• 제목/요약/키워드: Li reduction

검색결과 738건 처리시간 0.026초

Temperature Dependent Terahertz Generation at Periodically Poled Stoichiometric Lithium Tantalate Crystal Using Femtosecond Laser Pulses

  • Yu, N.E.;Kang, C.;Yoo, H.K.;Jung, C.;Lee, Y.L.;Kee, C.S.;Ko, D.K.;Lee, J.
    • Journal of the Optical Society of Korea
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    • 제12권3호
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    • pp.200-204
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    • 2008
  • Coherent tunable terahertz generation was demonstrated in periodically poled stoichiometric lithium tantalate crystal via difference frequency generation of femtosecond laser pulses. Simultaneous forward and backward terahertz radiations were obtained around 1.35 and 0.63 THz, respectively at low temperature. By cooling the crystal to reduce losses caused by phonon absorptions, the generated THz bandwidth was as narrow as 23GHz at the center frequency of 0.63 THz. The measurement result of temperature-dependent showed gradual intensity increase of the generated terahertz pulse and red shift of the center frequency as the temperature decrease from 291 to 143 K, but insignificant reduction of the spectral bandwidth. Furthermore, the stoichiometric crystal was very suitable for the suppression of THz loss at low temperature compared to the congruent $LiNbO_3$ crystal.

산소량에 따른 $SnO_x$ 박막의 음극 특성 (Anode Characteristics of $SnO_x$ Films with Various Oxygen Contents)

  • 문희수;성상현;김영일;박종완
    • 전기화학회지
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    • 제3권3호
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    • pp.178-181
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    • 2000
  • 본 실험에서는 리튬 이차 박막전지의 음극물질로 주석 산화물 박막을 RF magnetron sputter을 이용하여 증착하였다. RF power와 공정 압력을 각각 $2.5W/cm^2$와 10mTorr로 고정시키고 박막 중의 산소량을 조절하기 위해 산소 분압을 $0\~100\%$까지 조절하여 실험하였으며, 산소량을 더 줄이기 위해 주석 금속 칩을 사용하여 조절하였다. 산소량을 줄여 줌으로써 비가역적으로 형성되는 리튬산화물의 량을 줄이고 고용량의 $SnO_x$음극 박막을 제조하였다. 그 중 $SnO_{1.43}$일 때 가장 큰 가역용량(약$ 500{\mu}Ah/cm^2{\mu}m$) 얻었다.

Energy Efficient Sequential Sensing in Multi-User Cognitive Ad Hoc Networks: A Consideration of an ADC Device

  • Gan, Xiaoying;Xu, Miao;Li, He
    • Journal of Communications and Networks
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    • 제14권2호
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    • pp.188-194
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    • 2012
  • Cognitive networks (CNs) are capable of enabling dynamic spectrum allocation, and thus constitute a promising technology for future wireless communication. Whereas, the implementation of CN will lead to the requirement of an increased energy-arrival rate, which is a significant parameter in energy harvesting design of a cognitive user (CU) device. A well-designed spectrum-sensing scheme will lower the energy-arrival rate that is required and enable CNs to self-sustain, which will also help alleviate global warming. In this paper, spectrum sensing in a multi-user cognitive ad hoc network with a wide-band spectrum is considered. Based on the prospective spectrum sensing, we classify CN operation into two modes: Distributed and centralized. In a distributed network, each CU conducts spectrum sensing for its own data transmission, while in a centralized network, there is only one cognitive cluster header which performs spectrum sensing and broadcasts its sensing results to other CUs. Thus, a wide-band spectrum that is divided into multiple sub-channels can be sensed simultaneously in a distributed manner or sequentially in a centralized manner. We consider the energy consumption for spectrum sensing only of an analog-to-digital convertor (ADC). By formulating energy consumption for spectrum sensing in terms of the sub-channel sampling rate and whole-band sensing time, the sampling rate and whole-band sensing time that are optimal for minimizing the total energy consumption within sensing reliability constraints are obtained. A power dissipation model of an ADC, which plays an important role in formulating the energy efficiency problem, is presented. Using AD9051 as an ADC example, our numerical results show that the optimal sensing parameters will achieve a reduction in the energy-arrival rate of up to 97.7% and 50% in a distributed and a centralized network, respectively, when comparing the optimal and worst-case energy consumption for given system settings.

Knockdown of microtubule actin crosslinking factor 1 inhibits cell proliferation in MC3T3-E1 osteoblastic cells

  • Hu, Lifang;Su, Peihong;Li, Runzhi;Yan, Kun;Chen, Zhihao;Shang, Peng;Qian, Airong
    • BMB Reports
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    • 제48권10호
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    • pp.583-588
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    • 2015
  • Microtubule actin crosslinking factor 1 (MACF1), a widely expressed cytoskeletal linker, plays important roles in various cells by regulating cytoskeleton dynamics. However, its role in osteoblastic cells is not well understood. Based on our previous findings that the association of MACF1 with F-actin and microtubules in osteoblast-like cells was altered under magnetic force conditions, here, by adopting a stable MACF1-knockdown MC3T3-E1 osteoblastic cell line, we found that MACF1 knockdown induced large cells with a binuclear/multinuclear structure. Further, immunofluorescence staining showed disorganization of F-actin and microtubules in MACF1-knockdown cells. Cell counting revealed significant decrease of cell proliferation and cell cycle analysis showed an S phase cell cycle arrest in MACF1-knockdown cells. Moreover and interestingly, MACF1 knockdown showed a potential effect on cellular MTT reduction activity and mitochondrial content, suggesting an impact on cellular metabolic activity. These results together indicate an important role of MACF1 in regulating osteoblastic cell morphology and function.

Elastic modulus of ASR-affected concrete: An evaluation using Artificial Neural Network

  • Nguyen, Thuc Nhu;Yu, Yang;Li, Jianchun;Gowripalan, Nadarajah;Sirivivatnanon, Vute
    • Computers and Concrete
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    • 제24권6호
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    • pp.541-553
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    • 2019
  • Alkali-silica reaction (ASR) in concrete can induce degradation in its mechanical properties, leading to compromised serviceability and even loss in load capacity of concrete structures. Compared to other properties, ASR often affects the modulus of elasticity more significantly. Several empirical models have thus been established to estimate elastic modulus reduction based on the ASR expansion only for condition assessment and capacity evaluation of the distressed structures. However, it has been observed from experimental studies in the literature that for any given level of ASR expansion, there are significant variations on the measured modulus of elasticity. In fact, many other factors, such as cement content, reactive aggregate type, exposure condition, additional alkali and concrete strength, have been commonly known in contribution to changes of concrete elastic modulus due to ASR. In this study, an artificial intelligent model using artificial neural network (ANN) is proposed for the first time to provide an innovative approach for evaluation of the elastic modulus of ASR-affected concrete, which is able to take into account contribution of several influence factors. By intelligently fusing multiple information, the proposed ANN model can provide an accurate estimation of the modulus of elasticity, which shows a significant improvement from empirical based models used in current practice. The results also indicate that expansion due to ASR is not the only factor contributing to the stiffness change, and various factors have to be included during the evaluation.

H2/Air 비예혼합화염의 화염신장율에 따른 NO 생성경로의 상세해석 (Detailed Analysis of NO Formation Routes with Strain Rate in H2/Air Nonpremixed Flames)

  • 김종현;황철홍;이창언
    • 대한기계학회논문집B
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    • 제32권8호
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    • pp.604-611
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    • 2008
  • Detailed analysis of NO formation routes and its contributions with strain rate in hydrogen/air flames were numerically investigated. LiG detailed reaction mechanism has been used for calculation, which is compared with experimental data in literature. It shows good agreement with experiment for both temperature and NO mole fraction. Three routes have been found important for NO formation in hydrogen flames. These are the Thermal route, NNH route and $N_2O$ route. Strain rate were varied to discuss the $EI_{NO}$ reduction trend in hydrogen nonpremixed flames, which are analyzed by each NO formation routes. As a result, as the strain rate increase, $EI_{NO}$ decrease sharply until strain rate $100s^{-1}$ and decrease slowly until strain rate $310s^{-1}$ again, after that $EI_{NO}$ keeps nearly constant. It can be identified that $EI_{NO}$ trend with the strain rate is well explained by a combination of variation of production rate of above Thermal, NNH and $N_2O$ route. Also result of Thermal-Mech. that includes only thermal NO reaction is compared with those of Full-Mech. As a result, It can be identified that there was difference between the two results of calculation. It is attributed to result that Thermal-mech did not consider contributions of NNH and $N_2O$ route. From these result, we can conclude that NOx emission characteristics of hydrogen nonpremixed flames should consider contributions of above three routes simultaneously.

증착 온도에 따른 IZO 박막의 구조적 및 전기적 특성 (Structural and electrical characteristics of IZO thin films with deposition temperature)

  • 전대근;이유림;이규만
    • 반도체디스플레이기술학회지
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    • 제10권3호
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    • pp.67-74
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    • 2011
  • In this study, we have investigated the effect of the substrate temperature on the structural and the electrical characteristics of IZO thin films for the OLED (organic light emitting diodes) devices. For this purpose, IZO thin films were deposited by RF magnetron sputtering under various substrate temperature. The substrate temperature has been changed from room temperature to $400^{\circ}C$. Samples which were deposited under $250^{\circ}C$ show amorphous structure. The electrical resistivity of crystalline-IZO (c-IZO) film was higher than that of amorphous-IZO (a-IZO) film. And the electrical resistivity showed minimum value near $150^{\circ}C$ of deposition temperature. The OLED device was fabricated with different IZO substrates made by configuration of IZO/$\acute{a}$-NPD/DPVB/$Alq_3$/LiF/Al to elucidate the performance of IZO substrate. OLED devices with the amorphous-IZO (a-IZO) anode film show better current density-voltage-luminance characteristics than that of OLED devices with the commercial crystalline-ITO (c-ITO) anode film. It can be explained that very flat surface roughness and high work function of a-IZO anode film lead to more efficient hole injection by reduction of interface barrier height between anode and organic layers. This suggests that a-IZO film is a promising anode materials substituting conventional c-ITO anode in OLED devices.

저강도 타이치 운동이 시설거주노인의 체력, 골밀도 및 골절위험도에 미치는 효과 (Effects of Tai Chi Exercise on Physical Fitness, Bone Mineral Density, and Fracture Risk in Institutionalized Elderly)

  • 김현리;소희영;송라윤
    • 기본간호학회지
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    • 제17권3호
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    • pp.334-342
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    • 2010
  • Purpose: The purpose of this study was to examine the effects of Tai Chi exercise on flexibility, balance, walking ability, muscle strength, bone mineral density, and fracture risk in institutionalized elders. Method: A quasi-experimental pretest-posttest design with a nonequivalent comparison group was utilized, and 53 older adults living in one institution were recruited and assigned to one of two groups, experimental group (18) or comparison (20). Both groups completed posttest measures at 6 months. There was a 31% rate of dropouts. Tai Chi exercise was provided twice a week for 24 weeks. Outcome measurements were conducted by a physiotherapist at a university hospital health promotion center who did not know the group assignment. Results: At 6 months, the experimental group had significantly greater grip strength(t=2.12, p=.04), back muscle strength (t=2.42, p=.02), balance (t=5.31, p<001), and flexibility (t=3.57, p<.001). They also showed significantly greater bone mineral density of lumbar spine and femur, and reduced fracture risk. Conclusion: Tai Chi exercise was safely and effectively used with institutionalized elders for 6 months and significantly improved physical fitness, bone mineral density along with a reduction in fracture risk. Whether Tai Chi exercise would lead to prevention of fall episodes and fall related fractures in this population will require further study.

Electrochemistry of Hemoglobin in the Chitosan and TiO2 Nanoparticles Composite Film Modified Carbon Ionic Liquid Electrode and Its Electrocatalysis

  • Sun, Wei;Li, Xiaoqing;Liu, Shufeng;Jiao, Kui
    • Bulletin of the Korean Chemical Society
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    • 제30권3호
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    • pp.582-588
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    • 2009
  • Direct electron transfer of hemoglobin (Hb) in the chitosan (CTS) and $TiO_2$ nanoparticles (nano-$TiO_2$) composite films was achieved by using a room temperature ionic liquid of 1-butyl-3-methylimidazolium hexafluorophosphate ($BMIMPF_6$) modified carbon paste electrode (CILE) as the basal electrode. UV-Vis and FT-IR spectroscopy indicated that Hb in the film retained the native structure. Electrochemical investigation indicated that a pair of well-defined quasi-reversible redox peaks of Hb heme Fe(III)/Fe(II) was obtained with the formal potential located at -0.340 V (νs. SCE) in pH 7.0 phosphate buffer solution (PBS). The electrochemical parameters such as the electron transfer coefficient (α), the electron transfer number (n) and the standard electron transfer rate constant ($k_s$) were got as 0.422, 0.93 and 0.117 $s^{-1}$, respectively. The fabricated CTS/nano-$TiO_2$/Hb/CILE showed good electrocatalytic ability to the reduction of trichloroacetic acid (TCA) and hydrogen peroxide ($H_2O_2$), which exhibited a potential application in fabricating a new kind of third generation biosensor.

The Complete Oxidation of Ethanol at Low Temperature over a Novel Pd-Ce/γ-Al2O3-TiO2 Catalyst

  • Wang, Yanping;Zhao, Jinshuang;Wang, Xiaoli;Li, Zhe;Liu, Pengfei
    • Bulletin of the Korean Chemical Society
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    • 제34권8호
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    • pp.2461-2465
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    • 2013
  • Pd-$Ce/{\gamma}-Al_2O_3-TiO_2$ catalysts were prepared by combined sol-gel and impregnation methods. Transmission electron microscopy, X-ray diffraction, $H_2$-temperature-programmed reduction, $O_2$-temperature-programmed desorption, and ethanol oxidation experiments were conducted to determine the properties of the catalysts. Addition of an optimal amount of Ce improved the performance of the $Pd/{\gamma}-Al_2O_3-TiO_2$ catalyst in promoting the complete oxidation of ethanol. The catalyst with 1% Ce exhibited the highest activity, and catalyzed complete oxidation of ethanol at $175^{\circ}C$; its selectivity to $CO_2$ reached 87%. Characterization results show that addition of appropriate amount of Ce could enrich the PdO species, and weaken the Pd-O bonds, thus enhancing oxidation ability of the catalyst. Meanwhile, the introduction of $CeO_2$ could make PdO better dispersed on ${\gamma}-Al_2O_3-TiO_2$, which is beneficial for the improvement of the catalytic oxidation activity.