeration load), the cooling water inlet temperature, and the weak solution flow rate and this study compares the performance characteristics of refrigerator against the existence and non-existence of the Recirculation of the Weak solution which is used as a method to improve the performance of refrigerator. In case of Recirculation of the weak solution, more improved the Refrigeration Capacity and COP was obtained, and these effects became more larger in the high temperature of driving heat-source and large quantity of solution.

• 한국태양에너지학회 논문집
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• 제25권3호
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• pp.27-35
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• 2005

In this paper, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system with water-LiBr-LiSCN mixture which utilizes solar energy as evaporator heat source. In addition, a comparative study of the water-LiBr-LiSCN mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiBr-LiSCN mixture than for the water-LiBr pair, and FR is lower for the former.

• 한국태양에너지학회 논문집
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• 제26권4호
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• pp.73-81
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• 2006

In this paper, with water-LiBr-LiSCN mixture which utilizes solar energy as mid temperature range evaporator heat source, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system. A comparative study of the water-LiBr-LiSCN mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiBr-LiSCN mixture than for the water-LiBr pair, and FR is lower for the former.

• 대한기계학회논문집B
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• 제28권1호
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• pp.81-88
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• 2004

In this study, heat and mass transfer characteristics of five components solution (LiBr＋Lil＋LiNO$_3$＋LiCl＋$H_2O$) which could be substituted for commonly used LiBr solution are tested using a helical absorber. The arrangement of helical-typed heat exchangers allows to make the system more compact as compared to conventional one. The effects of experimental parameters, such as the solution flow rate, cooling water, solution temperature, solution concentration and surfactant have been investigated in view of the heat and mass transfer. The results of the experiment of heat and mass transfer performance show that five components solution should have 2％ higher concentration fur equal absorption capacity of LiBr solution. But considering that five components solution have higher solubility than LiBr solution about 4％ high concentration, five components solution could be applied to a small sized water cooled or air cooled absorption chiller/heater. The increase of heat and mass transfer coefficient by surfactant addition is about 25∼30％ and 23∼40％ respectively.

• 설비공학논문집
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• 제9권2호
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• pp.163-170
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• 1997

Solubility on $(LiBr+CaCl_2)$ in water has been measured systematically and compared with those of pure LiBr. It has been observed that there exists optimum value of $CaCl_2(LiBr+CaCl_2)$ in solubility when total$(LiBr+CaCl_2)$ concentration is higher than 57wt%. As total concentration increases up to 65wt%, it is found that the optimum value also increases monotonically. From the experimental results, a master plot has been constructed, with which optimum ratio of LiBr to $CaCl_2$ can be found in terms of total concentration. Vapor pressure of $H_2O/(LiBr+CaCl_2)$ solution with optimum contents of $CaCl_2$ has been observed to be changed negligibly at relatiely low temperature. However, as temperature increases, it is found that increasement in vapor pressure is significant.

• Journal of Advanced Marine Engineering and Technology
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• 제26권1호
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• pp.125-131
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• 2002

This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the fresh water and 62 % lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze was carried out. And polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: (1) As the experimental temperature increase, the change of corrosion rate of Al-Ni bronze become duller than SS 400 and Cu in 62% lithium bromide solution. (2) According as corrosion environment is changed from fresh water to 62% lithium bromide solution, potential change of Cu and Al-Ni bronze become less noble than SS 400. (3) The corrosion sensitivity of Al-Ni bronze was duller than that of Cu and SS 400 in 62% LiBr solution.