• 제목/요약/키워드: Li reduction

검색결과 738건 처리시간 0.028초

Slender RC columns strengthened with combined CFRP and steel jacket under axial load

  • Lu, Yi-yan;Li, Na;Li, Shan;Ou, Tian-yan
    • Steel and Composite Structures
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    • 제19권5호
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    • pp.1077-1094
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    • 2015
  • This paper presents an experimental study on the effectiveness of simultaneous application of carbon fiber-reinforced polymer (CFRP) and steel jacket in strengthening slender reinforced concrete (RC) column. The columns were 200 mm square cross section with lengths ranging from 1600 to 3000 mm. Ten columns were tested under axial load. The effects of the strengthening technique, slenderness ratio, cross-section area of steel angle and CFRP layer number were examined in terms of axial load-axial strain curve, CFRP strain, steel strip strain and steel angle strain. The experiments indicate that strengthening RC columns with combined CFRP and steel jacket is effective in enhancing the load capacity, ductility and energy dissipation capacity of RC column. Based on the existing models for RC columns strengthened with CFRP and with steel jacket, a design formula considering a slenderness reduction factor is proposed to predict the load capacity of the RC columns strengthened with combined CFRP and steel jacket. The predictions agree well with the experimental results.

Effect of Neutral Solvent on the Phase Behavior of Polystyrene-block-Poly(n-butyl methacrylate) Copolymers

  • Li, Chaoxu;Li, Guang-Hua;Moon, Hong-Chul;Lee, Dong-Hyun;Kim, Jin-Kon;Cho, Jun-Han
    • Macromolecular Research
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    • 제15권7호
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    • pp.656-661
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    • 2007
  • The effects of a neutral solvent of dioctyl phthalate (DOP) on the phase behavior of symmetric polystyrene-block-poly(n-butyl methacrylate) copolymers (PS-b-PnBMA) were assessed herein. Closed-loop phase behavior with a lower disorder-to-order transition (LDOT) and an upper order-to-disorder transition (UODT) was observed for PS-b-PnBMA/DOP solution when the quantity of DOP was carefully controlled. When the molecular weight of PS-b-PnBMA became larger, the LDOT did not appreciably change at smaller quantities of DOP. With larger quantities of DOP, the reduction in the UODT is greater than the increase in the LDOT. This behavior is discussed in accordance with a molecular theory predicated on a compressible random-phase approximation.

Binder-free Sn/Graphene Nanocomposites Prepared by Electrophoretic Deposition for Anode Materials in Lithium Ion Batteries

  • Bae, Eun Gyoung;Hwang, Yun-Hwa;Pyo, Myoungho
    • Bulletin of the Korean Chemical Society
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    • 제34권4호
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    • pp.1199-1204
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    • 2013
  • Nanocomposites consisting of Sn nanoparticles and graphene oxide (GO) were electrophoretically deposited onto Cu current collectors that was used for anodes in Li ion batteries (LIBs). In order to optimize the electrochemical performance of nanocomposites as an anode material by controlling the oxygen functionality, the GO was subjected to $O_3$ treatment prior to electrophoretic deposition (EPD). During thermal reduction of the GO in the nanocomposites, the Sn nanoparticles were reduced in size, along with the formation of SnO and/or $SnO_2$ at a small fraction, relying on the oxygen functionalities of the GO. The variation in the duration of time for the $O_3$ irradiation resulted in a small change in total oxygen content, but in a significantly different fraction of each functional group in the GO, which influenced the Sn nanoparticle size and the amount of SnO (and/or $SnO_2$). As a result, the EPD films prepared with the GO that possessed the least amount of carboxylic groups (made by treating GO in an $O_3$ environment for 3 h) showed the best performance, when compared with the nanocomposites composed of untreated GO or GO that was $O_3$-treated for a duration of less than 3 h.

Mechanical Properties of Styrene-Butadiene Rubber Reinforced with Silica by in situ Tetraethoxysilane Hydrolysis over Acid Catalyst

  • Li, Qingyuan;Li, Xiangxu;Cho, Ur Ryong
    • Elastomers and Composites
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    • 제53권2호
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    • pp.57-66
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    • 2018
  • Styrene-butadiene rubber (SBR), reinforced with different contents of silica (with or without modification using silane coupling agents), was prepared by a modified sol-gel method involving hydrolyzation of tetraethoxysilane over an acid catalyst. The structures of the as-prepared samples were characterized using various techniques, such as scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, and thermogravimetric analysis. The mechanical properties of the as-prepared samples were discussed in detail. The results revealed an increasing of the storage modulus (G') with increase in the silica content without modification. In contrast, G' decreased after modification using silane coupling agents, indicating a reduction in the silica-silica interaction and improved dispersion of silica in the SBR matrix. Both tensile stress and hardness increased with increase in the silica content (with modification) in the SBR matrix, albeit with low values compared to the samples with un-modified silica, except for the case of silica modified using (3-glycidyloxypropyl) trimethoxysilane (GPTS). The latter observation can be attributed to the special structure of GPTS and the effort of oxygen atom lone-pair.

Statistical-based evaluation of design codes for circular concrete-filled steel tube columns

  • Li, Na;Lu, Yi-Yan;Li, Shan;Liang, Hong-Jun
    • Steel and Composite Structures
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    • 제18권2호
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    • pp.519-546
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    • 2015
  • This study addresses the load capacity prediction of circular concrete-filled steel tube (CFST) columns under axial compression using current design codes. Design methods given in the Chinese code CECS 28:2012 (2012), American code AISC 360-10 (2010) and EC4 (2004) are presented and described briefly. A wide range of experimental data of 353 CFST columns is used to evaluate the applicability of CECS 28:2012 in calculating the strength of circular CFST columns. AISC 360-10 and EC4 (2004) are also compared with the test results. The comparisons indicate that all three codes give conservative predictions for both short and long CFST columns. The effects of concrete strength, steel strength and diameter-to-thickness ratio on the accuracy of prediction according to CECS 28:2012 are discussed, which indicate a possibility of extending the limitations on the material strengths and diameter-to-thickness ratio to higher values. A revised equation for slenderness reduction factor in CECS 28:2012 is given.

Field measurement and numerical simulation of snow deposition on an embankment in snowdrift

  • Ma, Wenyong;Li, Feiqiang;Sun, Yuanchun;Li, Jianglong;Zhou, Xuanyi
    • Wind and Structures
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    • 제32권5호
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    • pp.453-469
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    • 2021
  • Snow accumulation on the road frequently induces a big traffic problem in the cold snowy region. Accurate prediction on snow distribution is fundamental for solving drifting snow disasters on roads. The present study adopts the transient method to simulate the wind-induced snow distribution on embankment based on the mixture multiphase model and dynamic mesh technique. The simulation and field measurement are compared to confirm the applicability of the simulation. Furthermore, the process of snow accumulation is revealed. The effects of friction velocity and snow concentration on snow accumulation are analyzed to clarify its mechanism. The results show that the simulation agrees well with the field measurement in trends. Moreover, the snow accumulation on the embankment can be approximately divided into three stages with time, the snow firstly deposited on the windward side, then, accumulation occurs on the leeward side which induced by the wake vortex, finally, the snow distribution reaches an equilibrium state with the slope of approximately 7°. The friction velocity and duration have a significant influence on the snow accumulation, and the vortex scale directly affected the snow deposition range on the embankment leeward side.

Study of Stray-light Analysis and Suppression Methods for the Spectroscopic System of a Solar-radiation Observer Instrument

  • Zheng, Ru;Liu, Bo;Wang, Lingyun;Gao, Yue;Li, Guangxi;Li, Changyu
    • Current Optics and Photonics
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    • 제5권3호
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    • pp.220-228
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    • 2021
  • To improve the measurement accuracy of a solar-radiation observer instrument, aiming at the problem of multiorder-stray-light interference caused by the diffraction of the flat-field concave grating in the spectroscopic system, straylight suppression methods for different forms of optical traps are studied. According to the grating surface-scattering distribution-function model, the bidirectional scattering distribution function (BSDF) of a dust-polluted surface and the flat-field concave grating's transition area of the spectroscopic system is calculated, and a Lyot stop with blade baffle is designed to suppress this kind of stray light. For diffraction multiorder stray light, based on the theory of light-energy transmission, a design for precise positioning of the trench optical trap is proposed. The superiority of the method is verified through simulation and actual measurement. The simulation results show that in a spectroscopic system approximately 160 mm × 140 mm × 80 mm in size, the energy of the stray light is reduced by one order of magnitude by means of the trench optical trap and Lyot stop, and the number of beams is reduced from 5664 to 1040. The actual measurements show that the stray-light-suppression efficiency is about 69.4%, which is effective reduction of the amount of stray light.

Effect of pH Buffer and Carbon Metabolism on the Yield and Mechanical Properties of Bacterial Cellulose Produced by Komagataeibacter hansenii ATCC 53582

  • Li, Zhaofeng;Chen, Si-Qian;Cao, Xiao;Li, Lin;Zhu, Jie;Yu, Hongpeng
    • Journal of Microbiology and Biotechnology
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    • 제31권3호
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    • pp.429-438
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    • 2021
  • Bacterial cellulose (BC) is widely used in the food industry for products such as nata de coco. The mechanical properties of BC hydrogels, including stiffness and viscoelasticity, are determined by the hydrated fibril network. Generally, Komagataeibacter bacteria produce gluconic acids in a glucose medium, which may affect the pH, structure and mechanical properties of BC. In this work, the effect of pH buffer on the yields of Komagataeibacter hansenii strain ATCC 53582 was studied. The bacterium in a phosphate and phthalate buffer with low ionic strength produced a good BC yield (5.16 and 4.63 g/l respectively), but there was a substantial reduction in pH due to the accumulation of gluconic acid. However, the addition of gluconic acid enhanced the polymer density and mechanical properties of BC hydrogels. The effect was similar to that of the bacteria using glycerol in another carbon metabolism circuit, which provided good pH stability and a higher conversion rate of carbon. This study may broaden the understanding of how carbon sources affect BC biosynthesis.

Numerical study on fire resistance of cyclically-damaged steel-concrete composite beam-to-column joints

  • Ye, Zhongnan;Heidarpour, Amin;Jiang, Shouchao;Li, Yingchao;Li, Guoqiang
    • Steel and Composite Structures
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    • 제43권5호
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    • pp.673-688
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    • 2022
  • Post-earthquake fire is a major threat since most structures are designed allowing some damage during strong earthquakes, which will expose a more vulnerable structure to post-earthquake fire compared to an intact structure. A series of experimental research on steel-concrete composite beam-to-column joints subjected to fire after cyclic loading has been carried out and a clear reduction of fire resistance due to the partial damage caused by cyclic loading was observed. In this paper, by using ABAQUS a robust finite element model is developed for exploring the performance of steel-concrete composite joints in post-earthquake fire scenarios. After validation of these models with the previously conducted experimental results, a comprehensive numerical analysis is performed, allowing influential parameters affecting the post-earthquake fire behavior of the steel-concrete composite joints to be identified. Specifically, the level of pre-damage induced by cyclic loading is regraded to deteriorate mechanical and thermal properties of concrete, material properties of steel, and thickness of the fire protection layer. It is found that the ultimate temperature of the joint is affected by the load ratio while fire-resistant duration is relevant to the heating rate, both of which change due to the damage induced by the cyclic loading.

상변화물질을 활용한 원통형 리튬이온 배터리 셀의 냉각성능 및 등온유지성에 관한 연구 (Study on cooling performance and isothermal maintenance of cylindrical type lithium-ion battery cell using phase change material)

  • 윤재형;현수웅;정희준;신동호
    • 한국가시화정보학회지
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    • 제21권2호
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    • pp.34-45
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    • 2023
  • When lithium-ion batteries operate out of the proper temperature range, their performance can be significantly degraded and safety issues such as thermal runaway can occur. Therefore, battery thermal management systems are widely researched to maintain the temperature of Li-ion battery cells within the proper temperature range during the charging and discharging process. This study investigates the cooling performance and isothermal maintenance of cooling materials by measuring the surface temperature of a battery cell with or without cooling materials, such as silicone oil, thermal adhesive, and phase change materials during discharge process of battery by the experimental and numerical analysis. As a result of the experiment, the battery pack filled with phase change material showed a temperature reduction of 47.4 ℃ compared to the case of natural convection. It proves the advanced utility of the cooling unit using phase change material that is suitable for use in battery thermal management systems.