• The Transactions of The Korean Institute of Electrical Engineers
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• v.65 no.4
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• pp.617-621
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• 2016

In addition to the energy storage facilities based on high power technologies, Electric double layer capacitors(EDLC) are today's candidate for power quality stabilization. However, its low energy density is often inhibiting factor for application of electric power industry. Hybrid supercapacitor is an promising energy storage device that positioned between conventional EDLC and Li-ion battery. This paper describes the preparation and characteristics of a hybrid supercapacitor and module for power quality stabilization. A cylindrical 3200F hybrid supercapacitor ($60{\times}74.5mm$) was assembled by using the $Li_4Ti_5O_{12}$ electrode as an anode and activated carbon as a cathode. It shows 2.5 times higher energy density than conventional EDLC with the same volume. In order to determine the characteristics of the hybrid supercapacitor Module for uninterruptible power supply (UPS), hybrid supercapacitor cells were connected in series with active balancing circuit. At even the high current density of 14A(10C), Module prepared by 18 cells showed the capacitance of 170F at 30~50V, suggesting the applicability for UPS.

• KEPCO Journal on Electric Power and Energy
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• v.7 no.2
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• pp.317-321
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• 2021

As the large-scale renewable energy power plant increases, the high-capacity and compact Energy Storage System (ESS) is required. However, this trend could reduce the insulation reliability of ESS. In this study, the surface flashover characteristics for four types of solid insulators are investigated in the uniform electric field with AC and Lightning Impulse (LI) voltage waveforms under various contamination levels. In addtion, insulator surfaces are compared based on the contact angle before and after surface flashover. The experimental results show that AC flashover voltage is dependent on the materials and the contamination level, but LI flashover voltage is only associated with the contamination level. Especially, AC flashover voltage of PC (PolyCarbonate) is higher than that of other insulators, which is associated with the unique and sequential creepage discharge propagation pattern of PC. The localized discharges on the surface of PC form corresponding tracking points. Then, the interconnected trackings result in the complete flashover. This flashover patterns degrade the surface of PC much more than that of epoxy and Bulk Molding Compoud (BMC). Thus, the contact angle of PC is significantly reduced compared to that of other insulators. The increased hydrophilicity in the surface of PC enhances the insulator surface conductivity.

• Journal of Power Electronics
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• v.18 no.2
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• pp.343-355
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• 2018

A wide-voltage-conversion range bidirectional DC-DC converter is proposed in this paper. The topology is comprised of one typical LC energy storage component and a special common grounded asymmetric H-bridge with four active power switches/anti-parallel diodes. The narrow output PWM voltage is generated from the voltage difference between two normal (wider) output PWM voltages from the asymmetric H-bridge with duty cycles close to 0.5. The equivalent switching frequency of the output PWM voltage is double the actual switching frequency, and a wide step-down/step-up ratio range is achieved. A 300W prototype has been constructed to validate the feasibility and effectiveness of the proposed bidirectional converter between the variable low voltage side (24V~48V) and the constant high voltage side (200V). The slave active power switches allow ZVS turn-on and turn-off without requiring any extra hardware. The maximum conversion efficiency is 94.7% in the step-down mode and 93.5% in the step-up mode. Therefore, the proposed bidirectional topology with a common ground is suitable for energy storage systems such as renewable power generation systems and electric vehicles with a hybrid energy source.

• Geosystem Engineering
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• v.21 no.6
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• pp.326-334
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• 2018

Underground water-sealed gas storage caverns have become the primary method for strategic storage of LPG. Previous studies of excavation blasting effects on large-scale underground water-sealed gas storage caverns are rare at home and abroad. In this paper, the blasting excavation for underground water-sealed propane storage caverns in Yantai was introduced and field tests of blasting vibration were carried out. Field test data showed that the horizontal radial velocity had a major controlling effect in the blasting vibration and frequencies would not cause the vibration velocity concentration effects. In terms of the influence of blasting vibration on adjacent caverns, the dynamic finite element model in LS-DYNA soft was established, whose reliability was verified by field test data. The numerical results indicated the near-blasting side was primary zone for the structural failure and tensile failure tended to occur in the middle of the curved wall on the near-blasting side. Meanwhile, the safety criterions for adjacent caverns based on stress wave theory and according to statistic relationship between peak effective tensile stress and peak particle velocities were obtained, respectively. Finally, with Safety Regulations for Blasting in China (GB6722-2014) taken into account, a final safety criterion was proposed.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.4
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• pp.566-572
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• 2013

A microgrid is a small scale power system. The microgrid is operated in two operation modes, the grid-connected mode and the islanded mode. In the islanded mode, the frequency of a microgrid should be maintained constantly. For this, the balance between power supply and power demand during islanded mode should be met. In general, energy storage systems (ESSs) are used to solve power imbalance. In this paper, the frequency control effect of a Lithium-ion battery energy storage system (Li-ion BESS) has been tested on the hardware-in-the loop simulation (HILS) system environment.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.3
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• pp.163-171
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• 2021

Securing energy sources is a key element essential to economic and industrial development in modern society, and research on renewable energy and hydrogen energy is now actively carried out. This research was conducted through experiments and analytical methods on the hydrogen filling process in the hydrogen storage tank of the hydrogen charging station. When low-temperature, high-pressure hydrogen was injected into a high-pressure tanks where hydrogen is charged, the theoretical method was used to analyze the changes in temperature and pressure inside the high-pressure tanks, the amount of hydrogen charge, and the charging time. The analysis was conducted in the initial vacuum state, called the First Cycle, and when the residual pressure was present inside the tanks, called the Second Cycle. As a result of the analysis, the highest temperature inside the tanks in the First Cycle of the high-pressure tank increased to 442.11 K, the temperature measured through the experiment was 441.77 K, the Second Cycle increased to 397.12 K, and the temperature measured through the experiment was 398 K. The results obtained through experimentation and analysis differ within ±1%. The results of this study will be useful for future hydrogen energy research and hydrogen charging station.

• Journal of the Korean Electrochemical Society
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• v.7 no.1
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• pp.32-37
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• 2004

The charge/discharge capacity of natural graphite anode in lithium secondary batteries was examined as a function of charge/discharge rate. When the natural graphite anode was galvanostatically cycled in the range of 0.0-2.0V $(vs.\;Li/Li^+)$, the charging capacity decreased with an increase in the charging rate, which is caused by an earlier approach to the charging cut-off (0.0 V) before the complete charging that is in turn caused by an ever-increasing overpotential at higher rates. Even if the overpotential of discharging reaction also increased at higher discharge rates, the discharging reaction took place in the range of 0.0-0.3 V that is far below the discharge cut-off (2.0 V). As a result, the discharge capacity was not affected by the discharge rate because all the lithium ions once intercalated are fully discharged even at high current condition. As the overpotential of lithium deposition reaction also increased at high current condition, the charge capacity of natural graphite could be enlarged by lowering the charging cut-off voltage below 0.0 V, There is, however, a limitation for the lowering of cut-off voltage because the resistance for lithium deposition is smaller than that of lithium intercalation into graphite. When the charge cut-off voltage was lowered down to -0.04 V under IC condition, lithium ions were inserted into graphite without lithium deposition such that the discharge capacity could be raised up to $11\%$.

• Korean Journal of Materials Research
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• v.29 no.12
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• pp.774-780
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• 2019

The performance of Li-ion hybrid supercapacitors (asymmetric-type) depends on many factors such as the capacity ratio, material properties, cell designs and operating conditions. Among these, in consideration of balanced electrochemical reactions, the capacity ratio of the negative (anode) to positive (cathode) electrode is one of the most important factors to design the Li-ion hybrid supercapacitors for high energy storing performance. We assemble Li-ion hybrid supercapacitors using activated carbon (AC) as anode material, lithium manganese oxide as cathode material, and organic electrolyte (1 mol L^-1 LiPF₆ in acetonitrile). At this point, the thickness of the anode electrode is controlled at 160, 200, and 240 ㎛. Also, thickness of cathode electrode is fixed at 60 ㎛. Then, the effect of negative and positive electrode ratio on the electrochemical performance of AC/LiMn₂O₄ Li-ion hybrid supercapacitors is investigated, especially in the terms of capacity and cyclability at high current density. In this study, we demonstrate the relationship of capacity ratio between anode and cathode electrode, and the excellent electrochemical performance of AC/LiMn₂O₄ Li-ion hybrid supercapacitors. The remarkable capability of these materials proves that manipulation of the capacity ratio is a promising technology for high-performance Li-ion hybrid supercapacitors.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.26-26
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• 2003

Lithium storage electrodes for rechargeable batteries require mixed electronic-ionic conduction at the particle scale in order to deliver desired energy density and power density characteristics at the device level. Recently, lithium transition metal phosphates of olivine and Nasicon structure type have become of great interest as storage cathodes for rechargeable lithium batteries due to their high energy density, low raw materials cost, environmental friendliness, and safety. However, the transport properties of this family of compounds, and especially the electronic conductivity, have not generally been adequate for practical applications. Recent work in the model olivine LiFePO$_4$, showed that control of cation stoichiometry and aliovalent doping results in electronic conductivity exceeding 10$^{-2}$ S/cm, in contrast to ~10$^{-9}$ S/cm for high purity undoped LiFePO$_4$. The increase in conductivity combined with particle size refinement upon doping allows current rates of >6 A/g to be utilized while retaining a majority of the ion storage capacity. These properties are of much practical interest for high power applications such as hybrid electric vehicles. The defect mechanism controlling electronic conductivity, and understanding of the microscopic mechanism of lithiation and delithiation obtained from combined electrochemical and microanalytical techniques, will be discussed

• The Journal of Korean Institute of Communications and Information Sciences
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• v.42 no.4
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• pp.855-863
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• 2017

Because Li-ion battery and Li-Polymer battery have high-energy storage density, they are used for various electronic devices such as electronic cigarette, electronic bicycle, drone, second battery, even golf cart and electronic car. Recently, however, battery explosion is sometimes occurring on electronic devices using Li-ion battery and is becoming serious as bodily harm is breaking out due to explosion. For this, this paper described the Li-ion Battery's operating principles and verified the cause of explosion by overload tests caused by the high-energy storage density. According to the these experiments, we conducted a study to develope scanning techniques of fire and safety measures.