• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.3
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• pp.585-593
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• 2020

Until now, 29 fire accidents have occurred; 22 of them were caused by the interconnection of renewable energy sources that occurred during the rest period after the lithium-ion battery had been fully charged regardless of the seasons. The fire accidents of ESS were attributed to thermal runaway due to the overcharging of a few cells with the phenomenon of self-energy balancing, which is unintentional current flow from cells with a high SOC to the low cells if the SOC condition of each cell connected in parallel is different. Therefore, this paper proposes a novel configuration and operation algorithm of the BMS to prevent the self-energy balancing of ESS and presents a hybrid SOC estimation algorithm. From the test results of the self-energy balancing phenomenon between aging and normal cells based on the proposed algorithm and BMS, it was confirmed the possibility of self-energy balancing, which is unintentional current flow from cells with a high SOC to cells with a low SOC. In addition, the proposed configuration of the BMS is useful and practical to improve the safety of lithium-ion batteries because the BMS can reliably disconnect a parallel connection of the cells if the self-energy balancing current becomes excessively high.

• IEMEK Journal of Embedded Systems and Applications
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• v.15 no.5
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• pp.215-225
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• 2020

Light detection and ranging (LiDAR) sensors detect the distance of the surrounding environment and objects. Conventional LiDAR sensors require a certain amount of a power because they detect objects by transmitting lasers at a regular interval depending on a constant resolution. The constant power consumption from operating multiple LiDAR sensors is detrimental to autonomous and electric vehicles using battery power. In this paper, we propose two algorithms that improve the inefficient power consumption during the constant operation of LiDAR sensors. LiDAR sensors with algorithms efficiently reduce the power consumption in two ways: (a) controlling the resolution to vary the laser transmission period (T_P) of a laser diode (LD) depending on the vehicle's speed and (b) reducing the static power consumption using a sleep mode depending on the surrounding environment. A proposed LiDAR sensor with a resolution control algorithm reduces the power consumption of the LD by 6.92% to 32.43% depending on the vehicle's speed, compared to the maximum number of laser transmissions (N_x·max). The sleep mode with a surrounding environment-sensing algorithm reduces the power consumption by 61.09%. The proposed LiDAR sensor has a risk factor for 4-cycles that does not detect objects in the sleep mode, but we consider it to be negligible because it immediately switches to an active mode when a change in surrounding conditions occurs. The proposed LiDAR sensor was tested on a commercial processor chip with the algorithm controlling the resolution according to the vehicle's speed and the surrounding environment.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.541-547
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• 2011

Nanorod-clustered $MnO_2$ precursors with ${\alpha}$-, ${\beta}$-, and ${\gamma}$-phases are synthesized by hydrothermal reaction of $MnSO_45H_2O$ and $(NH_4)S_2O_8$. The formation of nanorod-clustered ${\beta}-MnO_2$ is particularly confirmed under the conditions of high reactant concentration and hydrothermal reaction at $150^{\circ}C$. The spinel $LiMn_2O_4$ nanorod-clusters are also prepared by lithiating the $MnO_2$ precursors, varying the concentration of lithiating agent ($LiC_3H_3O_2{\cdot}2H_2O$) and heat treatment temperature, and characterized for use as cathode material of lithium-ion batteries. As a result, the nanorod-clustered $LiMn_2O_4$ prepared from the ${\beta}-MnO_2$ at higher $LiC_3H_3O_2{\cdot}2H_2O$ concentration and the annealing at $800^{\circ}C$ is proven to show the cubic spinel structure and to achieve the high initial discharge capacity of 120 mAh/g.

• Clean Technology
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• v.28 no.2
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• pp.97-102
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• 2022

Lithium sulfur (Li-S) batteries have attracted considerable attention as a promising candidate for next-generation power sources due to their high theoretical energy density, low cost, and eco-friendliness. However, the poor electrical conductivity of sulfur and its insoluble discharging products (Li₂S₂/Li₂S), large volume changes, severe self-discharge, and dissolution of lithium polysulfide intermediates result in rapid capacity fading, low Coulombic efficiency, and safety risks, hindering Li-S battery commercial development. In this study, a three-dimensionally (3D) connected hierarchical porous carbon framework (HPCF) derived from waste sunflower seed shells was synthesized as a sulfur host for Li-S batteries via a chemical activation method. The natural 3D connected structure of the HPCF, originating from the raw material, can effectively enhance the conductivity and accessibility of the electrolyte, accelerating the Li⁺/electron transfer. Additionally, the generated micropores of the HPCF, originated from the chemical activation process, can prevent polysulfide dissolution due to the limited space, thereby improving the electrochemical performance and cycling stability. The HPCF/S cell shows a superior capacity retention of 540 mA h g^-1 after 70 cycles at 0.1 C, and an excellent cycling stability at 2 C for 700 cycles. This study provides a potential biomass-derived material for low-cost long-life Li-S batteries.

• Journal of the Korean Electrochemical Society
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• v.4 no.3
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• pp.98-103
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• 2001

The electrochemical characteristics and specific capacitance were investigated by preparation processes (dip coating method, doctor blade coating method and paste rolling method) of activated carbon electrode for an EDLC(electric double layer capacitor). The EDLC using $LiPF_6$ salts and PC-DEC solvents showed good specific capacitance, 130F/g and small IR-drop at linear time-voltage curve. 0.11V, Cyclic voltammetry analysis using the activated carbon electrode prepared by dip coating method was shown closer to ideal EDLC characterization.

• Journal of Electrochemical Science and Technology
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• v.9 no.3
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• pp.176-183
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• 2018

In this study, a $Li_2ZrO_3$ coated $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ (NCA) cathode was applied to an all-solid-state cell employing a sulfide-based solid electrolyte. Sulfide-based solid electrolytes are preferable for all-solid-state cells because of their high ionic conductivity and good softness and elasticity. However, sulfides are very reactive with oxide cathodes, and this reduces the stability of the cathode/electrolyte interface of all-solid-state cells. $Li_2ZrO_3$ is expected to be a suitable coating material for the cathode because it can suppress the undesirable reactions at the cathode/sulfide electrolyte interface because of its good stability and high ionic conductivity. Cells employing $Li_2ZrO_3$ coated NCA showed superior capacity to those employing pristine NCA. Analysis by X-ray photoelectron spectroscopy and electron energy loss spectroscopy confirmed that the $Li_2ZrO_3$ coating layer suppresses the propagation of S and P into the cathode and the reaction between the cathode and the sulfide solid electrolyte. These results show that $Li_2ZrO_3$ coating is promising for reducing undesirable side reactions at the cathode/electrolyte interface of all-solid-state-cells.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.547-552
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• 2019

Electrochemical properties of $LiMn_{0.8}Fe_{0.2}PO_4$ cathode were investigated with gel polymer electrolyte (GPE). To access fast and efficient transport of ions and electrons during the charge/discharge process, a pure and well-crystallized $LiMn_{0.8}Fe_{0.2}PO_4$ cathode material was directly synthesized via spray-pyrolysis method. For high operation voltage, polyacrylonitrile (PAN)-based gel polymer electrolyte was then prepared by electrospinning process. The gel polymer electrolyte showed high ionic conductivity of $2.9{\times}10^{-3}S\;cm^{-1}$ at $25^{\circ}C$ and good electrochemical stability. $Li/GEP/LiMn_{0.8}Fe_{0.2}PO_4$ cell delivered a discharge capacity of $159mAh\;g^{-1}$ at 0.1 C rate that was close to the theoretical value ($170mAh\;g^{-1}$). The cell allows stable cycle performance (99.3% capacity retention) with discharge capacity of $133.5mAh\;g^{-1}$ for over 300 cycles at 1 C rate and exhibits high rate-capability. PAN-based gel polymer is a suitable electrolyte for application in $LiMn_{0.8}Fe_{0.2}PO_4/Li$ batteries with perspective in high energy density and safety.

• Applied Chemistry for Engineering
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• v.7 no.3
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• pp.433-442
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• 1996

Electrochemical characteristics and physical properties of polymer electrolyte which immobilized lithium salts such as $LiClO_4$ and $LiCF_3SO_3$ and plasticizers such as ethylene carbonate(EC) and propylene carbonate(PC) in high molecular weight poly(ethylene oxide)[PEO] polymer was investigated. PEO-Li based polymer electrolyte with plasticizers showed ionic conductivity of $10^{-4}S/cm$ at room temperature and high electrochemical stability up to 4.5 V(vs. $Li^+/Li$), so it can be applied to lithium secondary battery. The crystallinity of PEO decreased with the addition of lithium salts and plasticizers, especially $LiClO_4$ and PC showed more effective than and $LiCF_3SO_3$ and EC. Glass transition temperature($T_g$) of polymer electrolyte increased with increasing lithium salt concentration whereas melting temperature ($T_m$) decreased. Polymer electrolyte with plasticizers crystallized at $6^{\circ}C$.

• Journal of Electrochemical Science and Technology
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• v.2 no.2
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• pp.103-109
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• 2011

Nanocrystalline $LiFePO_4$ powders were prepared at 660-$670^{\circ}C$ in an Ar atmosphere using two different synthetic routes, solid-state and sol-gel. Both materials showed well-developed XRD patterns without any impurity peaks. Particles composed in the range of 200-300 nm from the solid-state method, and 50-100 nm from the sol-gel method, were confirmed through scanning electron microscopy and dynamic light scattering. The $LiFePO_4$ obtained by the sol-gel method offered a high discharge capacity (153 mAh/g) and stable discharge behavior, even at elevated temperatures (50 and $60^{\circ}C$), whereas poor electrochemical performance was observed from the solid-state method. Rate capability studies for sol gel-derived $LiFePO_4$ ranged from 0.2 to 30 C, which revealed excellent retention over 70 cycles with a 99.9% capacity.

• The Transactions of the Korean Institute of Power Electronics
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• v.24 no.4
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• pp.268-272
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• 2019

A lithium polymer battery-based 9 kJ/s high-voltage capacitor charger, which comprises two stages, is proposed. A modified LCC resonant converter and resonant circuit are introduced at the first and second stages, respectively. In the first stage, the methods for handling low-voltage and high-current batteries are considered. Delta-wye three-phase transformers are used to generate a high output voltage through the difference between the phase and line-to-line voltages. Another method is placing the series resonant capacitor of the LCC resonant components on the transformer secondary side, which conducts considerably low current compared with the transformer primary side. On the basis of the stable operation of the first charging stage, the secondary charging stage generates final output voltage by using the resonance. This additional stage protects the rectifying diodes from the negative voltage when the output capacitor is discharged for a short time. The inductance and capacitance of the resonance components are selected by considering the resonance charging time. The design procedure for each stage with the aforementioned features is suggested, and its performance is verified by not only simulation but also experimental results.