• Title/Summary/Keyword: Lead extraction

Search Result 258, Processing Time 0.026 seconds

Lead Stabilization in Soil Amended with Lime Waste: An Extended X-ray Absorption Fine Structure (EXAFS) Investigation

  • Lim, Jung Eun;Lee, Sang Soo;Yang, Jae E.;Ok, Yong Sik
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.47 no.6
    • /
    • pp.443-450
    • /
    • 2014
  • To determine Pb species in soils following the immobilization process, sequential extraction has been used despite the possibility of overestimating Pb species from unintended reactions during chemical extraction. Meanwhile, the application of extended X-ray absorption fine structure (EXAFS) has been shown to provide a more precise result than chemical extraction. In this study, the immobilization of Pb in contaminated soils treated with liming materials such as oyster shell (OS) or eggshell (ES) was evaluated with thermodynamic modelling and EXAFS analysis. Thermodynamic modelling by visual MINTEQ predicted the precipitation of $Pb(OH)_2$ in OS and ES treated soils. In particular, the values of saturation index (SI) for $Pb(OH)_2$ in OS (SI=0.286) and ES (SI=0.453) treated soils were greater than in the control soil (SI=0.281). Linear combination fitting (LCF) analysis confirmed the presence of $C_{12}H_{10}O_{14}Pb_3$ (lead citrate, 44.7%) by citric acid from plant root, Pb-gibbsite (Pb adsorbed gibbsite, 26.4%), and Pb-kaolinite (Pb adsorbed kaolinite, 20.3%) in the control soil. On the other hand, $Pb(OH)_2$ (16.8%), Pb-gibbsite (39.3%), and Pb-kaolinite (25.6%) were observed in the OS treated soil and $Pb(OH)_2$ (55.2%) and Pb-gibbsite (33.8%) were also confirmed in the ES treated soil. Our results indicate that the treatment with OS and ES immobilizes Pb by adsorption of Pb onto the soil minerals as a result of the increase in soil negative charge and the formation of stable $Pb(OH)_2$ under high pH condition of soils.

A Dual-scale Network with Spatial-temporal Attention for 12-lead ECG Classification

  • Shuo Xiao;Yiting Xu;Chaogang Tang;Zhenzhen Huang
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • v.17 no.9
    • /
    • pp.2361-2376
    • /
    • 2023
  • The electrocardiogram (ECG) signal is commonly used to screen and diagnose cardiovascular diseases. In recent years, deep neural networks have been regarded as an effective way for automatic ECG disease diagnosis. The convolutional neural network is widely used for ECG signal extraction because it can obtain different levels of information. However, most previous studies adopt single scale convolution filters to extract ECG signal features, ignoring the complementarity between ECG signal features of different scales. In the paper, we propose a dual-scale network with convolution filters of different sizes for 12-lead ECG classification. Our model can extract and fuse ECG signal features of different scales. In addition, different spatial and time periods of the feature map obtained from the 12-lead ECG may have different contributions to ECG classification. Therefore, we add a spatial-temporal attention to each scale sub-network to emphasize the representative local spatial and temporal features. Our approach is evaluated on PTB-XL dataset and achieves 0.9307, 0.8152, and 89.11 on macro-averaged ROC-AUC score, a maximum F1 score, and mean accuracy, respectively. The experiment results have proven that our approach outperforms the baselines.

Effects of HCl and EDTA on Soil Washing to Remediate Lead-contaminated Soil in a Firing Range (사격장 납 오염토양 복원을 위한 토양세척시 HCl과 EDTA의 영향 연구)

  • Kim, Hyo-Sik;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
    • /
    • v.13 no.1
    • /
    • pp.60-66
    • /
    • 2008
  • Laboratory soil washing experiments with HCl or EDTA were conducted to remediate lead-contaminated soil in a firing range. After lead bullets were removed by standard sieve #18 (1.0 mM), Pb concentrations were measured by EPA Method 3050B (9,443 mg/kg) and Korea Standard Test (4,803.5 mg/kg). The results of the batch test showed that the removal efficiency curve was logarithmic and approximately 90% of lead in soil was removed, when HCl was used. In case of EDTA, the removal efficiency increased proportionally to the concentration of EDTA, up to 98% lead removal with 0.1M EDTA. High mixing strength resulted in increase of removal efficiency and kinetics showed that the most lead was extracted in 10 min.

LEACHING OF LEAD FROM DISCARDED NOTEBOOK COMPUTERS USING THE SCALE-UP TCLP AND OTHER STANDARD LEACHING TESTS

  • Jang, Yong-Chul;Townsend, Timothy G.
    • Environmental Engineering Research
    • /
    • v.11 no.1
    • /
    • pp.14-27
    • /
    • 2006
  • The proper management of discarded electronic devices (often called electronic-waste) is an emerging issue for solid waste professionals throughout the world because of the large growth of the waste stream, and the content of toxic metals in them, most notably heavy metals such as lead. Notebook computers are becoming one of the major components of discarded computer devices and will continue to increase in the waste stream in the future. While the computers hold great promise for recycling, a substantial amount of this waste is often disposed in municipal solid waste (MSW) landfills. The toxicity characteristic leaching procedure (TCLP) is commonly used to simulate worse case leaching conditions where a potentially hazardous waste is assumed to be disposed along with municipal solid waste in a landfill with actively decomposing materials overlying an aquifer. The objective of this study was to examine leaching potential of lead from discarded notebook computers using the scale-up TCLP, other standard leaching tests such as California waste extraction test (Cal WET), and the synthetic precipitation leaching procedure (SPLP) and actual landfill leachates as leaching solution. The scale-up TCLP is a modified TCLP (where the device was disassembled and leached in or near entirety) to meet the intent of the TCLP. The results showed that the scale-up TCLP resulted in relatively high lead found in the leachate with an average of 23.3 mg/L. The average level was less than those by the standard TCLP and WET (37.0 mg/L and 86.0 mg/L, respectively), but much greater than those by the SPLP and the extractions with the landfill leachates (0.55 mg/L and 1.47 mg/L, respectively). The pH of the leaching solution and the ability of the organic acids in the TCLP and WET to complex with the lead were identified as major factors that controlled the amount of lead leached from notebook computers. Based on the results obtained by a number of leaching tests in this study, notebook computers may present a potential leaching risk to the environment and human health upon land disposal. However, further investigation is still needed to assess the true risk posed by the land disposal of discarded notebook computers.

Study on GIS based Automatic Delineation Method of Accurate Stream Centerline for Water Quality Modeling (GIS기반의 수질모델링 지원을 위한 정확도 높은 하천중심선의 자동 추출기법에 관한 연구)

  • Park, Yong-Gil;Kim, Kye-Hyun;Lee, Chol-Young
    • Spatial Information Research
    • /
    • v.18 no.4
    • /
    • pp.13-22
    • /
    • 2010
  • For implementing TMDL(Total Maximum Daily Loading) to adopt more effective management of water pollution, water quality modeling is pre-requisite and such modeling requires the extraction of stream centerline. The institutes responsible for the water quality modeling, however, generates the stream centerline with their own criteria and this lead to low accuracy of the extracted centerline as well as different modeling results for the same watershed. Therefore, this study mainly focused on the development of extraction method of the stream centerline. For that, an automated method has been developed through the integration of the centerline extraction method using a maximum inscribed circle with GIS. The result has shown that the newly developed method could enable to represent more details of the stream topography along with enhanced accuracy compared with conventional extraction method. Furthermore, the new method can afford centerline extraction for the island areas which has been the limitation of the conventional method thereby supporting water quality modeling in a detailed level.

THE IMPORTANCE OF ANCHORAGE AND GROWTH THROUGH ORTHODONTIC TREATMENT BY THE EXTRACTION OF PREMOLAR (소구치발치교정증례를 통해본 고정 및 성장의 중요성에 대하여)

  • Son, Dae-Sik
    • The Journal of the Korean dental association
    • /
    • v.15 no.6
    • /
    • pp.445-456
    • /
    • 1977
  • Author had experienced orthodontic cases that had been treated by the extraction of premolar at department of orthodontics, Tokyo Dental College. This report contains four cases which occlusion and profile were well improved by the orthodotic treatment. Four cases were all female. Two cases started orthodontic treatment at the age of puberty the other at adult. All the cases needed maximum anchorage. As a result, treatment were succeeded and profile was well advanced by growth and anchorage. In orthodontic treatment, the growth and anchorage are the KEY which lead to success. But the prediction of growth is very difficult.

  • PDF

Lime Treatment of Waterworks Sludges for Soil Cover in Municipal Landfilling Site (석회처리에 의한 정수 슬러지의 복토재 활용에 관한 연구)

  • Lim, Sung-Jin;Lee, Jae-Bok
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.14 no.3
    • /
    • pp.231-239
    • /
    • 2000
  • Water treatment processes produce sludges resulting from water clarification. Sludge production amount increases each year and its treatment and disposal is growing to social problems according to water demand increase. Water treatment plant sludges can be modified to soil cover in sanitary landfill site through the lime treatment. Compression strength of $1.0kg/cm^2$ or more is recommended for soil cover material in municipal landfilling site. Compression and shear strength properties of modified sludges showed material property improvement applicable for soil cover alternatives. Solidification effect of the modified sludge was observed through the scanning electron microscope. Extraction tests for hazardous components in sludges revealed that extraction levels of cadmium, copper, and lead were below the regulated criteria. When adding 10% calcium hydroxide to water treatment plant sludges, the modified sludges can reach material properties for cover soil after 28 days solidification reaction.

  • PDF

Heavy Metal Distribution in Soils from the Maehyang-ri Inland Shooting Range Area (매향리 내륙 사격장 토양의 중금속 오염 분포)

  • Lee, Jun-Ho;Park, Kap-Song
    • Journal of Korean Society on Water Environment
    • /
    • v.24 no.4
    • /
    • pp.407-414
    • /
    • 2008
  • This study was conducted to evaluate the heavy metal contamination in the soils of Maehyang-ri inland shooting range area. The texture of the Maehyang-ri inland shooting range soil was sandy. Extraction of heavy metals reached quasi-equilibrium within 6 hours using shaking with 0.1 N HCl. 95% and 94% of extraction efficiency was observed for Cu and Pb in the Maehyang-ri shooting range soils, respectively. And Cu and Pb contamination of level of the T-1 region soil was $114.4{\pm}5.7mg/kg$ and $362.3{\pm}20.5mg/kg$. This may be due to the effects of mineralogical factor, soil particle size and un-residual fractions such as exchangeable, carbonate, Fe-Mn oxide and organic+sulfide.

Mandibular canal branches supplying the mandibular third molar observed on cone beam computed tomographic images: Reports of four cases (콘빔형 전단화단층영상에서 관찰되는 하악관 분지 4 증례)

  • Lee, Jae-Seo;Yoon, Suk-Ja;Kang, Byung-Cheol
    • Imaging Science in Dentistry
    • /
    • v.39 no.4
    • /
    • pp.209-212
    • /
    • 2009
  • Bifid mandibular canal can be an anatomic variation. This condition can lead to complication when performing mandibular anesthesia or during extraction of lower third molar, placement of implants and surgery in the mandible. Four patients underwent preoperative imaging for extraction of third molars using CBCT (CB Mercuray, Hitachi, Japan). The axial images were processed with CBworks program 2.1 (CyberMed Inc., Seoul, Korea). The branches for supplying the lower third molar were identified mainly on cross-sectional and panoramic images of CBCT. Since the location and configuration of mandibular canal variations are important in any mandibular surgical procedures, we report 4 cases of bifid mandibular canal with panoramic and the CBCT images.

  • PDF

CARE OF ANXIETY DISORDER AND HYPERVENTILATION DURING REFRACTORY TOOTH EXTRACTION IN A PSYCHOLOGIC DISABLED PATIENT (정신장애 환자에서 난발치 중의 불안장애와 과환기 관리 : 증례보고)

  • Oh, Ji-Hyeon;Yoo, Jae-Ha;Kim, Jong-Bae
    • The Journal of Korea Assosiation for Disability and Oral Health
    • /
    • v.10 no.2
    • /
    • pp.106-113
    • /
    • 2014
  • Hyperventilation is produced by several distinct causes: anxiety, respiratory alkalosis, increased blood catecholamine levels, and a decrease in the level of the ionized calcium in the blood. The dental fears about acute pain, bleeding, needle, drill and dental surgery lead to the severe anxiety and increased blood catecholamine level. Therefore, the most dental patient should be cared gently as the stress reduction protocol. In spite of the gentle care, a hyperventilation were occurred during the surgical extraction of impacted third molar with pericoronitis. We suggest that the dental patients with anxiety disorder must be attention for the manifestation of hyperventilation, especially in the psychologic disabled patient.