• Proceedings of the KIEE Conference
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• 2006.07c
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• pp.1402-1403
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• 2006

The sulphation is main deterioration of lead-acid batter, then there were many kinds of attempts to improve these problems and one of them is to add additives to the electrolyte. In this study some mixed additives such as silicate & boric acid and silicate & phosphoric acid were added to 38% $H_{2}SO_{4}$ electrolyte of lead acid battery to improve electrochemical properties of corrosion resistance, etc. of anode and cathode of lead acid battery.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 1998.11a
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• pp.177-180
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• 1998

To manage lead-acid battery efficiently and to use it longer in UPS, the state of charge(SOC) indicator of the battery is needed. So a new approach to developing battery SOC indicator for UPS is discussed in this paper. This method to determining SOC by combining the available data of discharge characteristics of a battery with neural networks(NN) is presented. The 3-layered NN with back propagation algorithm has been used. Exprement results show that the proposed method is appropriate as SOC indicator of the battery.

• Journal of Environmental Health Sciences
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• v.17 no.1
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• pp.95-103
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• 1991

For the purpose of estimating the working environment and the relationship between the airborne lead concentration and the ZPP level in the whole blood of the workers, the airborne lead concentrations and the ZPP level were measured at the 26 plants which deal with lead, from October 5 to November 5 in 1988. Analysis of the airborne lead concentration was performed by NIOSH Method 7082, and the ZPP level was measured by a hematofluorometer. The following results are concluded. 1. The average airborne lead concentration of the lead battery manufactures is 0.025mg/m$^{3}$ and that of the secondary lead smelters is 0.023mg/m$^{3}$. There were no significant differences between industry (p>0.1) 2. At the lead battery manufacture, the process of lead powder production showed the highest concentration of 0.034mg/m$^{3}$ but there were no significant differences among the processes (p>0.1). At the secondary lead smelter, the process of dismantling waste batteries showed the highest concentration 0.141mg/m$^{3}$, and there were very significant differences among the processes (p<0.005). 3. The ZPP level in the whole blood showed significant differences between industry (p<0.10). The average ZPP level of the lead battery manufactures is 133.0 + 106.3 $\mu$g/100ml and that of the secondary lead smelters is 149.6 + 110.9 $\mu$g/100ml. 4. The correlation coefficients between the airborne lead concantration and ZPP level were 0. 426 (p<0.001) for the lead battery manufactures and 0.484 (p<0.001) for the secondary lead smelters. The correlation coefficients between the work duration (in months) and the ZPP level were 0.238 (p<0.001) for the lead battery mannfactures and 0.075 (p>0.10) for the secondary lead smelters. 5. The linear regression equation, with the airborne lead concentration as an independent variable and the ZPP level as a dependent variable, is Y=96.84+1300.34X (r=0.448, p<0.001) for the 26 plants which deal with lead. The linear regression equation, with the work duration(in months) as an independent variable and the ZPP level as a dependent variable, is Y=127.28 +0.49X (r=0.162, p<0.05). 6. The correlation coefficients between the amount of inhaled lead and ZPP level were 0.349 (p < 0.001) for the lead battery manufactures and 0.318(p<0.001) for the secondary lead smeltes. The linear regression equation for the 26 plants surveyed, with the amount of inhaled lead as an independent variable and ZPP level as a dependent variable, is Y=123.63+18.82X (r=0. 335, p<0.001).

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.34 no.1
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• pp.96-103
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• 1998

Lead-acid battery is being most widely used with secondary battery because of its low price, and long life cycles. But According to using for a long time, its voltage, capacity, and recovery ability is decreased gradually. Therefore there are many papers about improving the property of a lead-acid battery. One of them is to slow down sulfation due to formation of inner PbSO sub(4) by adding inhibitor to electrolyte, however it was not well known what is inhibitor's composition and its role acting on both cathodic and anodic electrode because of its know-how of every country and companies. The purpose of this paper is to study about improvement of property of lead-acid battery by adding one of the inhibitor to H sub(2) SO sub(4) electrolyte.

• Journal of the Korean Solar Energy Society
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• v.29 no.2
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• pp.1-7
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• 2009

Use of the PV(photovoltaic) generation system is increased in such areas as remote mountain places or islands at which electrical energy is not serviced. The stand alone PV system is required the power storage products such as battery, fly wheel and super capacitor. Several lead storage batteries are connected in series to get high voltages. The life of lead storage battery is shortened when over charge or over discharge takes place. So, it is needed to control batteries not to be overcharged or be discharged deeply. Voltage of each battery was ignored in former control methods in which overall voltage was used to control charge or discharge battery. In this study, the charging and discharging voltage variations of sealed lead storage batteries with l2V/l.2A were investigated step by step experiments. The results of the test show that one should consider and specify the state of each battery to prevent overcharge or deep discharge. With the basis of the experiments, we designed a monitoring unit to monitor battery voltages simultaneously using micro-controller. The unit measures voltage of 20 batteries simultaneously and displays data on the color LCD monitor with curved line graph. It also sends data to PC using the RS232C communication port. The designed unit was adapted to stand alone PV system with 1kW capacity and lead storage batteries are connected to the PV generation system. The number of lead storage batteries was 10 in series and 12V/250Ah each. Resistive load with 3kW was used for discharging.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.1
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• pp.369-377
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• 2013

This paper deals with the state of charge(SOC) and life cycle evaluation algorithm for lead-acid battery, which is essential factor of the electric vehicle(EV) and the stabilization of renewable energy in the smart grid. In order to perform the effective operation of the lead-acid battery, SOC and life cycle evaluation algorithm is required. Specific gravity with the change of electrolyte temperature inside battery case should be obtained to evaluate the SOC of lead-acid battery, however it is difficult to measure the electrolyte temperature of sealed type lead-acid battery. To overcome this problem, this paper proposes the equation of thermal transmission to compensate internal temperature of the lead-acid battery. Also, it is difficult to exactly evaluate the life cycle of battery, depending on the operation conditions of lead-acid battery such as charging and discharging state, self discharging rate and environmental issue. In order to solve the problem, this paper presents the concept for gravity accumulation of charge and discharge cycle, which is the value converted at $20^{\circ}C$. By using the proposed algorithm, this paper propose the test device based on the Labview software. The simulation results show that it is a practical tool for the maintenance of lead-acid battery in the field of industry.

• Applied Chemistry for Engineering
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• v.24 no.4
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• pp.344-349
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• 2013

Energy storage system is an energy reservoir which can store the electrical energy produced by the power plant into the chemical energy at the time whenever it needs to use. Accordingly, the energy storage system can help to improve the energy utilization efficiency and the stabilization of the power supply system. In addition, it can cope with the issues of carbon dioxide reduction and depletion of fossil fuel. Lead-acid battery in the secondary battery fields is one of the most developed technologies. It is also economical, reliable storage device. Therefore, the instantiation case of energy storage system using lead-acid battery was investigated for the reference studies.

• Journal of the Korean Applied Science and Technology
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• v.23 no.4
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• pp.347-354
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• 2006

Generally, it has been known that positive plate efficiency is the most influential effect on the initial current capacity of lead acid battery. Thus, in this study, we have investigated the curing effect of the positive plate, which is one of the important lead acid battery processes. The curing process of the positive plate is performed either with the separation of each plate with 1mm gap or with no gap of plate. As a result, when there is no interval between each plate, the higher temperature current happened than expected, resulting in the changes in the initial current efficiency of the lead acid battery. The chemical composition and crystal structure of a material coated on the positive plate were identified with XRD and SEM. It was resulted that were only there not a lot of 4BS (tetrabasic-lead sulfate, $4PbO{\cdot}PbSO_4)$ on the plate in case of curing of plates without interval, but a large quantity of $Pb_3O_4$ also formed on the surface. On the other hand, it was observed that 3BS (tribasic-lead sulface, $3PbO{\cdot}PbSO_4{\cdot}H_2O)$ was the main product on the plate in case of typical curing process with some interval. From the initial current capacity test, the positive plate having 3BS was approximately 40% higher in initial current capacity than that having 4BS. It was concluded that 4BS and $Pb_3O_4$ on the plate surface were harmful to the initial current capacity of lead acid battery.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.65 no.6
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• pp.962-968
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• 2016

The large scaled lead-acid battery is widely used for efficient operation of the photovoltaic system in many islands. However, lithium-ion battery is now being introduced to mitigate the fluctuation of wind power and to replace lead-acid battery. Therefore, hybrid ESS(Energy Storage system) that combines lithium-ion battery with lead-acid battery is being required because lithium-ion battery is costly in present stage. Under this circumstance, this paper presents the optimal algorithm to create composition rate of hybrid ESS by considering fixed and variable costs in order to maximize advantage of each battery. With minimization of total cost including fixed and variable costs, the optimal composition rate can be calculated based on the various scenarios such as load variation, life cycle and cost trend. From simulation results, it is confirmed that the proposed algorithms are an effective tool to produce a optimal composition rate.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.1
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• pp.49-54
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• 2016

The large scaled lead-acid battery is widely used for efficient operation of the photovoltaic system in many islands. However, lithium-ion battery is now being introduced to mitigate the fluctuation of wind power and to replace lead-acid battery. Therefore, hybrid ESS (Energy Storage system) that combines lithium-ion battery with lead-acid battery is being required because lithium-ion battery is costly in present stage. Under this circumstance, this paper presents the optimal algorithm to create composition rate of hybrid ESS by considering fixed and variable costs in order to maximize advantage of each battery. With minimization of total cost including fixed and variable costs, the optimal composition rate can be calculated based on the various scenarios such as load variation, life cycle and cost trend. From simulation results, it is confirmed that the proposed algorithms are an effective tool to produce a optimal composition rate.