• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.1857-1860
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• 2003

The ablative decomposition mechanism of PMMA(polymethyt methacrylate), PET(polyethylene terephthalate) and PC(polycarbonate) with KrF excimer laser(λ: 248nm, pulse duration: 5ns) is investigated. The UV/Vis spectrometer analysis showed that PMMA is a weak absorber and PET, PC are a strong absorber at the wavelength of 248nm. The results(surface debris, melt, etch depth, etching shape) from drilling and direct writing experiments imply that ablation mechanism of PMMA is dominated by photothermal process, while that of PET, PC are dominated by photochemical process.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.11
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• pp.969-975
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• 2000

Laser direct writing of micro-patterned copper lines has been achieved by pyrolytic decomposition of copper formate films (Cu(HCOO)$_2$.4$H_2O$), as a metallo-organic precursor, using a focused CW Ar$^{+}$ laser beam (λ=514nm) on PCB boards and glass substrates. The linewidth and thickness of the lines wee investigated as a functin of laser power and scan speed. The profiles of the lines were measured by scanning electron microscope (SEM), surface profiler ($\alpha$-step) and atomic force measured by scanning electron microscope (SEM), surface profiler ($\alpha$-step) and atomic force microscopy (AFM). The electrical resistivities of the patterned lines were also investigated as a function of laser parameters using probe station and semiconductor analyzer. We compared resistivities of the patterned copper lines with these of the Cu bulk. Resistivities decreased due to changes in morphology and porosity of the deposit, which were about 3.8 $\mu$$\Omega$cm and 12$\mu$$\Omega$cm on PCB and glass substrates after annealing at 30$0^{\circ}C$ for 5 minutes.s.

• Journal of the Korean Society of Propulsion Engineers
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• v.12 no.3
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• pp.1-8
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• 2008

We present a model for simulating high energy laser heating of metal for ignition of energetic materials. The model considers effect of ablation of steel plate with long laser pulses and continuous lasers of several kilowatts and the thermal response of well-characterized high explosives for ignition. Since there is enough time for the thermal wave to propagate into the target and to create a region of hot spot in the high explosives, electron thermal diffusion of ultra-short (femto- and pico-second) lasing is ignored; instead, heat diffusion of absorbed laser energy in the solid target is modeled with thermal decomposition kinetic models of high explosives. Numerically simulated pulsed-laser heating of solid target and thermal explosion of RDX, TATB, and HMX are compared to experimental results. The experimental and numerical results are in good agreement.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.270-276
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• 2008

$N_2$ doped $TiO_2$ nano-sized powder was prepared using a DC arc plasma jet and investigated with XRD, BET, SEM, TEM, and photo-catalytic decomposition. Recently the research interest about the nano-sized $TiO_2$ powder has been increased to improve its photo-catalytic activity for the removal of environmental pollutants. Nitrogen gas, reacting gas, and titanium tetrachloride ($TiCl_4$) were used as the raw materials and injected into the plasma reactor to synthesize the $N_2$ doped $TiO_2$ power. The particle size and XRD peaks of the synthesized powder were analyzed as a function of the flow rate of the nitrogen gas. Also, the characteristics of the photo-catalytic decomposition using the prepared powder were studied. For comparing the photo-catalytic decomposition performance of $TiO_2$ powder with that of $TiO_2$ coating, $TiO_2$ thin films were prepared by the spin coating and the pulsed laser deposition. For the results of the acetaldehyde decomposition, the photo-catalytic activity of $TiO_{2-x}N_x$ powder was higher than that of the pure $TiO_2$ powder in the visible light region. For the methylene blue decomposition, the decomposition efficiency of $TiO_2$ powder was also higher than that of $TiO_2$ film.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.889-891
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• 1998

Copper films have been deposited on glass substrate via a thermal decomposition of copper(II) formate using a focused $Ar^+$ laser emitting at 514 nm. The growth kinetics of these Cu films was investigated as a function of laser power and scan speed which varied in the range of 70-150 mW and 0.1-20 mm/s, respectively. The resistivity of the copper films was a factor of about 20 higher than· that of bulk value, but the resistivity decreased due to changes in morphology and porosity of the deposit after annealing at $300^{\circ}C$, 5 min. and was about $10{\mu}{\Omega}cm$.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.10 s.181
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• pp.2560-2567
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• 2000

When spatially dense velocity distribution is measured by a scanning laser Doppler vibrometer, the Fourier transform method provides the real and imaginary parts of the mode shapes in the form of a polynomial. However the Fourier transform method is often impractical because the independent decomposition property of cosine and sine components into real and imaginary parts, respectively, does not hold due to the leakage problem which commonly occurs in the Fourier transform of harmonic signals. To deal with this problem, a Hilbert transform method is newly proposed in this article. The proposed method is free from the leakage problem and relatively robust to the scanning error. A simulation example is provided to verify the effectiveness of this method.

• Proceedings of the KSME Conference
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• 2000.04a
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• pp.420-425
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• 2000

When spatially dense velocity distribution is measured by a scanning laser Doppler vibrometer, the Fourier transform method provides the real and imaginary parts of the mode shapes in the form of a polynomial. However the Fourier transform method is often impractical because the independent decomposition property of cosine and sine components into real and imaginary parts, respectively, does not hold due to the leakage problem which commonly occurs in the Fourier transform of harmonic signals. To deal with this problem, a Hilbert transform method is newly proposed in this article. The proposed method is free from the leakage problem and relatively robust to tire scanning error. A simulation example is provided to verify the effectiveness of this method.

• Bulletin of the Korean Chemical Society
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• v.9 no.3
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• pp.161-164
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• 1988

Infrared multiphoton decompositions (IRMPD) of $BrCH_2CH_2CH_2CH_2Cl$ were studied by using the pulsed $CO_2$laser. At 0.3 J laser energy the experimentally observed product ratios could be reasonably explained by the RRKM calculation with initial excitation energy of ca. 80 Kcal/mol. The pressure dependence of product yields led us to conclude that the collisional deactivation by the inert gas decreased the yield of low energy dissociation channel more significantly.

• Journal of the Korean Society for Precision Engineering
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• v.19 no.7
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• pp.106-115
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• 2002

Growth characteristics of micro carbon structures fabricated by laser-assisted chemical vapor deposition are studied. Argon ion laser and ethylene were used as the energy source and reaction gas, respectively, to grow micro carbon rod through pyrolytic decomposition of the reaction gas. Experiments were performed at various conditions to investigate the influence of process parameters on growth characteristics such as the diameter or growth rate of the micro carbon rod with respect to reaction gas pressure and incident laser power. Reaction gas pressure in experiments ranges from 200 to 600Torr and the incident laser power from 0.3 to 3.8W. For these conditions, the diameter of the rod increases linearly with respect to the laser power but is almost independent of the reaction gas pressure. Growth rate of the rod changes little with gas pressure when the laser power remains below IW. For a constant reaction gas pressure, the growth rate increase with Increasing laser power, but the rate of increase decreases gradually, implying that the chemical vapor deposition condition changes from a kinetically-limited regime to a mass-transport-limited regime. When the carbon rod was grown at near threshold laser power, a very smooth surface is obtained on the rod. By continuously moving the focusing lens in the direction of growth, a micro carbon rod with a diameter of 287${\mu}{\textrm}{m}$ and aspect ratio of 100 was fabricated..

• Korean Journal of Remote Sensing
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• v.28 no.3
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• pp.307-318
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• 2012

To understand forest structures, the Geoscience Laser Altimeter System (GLAS) instrument have been employed to measure and monitor forest canopy with feasibility of acquiring three dimensional canopy structure information. This study tried to examine the potential of GLAS dataset in measuring forest canopy structures, particularly maximum canopy height estimation. To estimate maximum canopy height using feasible GLAS dataset, we simply used difference between signal start and ground peak derived from Gaussian decomposition method. After estimation procedure, maximum canopy height was derived from airborne Light Detection and Ranging (LiDAR) data and it was applied to evaluate the accuracy of that of GLAS estimation. In addition, several influences, such as topographical and biophysical factors, were analyzed and discussed to explain error sources of direct maximum canopy height estimation using GLAS data. In the result of estimation using direct method, a root mean square error (RMSE) was estimated at 8.15 m. The estimation tended to be overestimated when comparing to derivations of airborne LiDAR. According to the result of error occurrences analysis, we need to consider these error sources, particularly terrain slope within GLAS footprint, and to apply statistical regression approach based on various parameters from a Gaussian decomposition for accurate and reliable maximum canopy height estimation.