• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.6
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• pp.443-449
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• 2014

Thermoacoustic (TA) models have been widely used to predict combustion instability characteristics in a gas turbine lean premixed combustor. However, these techniques have shown some limitations in improving the model accuracy related to an over-simplification of the combustion system and flame geometry. Efforts were made in the current study to improve the limitations of the TA models. One strategy was to modify the actual flame location in the model, and another was to consider the heat release distribution through the flames. The modified TA model results show better accuracy in predicting the growth rate of instabilities compared with the previous results.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.215-218
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• 2012

In this study, syngas laminar burning velocities with various hydrogen contents were studied using both experimental measurements and kinetic simulations. The laminar burning velocities were measured by the angle method of Bunsen flame configuration and the numerical calculations including burning velocities were made using CHEMKIN Package with USC-Mech II. A large range of syngas mixture compositions such as 10:90%, 25:75%, 50:50%, 75:25% and equivalence ratio from lean condition of 0.5 to rich condition of 5.0 have been conducted. The experimental results of burning velocity were in good agreement with previous other research data and numerical simulation. Also, it was shown that the experimental measurements of laminar burning velocity linearly increased with the increasing of $H_2$ content although the flame speed of hydrogen is faster about ten times than carbon monoxide. This phenomenon is attributed to the rapid production of the hydrogen related radicals such as H and OH at the early stage of combustion, which is confirmed the linear increasing of radical concentrations on kinetic simulation.

• Korean Journal of Optics and Photonics
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• v.9 no.4
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• pp.264-269
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• 1998

The Measurement of concentration patterns for $C_2$, CH and OH radicals in the premixed propane-air flame could be managed through an image processing technique. This technique was applied to the three kinds of flames on a bunsen burner-mixtures of fuel to be lean, optimum and excessive respectively. The image processing system was complished by treating single wavelength flame images around the eac radical luminescence band, which was obtained by using a set of narrow band pass filters, an image intensifier, CCD and PC. It was possible to observe and predict the reaction zone and the concentration distribution of the radicals, Spatial distribution of each radicals in the raaction zone gave us enough informations to analyze the reaction mechanisms in $C_mH_n$ combustion process. According to this informations, the image of $C_2$ radical exists at front zone, following the images of CH and OH radicals at downstream.

• Journal of the Korean Society of Combustion
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• v.17 no.4
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• pp.5-10
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• 2012

The reformer system is a chemical device that drives the conversion of hydrocarbon to hydrogen rich gas under high temperature environment($600-1,000^{\circ}C$). Generally, NG(Natural Gas) or AOG(Anode Off Gas) is used as fuel of fuel cell reformer combustion system. The experimental study to analyze the combustion characteristics of a premixed ceramic burner used for 0.5-1.0 kW fuel cell reformer was performed. Ceramic burner experiments using NG and AOG were carried out to investigate the flame stability characteristics by heating capacity, equivalence ratio and different fuels respectively. The results show that surface flames can be classified into green, red, blue and lift-off flames as the equivalence ratio of methane-air mixture decreases. And the stable flames can be established using NG and AOG as reformer fuel in the perforated ceramic burner. In particular, the blue flame is found to be stable at a lean equivalence ratio under different mixture conditions of NG and AOG for the 0.5 to 1.0 kW fuel cell system power range. NOx emission is under 60 ppm between 0.70 to 0.78 of equivalence ratio and CO emission is under 50 ppm between 0.70 to 0.84 of equivalence ratio.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.1
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• pp.47-58
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• 2023

Experimental data conducted by Colson et al. and numerical data conducted in this study were compared through counterflow flames to understand of the characteristic of basic flame about mixture of ammonia/methane. In order to use the suitable numerical mechanism, the validation was performed using total four mechanisms and the Okafor's mechanism showed satisfactory experimental results. The extinction boundary of the stability map could be explained through the effective Lewis number and the trend of LeD. The extinction behavior of the flame was different under the lean and rich symmetric conditions and it was investigated by the major variables, global strain rate (a_g) and mole fraction of ammonia (Ω_NH3).

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.4
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• pp.555-560
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• 2002

Numerical simulations of freely propagating flames burning stoichiometric CH$_4$/O$_2$/$N_2$mixtures are performed at atmospheric pressure in order to understand the effect of the $O_2$enrichment level on CH$_4$/Air flame. A chemical kinetic mechanism is employed, the adopted scheme involving 54 gas-phase species and 632 forward reactions. The calculated flame speeds are compared with the experiments for the flames established at several $O_2$enrichment level, the results of which is in excellent agreement. As a result of the increased $O_2$enrichment level from 0.21 to 1, the mole fraction of CO in the burred gas is increased. The flame speed and the temperature in the burned gas are also increased, but the thickness of the flame is severely shrunken in the preheat region. The maximum of the calculated EINO is obtained around 0.6 and 0.7 of the $O_2$enrichment level in cases of flames for fuel-lean mixtures.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.2
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• pp.174-180
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• 2017

Recently, the world faces the environmental problem such as air pollution due to harmful gas discharged from car and abnormal climate due to the green-house gases increased by the discharge of $CO_2$. Compressed Natural Gas (CNG), one of alternative for this problem, is less harmful, compared to the existing fossil fuel, as gaseous fuel, and less carbon in fuel ingredients and carbon dioxide generation rate relatively favorable more than the existing fuel. However, CNG fuel has the weakness of slow flame propagation speed and difficult fast burn. On the other hand, hydrogen does not include carbon in fuel ingredients, and does not discharge harmful gas such as CO and HC. Moreover, it has strength of quick burning velocity and ignition is possible with small ignition energy source and it's has wide Lean Flammability Limit. If using this hydrogen with CNG fuel, the characteristics of output and discharge gas is improved by the mixer's burning velocity improved, and, at the same time, is possible to have stable lean combustion with the reduction of $CO_2$ expected. Therefore, this research tries to identify the characteristics of engine and emission gas when mixing CNG fuel and hydrogen in each portion and burning them in spark igniting engine, and grasp the lean combustion limit and emission gas characteristics according and use it as the basic data of hydrogen-CNG premixed engine.

• Journal of the Korean Society of Safety
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• v.25 no.1
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• pp.17-21
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• 2010

The chemistry and ignition delay of hydrogen/air/HFP premixed mixtures was investigated numerically with unsteady perfectly stirred reactor(PSR). The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the temporal concentration variations of major or reactants such as hydrogen and oxygen during autoignition were similar to the spatial distribution of premixed flame while water vapor produced at the ignition temperature was decomposed later, which can be clarified with the relate species production rates that the the re-growth (or shoulder) of OH concentration is a result of F radicals attacking $H_20$ forming OH and HF. For the stoichiometric $H_2$/air mixture inhibited by 20% HFP, HFP thermal decomposition reaction prevails over the radical attack such as H at initial stage. Even though relatively large HFP addition contributes to delay the ignition, chemical effect on the ignition delay is not effective because of late thermal decomposition of HFP. The most small ignition delay was observed at a slightly fuel lean condition ($\phi$ = 0.9), and temperature dependency of ignition delay was clearly shown near 900 K.

• Journal of the Korean Society of Propulsion Engineers
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• v.16 no.6
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• pp.41-47
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• 2012

It is very important to predict the nonlinear behavior of combustion instability such as transition phenomena and limit cycle amplitude for fully understanding and controlling the instabilities. These nonlinear instability characteristics are highly dependent upon the flames' nonlinear dynamics in a gas turbine premixed combustor. In this study, nonlinear instability TA(Thermo-acoustic) models were introduced by applying the concept of flame describing function to the thermoacoustic analysis method. As a result of model development, for a given combustor length, the growth rate of instability was greatly affected by the change in amplitude, although the instability frequency was not. Further researches under various operating conditions and model validation on limit cycle amplitude are required.

• Journal of Mechanical Science and Technology
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• v.19 no.6
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• pp.1366-1377
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• 2005

Experimental study was carried out in an atmospheric pressure, laboratory-scale dump combustor showing features of combustion instabilities. Flame structure and heat release rates were obtained from OH emission spectroscopy. Qualitative comparisons were made between line-integrated OH chemiluminescence image and Abel-transformed one. Local Rayleigh index distributions were also examined. Mean temperature, normalized standard deviation and temperature fluctuations were measured by coherent anti-Stokes Raman spectroscopy (CARS). To see the periodic behavior of oscillating flames, phase-resolved measurements were performed with respect to the pressure wave in the combustor. Results on system damping and driving characteristics were provided as a function of equivalence ratio. It also could be observed that phase resolved temperatures have been changed in a well-defined manner, while its difference between maximum and minimum reached up to 280K. These results would be expected to play an important role in better understanding of driving mechanisms and thermo-acoustic interactions.