• Title/Summary/Keyword: Layered material

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Syntheses and Characteristics of Layered Perovskite $La_{2-x}Ca_{1+x}Mn_{2}O_{7}$ (층상구조형 페롭스카이트 $La_{2-x}Ca_{1+x}Mn_{2}O_{7}$상의 합성 및 특성)

  • 서상일;이재열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.555-558
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    • 2000
  • Layered perovskite La$_{2-x}$Ca$_{l-x}$Mn$_2$O$_{7}$ phases were synthesized by solid state reaction. Single phase R-P could be obtained in the range of 0.4$_{2-x}$Ca$_{l-x}$Mn$_2$O$_{7}$. About 30% of MR ratio was obtained at 270K when 5 T of magnetic field was applied.ied.ied.ied.

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Synthesis and Characterization of Molecular Composite Prepared from Layered Perovskite Oxide, $HLa_2Ti_2NbO_{10}$

  • 홍영식;김시중
    • Bulletin of the Korean Chemical Society
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    • v.18 no.6
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    • pp.623-628
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    • 1997
  • A layered perovskite oxide, $RbLa_2Ti_2NbO_{10}$, was prepared and investigated for proton exchange and intercalation behaviors. Its protonated form, $Hla_2Ti_2NbO_{10}$, exhibits the Bronsted acidity and reacts with organic amines. Polyoxonuclear cation, 4Al_{13}$, was then introduced into the interlayer by refluxing octylamine-intercalated compound with an $Al_{13}$ pillaring solution. These layered oxides were characterized by X-ray diffractometer, thermogravimeter, FT-infrared spectrometer and elemental analyzer. It is observed that the polyoxonuclear cation-pillared material exhibits a bilayer structure and is thermally more stable than organic counterpart at higher temperatures. The surface area of the pillared material annealed at 400 ℃ was the value of 25.1 m²/g.

Analysis Method of Transmission Characterization for Multi-layered Composite Material Based on Homogenization Method

  • Hyun, Se-Young;Song, Yong-Ha;Jeoun, Young-Mi;Kim, Bong-Gyu
    • Journal of Aerospace System Engineering
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    • v.15 no.6
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    • pp.59-65
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    • 2021
  • In this paper, the transmission characteristics of the multi-layered composite material with wire mesh and honeycomb core for aircraft applications have been analyzed with the proposed method. The proposed method converts the conductive wire mesh into effective layer, while for the dielectric honeycomb core, effective permittivity has been derived based on volume fraction with the proposed method. The proposed method has been verified through comparison with full-wave simulation and revealed excellent. In addition, the calculation time of the proposed method is a few order of magnitude faster in comparison with the full-wave simulation.

First-Principles Study on the Electronic Structure of Bulk and Single-Layer Boehmite

  • Son, Seungwook;Kim, Dongwook;Na-Phattalung, Sutassana;Ihm, Jisoon
    • Nano
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    • v.13 no.12
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    • pp.1850138.1-1850138.6
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    • 2018
  • Two-dimensional (2D) or layered materials have a great potential for applications in energy storage, catalysis, optoelectronics and gas separation. Fabricating novel 2D or quasi-2D layered materials composed of relatively abundant and inexpensive atomic species is an important issue for practical usage in industry. Here, we suggest the layer-structured AlOOH (Boehmite) as a promising candidate for such applications. Boehmite is a well-known layer-structured material and a single-layer can be exfoliated from the bulk boehmite by breaking the interlayer hydrogen bonding. We study atomic and electronic band structures of both bulk and single-layer boehmite, and also obtain the single-layer exfoliation energy using first-principles calculations.

Controlled Growth of Layered Silver Stearate on 2D and 3D Surfaces

  • Lee, Seung-Joon;Han, Sang-Woo;Kim, Kwan
    • ETRI Journal
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    • v.25 no.6
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    • pp.517-522
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    • 2003
  • This investigation confirms that silver stearate consists of an infinite-sheet, two-dimensional, nonmolecular layered structure. Scanning electron microscopy, X-ray diffraction, and infrared spectroscopy reveal the following: plate-like morphology is identified from the SEM image, XRD peaks can be indexed to the (0k0) reflections of a layered structure, and infrared peaks show that alkyl chains are present in an all-trans conformational state with little or no significant gauche population. Based on these structural characteristics, we demonstrate that silver stearate, a prototype of layered organic-inorganic hybrid material, can be grown not only in a designed two-dimensional pattern but also in three-dimensionally ordered ways by using carboxyl-group terminated nanoparticles as a template.

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A Literature Study on the Development of Cementitious Materials using a Layered Double Hydroxide (층상이중수산화물(Layered Double Hydroxides)을 활용한 시멘트계 재료 개발에 관한 문헌조사 연구)

  • Lee, Seung-Yeop;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.107-108
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    • 2015
  • Layered Double Hydroxides is known as a hydrotalcite-like material. It is a type of anionic clay with planar structure. It is composed of layer structure which is able to exchange anion between two layers which includes divalent ion and trivalent ion. Therefore, layered double hydroxide is applicable for eliminating harmful heavy metals and anionic substances which exist in the concrete. Because it is also able to be used as catalyst and has high possibility of utilization, It is getting an large amount of attention recently. In this study, an analysis on the structure of the layerd double hydroxide (LDH) which is possible to bind the anion was carried out.

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Effect of Organically Modified Layered Silicate on Thermal, Mechanical, and Electrical Properties of Epoxy-Based Nanocomposites

  • Park, Jae-Jun;Kwon, Soon-Seok;Lee, Jae-Young
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.4
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    • pp.135-139
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    • 2011
  • In an effort to develop new electrical insulation materials, four different kinds of organically modified layered silicate were incorporated into an epoxy matrix to prepare nanocomposites for electrical insulation. Five wt% of organically modified layered silicates were processed in a planetary centrifugal mixer in an epoxy matrix, and the thermal, mechanical, and electrical properties of the cured epoxy/layered silicate were investigated. The morphology of the nanoscale silicate dispersed in the epoxy matrix was observed using transmission electron microscopy, and the interlayer distance was measured by wide-angle X-ray scattering diffraction analysis.

The applications and conduct of vibration equations for constrained layered damped plates with impact

  • Luo, G.M.;Lee, Y.J.;Huang, C.H.
    • Steel and Composite Structures
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    • v.8 no.4
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    • pp.281-296
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    • 2008
  • Visco-elastic material and thin metals were adhered to plate structures, forming the composite components that are similar to the sandwich plates, called constrained layered damped (CLD) plates. Constrained layer damping has been utilized for years to reduce vibration, and advances in computation and finite element analysis software have enabled various problems to be solved by computer. However, some problems consume much calculation time. The vibration equation for a constrained layered damped plate with simple supports and an impact force is obtained theoretically herein. Then, the results of the vibration equation are compared with those obtained using the finite element method (FEM) software, ABAQUS, to verify the accuracy of the theory. Finally, the 3M constrained layer damper SJ-2052 was attached to plates to form constrained layered damped plates, and the vibration equation was used to elucidate the damping effects and vibration characteristics.

A Study on Flame Spread Prevention of Sandwich Panel (복합자재 화재확산방지구조에 대한 연구)

  • Cho, Nam-Wook;Kim, Do-Hyun;Shim, Ji-Hun
    • Fire Science and Engineering
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    • v.29 no.6
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    • pp.84-90
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    • 2015
  • Multi-layered material (sandwich panel) consists of double-sided steel plate which is incombustible material or similar material and core material which is not incombustible material. In case of sandwich panel which uses combustible material as insulation, flames spread inside the steel plate at the time of fire so that it is difficult to extinguish fire from the outside and flames spread rapidly and may cause the building to collapse. The current Building Act requires the sandwich panel to secure fire-retardant performance according to the purpose and size of building. In this study, the fire spreading prevention structure applied to partial exterior walls was applied to multi-layered material and its effect was measured through full scale fire test and the possibility to secure fire safety of buildings by applying the fire spreading prevention structure to multi-layered material in future was presented.