• Journal of Conservation Science
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• v.18 s.18
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• pp.5-18
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• 2006

Dujeong-dong site of Cheonan is known as the site of Baekje period in the first half of the fourth century. This study investigated the visible properties and the chemical composition of the 18 pieces of the glass found in the site, and considered scientific properties and periodic interrelationship of the glass on the basis of the analysis result. The observation of the visible properties and microstructure of ancient glass was performed with both an electron microscope and an optical microscope, and the chemical composition was conducted by way of both quantitative and qualitative analysis using Scanning Electron Microscope(SEM) with Energy Dispersive Spectrometer(EDS). In the analysis result, various chemical composition systems are identified in the glass beads of Dujeong-dong site, such as lead-barium, soda and potash glass, and also different shapes were found such as gold foil glass beads, tubular beads, and round beads. It is estimated that the classification of glass by means of its chemical composition was also closely related to the color of glass.

• Microbiology and Biotechnology Letters
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• v.41 no.1
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• pp.60-69
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• 2013

Purified melanin pigment from Klebsiella sp. GSK was characterized by thermogravimetric, differential thermal, X-ray diffraction and elemental analysis. This melanin pigment is structurally amorphous in nature. It is thermally stable up to $300^{\circ}C$ and emits a strong exothermic peak at $700^{\circ}C$. Its carbon, hydrogen and nitrogen composition is 47.9%, 6.9% and 12.0%, respectively. It was used to scavenge metal ions and free radicals. After immobilizing the pigment and using it to adsorb copper and lead ions, the metal ion adsorption capacity was evaluated by atomic absorption spectroscopy (AAS) and the identity of melanin functional groups involved in the binding of metal ions was determined by Fourier transform infrared (FT-IR) spectroscopy. Batch adsorption studies showed that 169 mg/g of copper and 280 mg/g of lead were adsorbed onto melanin-alginate beads. The metal ion adsorption capacity of the melanin-alginate beads was relatively significant compared to alginate beads. The metal ion desorption capacity of HCl was greater (81.5% and 99% for copper and lead, respectively) than that of EDTA (80% and 71% for copper and lead, respectively). The ability of the melanin pigment to scavenge free radicals was evaluated by inhibition of the oxidation of 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and was shown to be about 74% and 98%, respectively, compared with standard antioxidants.

• Conservation Science in Museum
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• v.22
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• pp.69-84
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• 2019

This study investigated the formal characteristics and chemical compositions of eighty beads excavated from a Silla tomb complex at Deokcheon-ri, Uljin in order to reveal the methods of production and the characteristics of the raw materials involved, thereby illuminating characteristics of the relics from each tomb. The beads excavated from these Silla tombs include one curved bead, one tubular bead, and 78 globular beads. Among them, the curved and tubular beads and three globular beads were identified to be made of minerals, and the remaining 75 beads are made of glass. Most of the glass beads are thought to have been produced using the drawing technique. The characteristics of the beads were classified according to their site of excavation. The globular beads from Tomb No. 34 belong to the lead-barium glass and potash glass groups, indicating that these beads were produced at a relatively earlier period in time. The glass beads excavated from the tombs in the northern portion of the complex differ in color and chemical composition from those in the southern portion, which indicates the character that each group of beads had different aspect according to site location. Considering that the excavated beads were mainly from fifth- and sixth-century tombs, it is likely that certain groups of people living around Uljin used and buried beads in their tombs. As the governance of Silla became more centralized in the sixth century, the use of beads for burial purpose appears to have come to an end in this region.

• Journal of the Korean Chemical Society
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• v.17 no.3
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• pp.198-206
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• 1973

We produced the glass beads using a spherical vessel which is rotable with the mix ture of releasing agent and glass powder in a electric furnace (apparatus 1), a tubing apparatus of electric furnace which can be gravitated a cullet (apparatus 2) and a tubing apparatus which is dispersible glass powders with the flame of propane gas (apparatus 3). The substrates which are Korean sodium silicates glass 1, 2, boro silicates glass and lead silicates glass are used and the size of cullets is 60-300 mesh. In the results of experimental apparatus, the preferable temperature of apparatus 1 is 880$^{\circ}C$, apparatus 2 is 980$^{\circ}C$ and apparatus 3 is 1100$^{\circ}C$. However, the method of apparatus 3 is more effective than the methods of apparatus 1 and 2 in view of treating time and rate of adhesion.

• 보존과학연구
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• s.32
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• pp.113-121
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• 2011

Four glass beads from Hakso-ri site, O'chang were analyzed for thirteen oxides with SEM/EDS and lead isotope ratios with TIMS respectively. These samples were classified to potash glass system($K_2O-CaO-SiO_2$) with HCLA(High CaO, Low $Al_2O_3$). However three samples with above 4% for lead could be classified to potash-lead ($K_2O-PbO-CaO-SiO_2$)glass system and it seemed that coloring agent for greenish blue was Cu. Lead isotope ratio data for four samples did not make a group but scattered to the space respectively. It needs more study for compositions and lead iosotope data of potash-lead glasses with regions and ages.

• Journal of Conservation Science
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• v.33 no.3
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• pp.215-223
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• 2017

The purpose of this study is to reveal the characteristics, correlations, and colorant materials of those using the chemical compositions of 30 glasses excavated from the Sarari hall of the Mireuksaji stone pagoda, and to determine the correlations between them and other glass excavated from the Wanggungri site. The results of the chemical analysis of the 11 glass beads show that they are a soda glass group with high contents of $SiO_2$ and $Na_2O$; these can be further subdivided into soda-alumina groups ($Na_2O-Al_2O_3-CaO-Si_2O$). The characteristics of the stabilizer are classified as being of the high alumina glass group (LCHA), except for two glasses. It was concluded that colorant materials affected the coloring for glass beads by various components including Ti, Mn, Fe, Cu and Pb. In addition, we examined six lead glasses which are glass plate and unknown fragments that are of a common lead glass system ($PbO-SiO_2$) with respect to the average contents of PbO (70wt.%) and $SiO_2$ (30wt.%). As a result of comparing these relics with those of the glass beads excavated by Wanggungri, there is a similarity in that they belong to the soda glass group. However, the contents of $Na_2O$ are relatively higher than that of the glass beads in the Mireuksaji pagoda, and most of relics include glasses with a low content of $K_2O$ and CaO. In addition, the PbO and $SiO_2$ contents are slightly different in the lead glass. It seems that the glass relics made at two different sites may have used different raw materials or techniques.

• Conservation Science in Museum
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• v.30
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• pp.71-88
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• 2023

This paper examined the visible characteristics and chemical composition of glass beads from the Joseon Dynasty as well as the associations thereof. It also explored the characteristics and uses of glass beads by region. This study covered a total of 1,819 pieces excavated from 25 locations in the Gyeonggi, Chungcheong, and Gyeongsang regions, of which 537 pieces were analyzed for their chemical composition. Glass beads of the Joseon Dynasty take a variety of shapes such as a Round, Coil, Floral, Segmented, Flat, Oval, and Calabash. Colors vary from shades of brown (brown, lemon yellow) and shades of blue (Bluish-Green, greenish-Blue, Purple-Blue) to shades of white (colorless, white) and shades of green (Green, Greenish-Blue, Greenish-Brown). Brown accounts for the largest percentage, followed by Bluish-Green, greenish-Blue. It was identified that Drawing technique was the most common glass bead production technique of the Joseon Dynasty. Potassium oxide (K₂O) was the most common flux agent for glass beads, while the potash glass and mixed alkali glass groups account for the largest quantity. The choice of stabilizers depended on the type of flux agents used, but the most common were calcium oxide (CaO) and aluminum oxide (Al₂O₃). The potash glass and potash lead glass groups are high in CaO and low in Al₂O₃, the mixed alkali glass group is high in CaO, and the lead glass group is low in CaO. In terms of the association between color and shape, most of the beads with shade of brown and blue have round shapes of brown and blue have spherical shapes, while the coil shape is prominent in blue beads. A high percentage of green and colorless beads also take the shape of a coil, while white beads in general have a floral shape. In terms of the association between shape and chemical composition, round, floral and segmented shapes account for a high percentage of the potash glass group, while coil and flat shapes are common in the mixed alkali glass group. This paper also analyzed the colorants for each color based on the association between color and chemical composition. Iron (Fe) was used as the colorant for brown and white, and titanium (Ti) and iron were used for light yellow. Purple-Blue was produced by by cobalt (Co), and greenish-Blue, Bluish-Green, green, Greenish-Blue were produced by iron and copper (Cu). Colorless beads had a generally low colorant content.

• International Journal of Highway Engineering
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• v.14 no.3
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• pp.131-140
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• 2012

Lane markings such as edgelines, centerlines, and lines that delineate lanes generally provide drivers with the various information for safe driving. Drivers can easily recognize the lane markings through the color differences between the markings and road surfaces during the daytime. However, it is a bit difficult for drivers to perceive them during the nighttime due to the lack of artificial lights. Although the glass beads with the 1.5-refractive index have been used to improve the visibility of the lane markings during the nighttime, it is still difficult for drivers to recognize the lane markings properly, especially during the rainy nighttime, which may often lead to traffic accidents. To improve the retroreflectivity and visibility of the lane markings during the rainy nighttime, the high refractive beads with the 2.4-refractive index are essentially required, but they do not work appropriately during the dry nighttime. Thus, the mixed materials with the 1.5, 1.9, and 2.4-refractive beads should be considered for the satisfactory implementation of the lane markings. This study reveals the best mixing rates of the beads by conducting benefit-cost analysis under various weather conditions in Korea. The analysis results show that the lane markings with the 100% of the 2.4-refractive beads provide the highest visibility of lane markings regardless of the roadway conditions, but the benefit-cost (B/C) ratio of the bead mixture is merely 0.46. The best mixing rate of the beads, from the highest B/C ratio viewpoint, was identified as the mixture with a 80% of 1.5-refractive beads and a 20% of 2.4-refractive beads. Some limitations and future research agenda have also been discussed.

• Journal of the Korean Chemical Society
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• v.48 no.6
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• pp.590-598
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• 2004

The preconcentration and determination of trace Cu(II) and Pb(II) on calcium alginate beads in aqueous solution were studied. A calcium alginate beads were prepared by adding an alginic acid to sample solution contained Ca(II). Some following conditions were optimized: the pH of sample solution, amount of alginic acid, and stirring time for effective adsorption; the type and concentration of acid, and sonication time in an ultrasonic vibrator for the perfect de-sorption. A sample solution was prepared with Cu(II) and Pb(II) in DI water. And Ca(II) and ethanol was added into the sample solution. The pH of the final sample solution was controlled with buffer solution. The alginic acid were dispersed in the sample solution by a magnetic stirrer. This mixture was stored in room temperature for 30 min to form a calcium alginate. After the beads were filtered and washed on a membrane filter, the analytes were redissolved from the beads by an ultrasonic vibration of 10 minutes in 1.0M $HNO_3$ solution. The effect of diverse ions on the adsorption of analytes were studied. This procedure was applied for the analysis of two real samples. The recoveries in spiked samples were $90.4{\sim}104.3%$ for analytes.

• Journal of the korean Society of Automotive Engineers
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• v.15 no.3
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• pp.96-110
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• 1993

A procedure has been developed so that a die-face for stamping automobile outer panels can be design and modelled efficiently. The procedure is composed of four parts each of which corresponds to modeling major components of a die-face, i.e. tipped product, blankholder, draw beads, and step draw. The modeling techniques developed specifically for die-face design enable a designer to generate the shape of a die-face quickly with the minimum input, and the resulting models can be used in FEM analysis and NC tool path generation. This will lead to the reductions in lead time and manhours required for the design and manufacture of the stamping dies.