• Title/Summary/Keyword: Lattice diffusion

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Effects of Additives and Atmospheres on the Grain Growth of TiO2 Ceramics (분위기와 첨가제가 TiO2 세라믹스의 입자성장에 미치는 영향)

  • 박정현;최헌진;박한수
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.390-398
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    • 1988
  • Effects of atmospheres and adidtives on the grain growth of TiO2 ceramics were investigated. In the range of 1300~140$0^{\circ}C$, grain growth was increased in CO2 as compared with O2 atmosphere and the grain boundary migration activation energy was lower than the diffusion activation energy of oxygen ion in TiO2. Also, in the case of addition of oxides, the grain growth was increased by oxides acting as a acceptor andinhibited by oxides acting as a donor. From the above results, when the oxygen vacancy concentration was increased, the intrinsic grain boundary mobility was increased and the pore drag force was decreased due to the rapid densification. Also it seems that the pore was migrated by the surface diffusion rather than lattice diffusion.

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Permittivity of Solid State Electron Plasma Including the Effect of Diffusion (고상전자 프라즈마의 유도율과 확산현상과의 관계)

  • Cho, Chul
    • 전기의세계
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    • v.20 no.6
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    • pp.19-21
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    • 1971
  • Permittivities are closely related to lattice vibrations and dispersions relations, and this paper deals with the tensor permittivities which include the effect of diffusion. It is a great convenience in the consideration of plasma waves to treat the plasma as a dielectric medium with its circumference. And, on the assumption that the motion of the ionized donors be neglected the general expression from which the tensor permittivity can be derived is derived from the view point that the plasma can be treated as a hydrodynamical fluid. The effect of diffusion appears as perturbation terms in the tensor permittivities of the non-streaming solid state electron magnetoplasmas and affects no influence on the anisotropic terms in the specific configuration.

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DIRICHLET FORMS AND DIFFUSION PROCESSES RELATED TO QUANTUM UNBOUNDED SPIN SYSTEMS

  • Lim, Hye-Young;Park, Yong-Moon;Yoo, Hyun-Jae
    • Journal of the Korean Mathematical Society
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    • v.33 no.4
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    • pp.823-855
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    • 1996
  • We study Dirichlet forms and the associated diffusion processes for the Gibbs measures related to the quantum unbounded spin systems (lattice boson systems) interacting via superstable and regular potentials. This work is a continuation of the author's previous study on the classical systems [LPY] to the quantum cases. In [LPY], we constructed Dirichlet forms and the associated diffusion processes for the Gibbs measures of classical unbounded spin systems. Furthermore, we also showed the essential self-adjointness of the Dirichlet operator and the log-Sobolev inequality for any Gibbs measure under appropriate conditions on the potentials. In this atudy we try to extend the results of the classical systems to the quantum cases. Because of some technical difficulties, we are only able to construct a Dirichlet form and the associated diffusion process for any Gibbs measure of the quantum systems. We utilize the general scheme of the previous work on the theory in infinite dimensional spaces [AH-K1-2, AKR, AR1-2, Kus, MR, Ro, Sch] and the ideas we employed in our study of the calssical systems ]LPY].

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A Study on the Crystallization of Grain-Boundary Phases in Si3N4-Y2O3-Al2O3 System (Si3N4-Y2O3-Al2O3계의 입계상 결정화에 관한 연구)

  • 박정현;황종희
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.13-20
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    • 1989
  • After sintering Si3N4 containing 20wt% of variable composition ratio of Y2O3 and Al2O3 at 1$600^{\circ}C$, the specimens were annealed at 125$0^{\circ}C$ and 135$0^{\circ}C$ for 5, 10, 15 hours in order to crystallize the remanining oxynitride glass phases. The main grain-boundary crystalline phases in the Si3N4-Y2O3-Al2O3 system were melilite and YAG. By annealing 15hrs. at 125$0^{\circ}C$, almost all of the glasses were crystallized. During the growth of melilite, lattice volyume of $\beta$-Si3N4 was increased as Al3+ and O2- ions in the oxynitride glass diffuse into $\beta$-Si3N4 lattice, but during the growth of YAG, lattice volume of $\beta$-Si3N4 was decreased by reverse diffusion of Al3+ and O2- ions. In case of crystallization of glass phase to melilite, thermal expansion of sample was decreased, but in case of crystallization to YAG, inverse phenomen on was observed.

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Fabrication of the Bulk Superconductor by Thermal Diffusion Process (열확산 프로세스에 의한 초전도 벌크 합성)

  • Lee, Sang Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.6
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    • pp.461-465
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    • 2021
  • A diffusion heat treatment process for YBa2Cu3O7-y bulk superconductor in a Gd2O3 powder was attempted. As a result of measuring the critical temperature of the superconducting bulk, there was no change in the superconducting transition temperature as the Gd particles diffused into the YBa2Cu3O7-y lattice, resulting in dense microstructure. As a result of measuring the critical current, the critical current density (Jc) of the superconducting bulk having treated by the Gd thermal diffusion treatment at 0 T increased to 3×104 A/cm2 at 0 T, which was higher than that of the superconducting bulk without thermal diffusion treatment. The surface magnetic force of the superconducting bulk with Gd thermal diffusion treatment was observed at the center of the superconducting bulk with the maximum trapped magnetic force (Hmax) of 1.51 kG. This result means that the Gd thermal diffusion treatment contributes to improving the critical current density Jc of YBa2Cu3O7-y, and it is believed that Gd particles migrating into the superconducting bulk through thermal diffusion either fill the surface pores of YBa2Cu3O7-y superconductors or act as a flux pinning center.

Development of nodal diffusion code RAST-V for Vodo-Vodyanoi Energetichesky reactor analysis

  • Jang, Jaerim;Dzianisau, Siarhei;Lee, Deokjung
    • Nuclear Engineering and Technology
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    • v.54 no.9
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    • pp.3494-3515
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    • 2022
  • This paper presents the development of a nodal diffusion code, RAST-V, and its verification and validation for VVER (vodo-vodyanoi energetichesky reactor) analysis. A VVER analytic solver has been implemented in an in-house nodal diffusion code, RAST-K. The new RAST-K version, RAST-V, uses the triangle-based polynomial expansion nodal method. The RAST-K code provides stand-alone and two-step computation modes for steady-state and transient calculations. An in-house lattice code (STREAM) with updated features for VVER analysis is also utilized in the two-step method for cross-section generation. To assess the calculation capability of the formulated analysis module, various verification and validation studies have been performed with Rostov-II, and X2 multicycles, Novovoronezh-4, and the Atomic Energy Research benchmarks. In comparing the multicycle operation, rod worth, and integrated temperature coefficients, RAST-V is found to agree with measurements with high accuracy which RMS differences of each cycle are within ±47 ppm in multicycle operations, and ±81 pcm of the rod worth of the X2 reactor. Transient calculations were also performed considering two different rod ejection scenarios. The accuracy of RAST-V was observed to be comparable to that of conventional nodal diffusion codes (DYN3D, BIPR8, and PARCS).

Mössbauer Study of the Dynamics in BaFe12O19 Single Crystals

  • Choi, J.W.;Sur, J.C.;Lim, Jung-Tae;Kim, Chin-Mo;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.17 no.1
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    • pp.6-8
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    • 2012
  • M$\ddot{o}$ssbauer spectra of hexagonal $BaFe_{12}O_{19}$ single crystals were studied at various temperatures (4-300 K). It was found that the spin states in Fe atoms were parallel to the ${\gamma}$-ray's direction into a single crystal along the caxis. The location of the Fe ion in the 2b site is unusual in an oxide structure and has strong anisotropic lattice vibrations. Moreover, at room temperature, the zero absorption lines of the Fe ions at the 2b site were observed due to fast diffusion motion in a double well atomic potential. The two Fe ions of the single crystal mainly enter into the sites in the mirror plane of the trigonalbipyramidal structure.

GLOBALIZATION OF A LOCAL MARKET DYNAMICS ONTO AN INFINITE CHAIN OF LOCAL MARKETS

  • Kim, Yong-In
    • The Pure and Applied Mathematics
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    • v.16 no.1
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    • pp.133-145
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    • 2009
  • The purpose of this paper is to extend and globalize the Walrasian evolutionary cobweb model in an independent single local market of Brock and Hommes ([3]), to the case of the global market evolution over an infinite chain of many local markets interacting each other through a diffusion of prices between them. In the case of decreasing demands and increasing supplies with a weighted average of rational and naive predictors, we investigate, via the methods of Lattice Dynamical System, the spatial-temporal behaviors of global market dynamics and show that some kind of bounded dynamics of global market do exist and can be controlled by using the parameters in the model.

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Low-Temperature Sinterbility of Semiconducting $BaTiO_3$ Ceramics with $Pb_5Ge_3O_11$ Additives ($Pb_5Ge_3O_11$에 의한 반도성 $BaTiO_3$ 세라믹스의 저온소결성)

  • 윤상옥;정형진;윤기현
    • Journal of the Korean Ceramic Society
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    • v.28 no.5
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    • pp.359-364
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    • 1991
  • The effects of Pb5Ge3O11 on the sinterbility and lattice variation of the semiconducting 0.15 mol% Y2O3 doped BaTiO3 have been investigated as functions of additive contents (from 0.25 mol% to 2.5 mol%) and sintering temperatures (from 110$0^{\circ}C$ to 130$0^{\circ}C$). As the amount of Pb5Ge3O11 increases, the sinterbility of BaTiO3 increases abruptly at around 115$0^{\circ}C$. During the sintering, the most of Pb+2 ions in additives penetrate into BaTiO3 lattices and Ge+4 ions present at grain boundaries. Therefore the c lattice of the BaTiO3 increases largely and then the tetragonality increases due to the diffusion of the Pb+2 ions.

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STATIONARY GLOBAL DYNAMICS OF LOCAL MARKETS WITH QUADRATIC SUPPLIES

  • Kim, Yong-In
    • The Pure and Applied Mathematics
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    • v.16 no.4
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    • pp.427-441
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    • 2009
  • The method of Lattice Dynamical System is used to establish a global model on an infinite chain of many local markets interacting each other through a diffusion of prices between them. This global model extends the Walrasian evolutionary cobweb model in an independent single local market to the global market evolution. We assume that each local market has linear decreasing demands and quadratic supplies with naive predictors, and investigate the stationary behaviors of global price dynamics and show that their dynamics are conjugate to those of $H{\acute{e}}non$ maps and hence can exhibit complicated behaviors such as period-doubling bifurcations, chaos, and homoclic orbits etc.

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