• Title/Summary/Keyword: Laser Raman Scattering

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Phase Stability of Laser-ablated $SmBa_2Cu_3O_{7-y}$ thin Films Investigated by Raman Scattering Spectroscopy

  • Kim, G.;Jeong, A.R.;Jo, W.;Park, D.Y.;Cheong, H.;Tsukada, A.;Hammond, R.H.;Beasley, M.R.
    • Progress in Superconductivity
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    • v.11 no.2
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    • pp.141-146
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    • 2010
  • Phase stability diagram and boundary of a- and c-axis orientation of $SmBa_2Cu_3O_{7-y}$ (SmBCO) thin films grown by pulsed laser deposition (PLD) were reported with studies based on x-ray diffraction [1]. Four different samples are systematically analyzed: normal c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$, a-axis oriented $SmBa_2Cu_3O_{7-y}$, c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$ with $Sm_2BaCuO_5$ phase, and a mixture with c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$ and anomalously long-c tetragonal $SmBa_2Cu_3O_x$. Raman scattering spectroscopy equipped with polarization analysis elucidates the crystal orientation and the origin of the growth of the materials. It indicates that the technique can be used for quality control of conductor manufacturing processes as well as for enhancement of the materials properties.

The Characteristics of Resonant Stimulated Raman Scattering in the water droplet (미세 물방울에서의 공명 유도라만산란의 특성)

  • 문희종;김광훈;임용식;고춘수;이재형;장준성
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.337-344
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    • 1995
  • We have detected the resonant stimulated Raman scattering signal when the Q-switched Nd:YAG laser beam are incident on the $35~62{\mu}m$ sized water droplet as pump beam. The signals appeared as uniformly spaced peaks and the intervals between peaks become narrow as the droplet size increases. Also we have confirmed the morphology dependent resonances (MDR's) characteristic of the stimulated Raman scattering signal when the water droplet becomes nearly spherical shape after two water droplets are coupled to a droplet. The error in the measured intervals between MDR's of same mode order is about 5%.out 5%.

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Measurements of Equivalence Ratio in the Spark Plug Gap and Its-Effects on Combustion Under Stratified Mixture Conditions in a Constant Volume Chamber (정적 연소실에서 성층화된 혼합기 조건하의 점화 전극사이 당량비 측정과 연소 특성에 미치는 영향)

  • Bae, Sang-Su;Lee, Gi-Cheol;Min, Gyeong-Deok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.10
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    • pp.1311-1317
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    • 2001
  • To investigate only the effects of the stratified mixture distribution on initial flame propagation and combustion characteristics, the instantaneous equivalence ratio in the spark plug gap and combustion pressure were measured simultaneously In a constant volume chamber, To induce the stratified propane-air mixture distribution near the spark plug, counter-flow typed mixture injection system was used under the constant mean equivalence ratio $\Phi$$\_$mean/= 1.0 The instantaneous equivalence ratio was measured by a single-shot Raman scattering with narrow-band KrF excimer laser. The measuring error was within the limit of $\pm$ 3.5% provided that the proposed method was applied to the measured Raman signals. Judging from mass fraction burned derived from the measured pressure, the optimum combustion characteristics were shown under the condition that the local equivalence ratio in the spark plug was near 1.28$\pm$0.04, and these characteristics were more remarkable at the initial stage of combustion.

Raman Chemical Imaging Technology for Food and Agricultural Applications

  • Qin, Jianwei;Kim, Moon S.;Chao, Kuanglin;Cho, Byoung-Kwan
    • Journal of Biosystems Engineering
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    • v.42 no.3
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    • pp.170-189
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    • 2017
  • Purpose: This paper presents Raman chemical imaging technology for inspecting food and agricultural products. Methods The paper puts emphasis on introducing and demonstrating Raman imaging techniques for practical uses in food analysis. Results & Conclusions: The main topics include Raman scattering principles, Raman spectroscopy measurement techniques (e.g., backscattering Raman spectroscopy, transmission Raman spectroscopy, and spatially offset Raman spectroscopy), Raman image acquisition methods (i.e., point-scan, line-scan, and area-scan methods), Raman imaging instruments (e.g., excitation sources, wavelength separation devices, detectors, imaging systems, and calibration methods), and Raman image processing and analysis techniques (e.g., fluorescence correction, mixture analysis, target identification, spatial mapping, and quantitative analysis). Raman chemical imaging applications for food safety and quality evaluation are also reviewed.

Development of a Raman Lidar System Using the Photon-counting Method to Measure Carbon Dioxide (이산화탄소 원격 계측을 위한 광 계수 방식의 라만 라이다 장치 개발)

  • Sun Ho Park;In Young Choi;Moon Sang Yoon
    • Korean Journal of Optics and Photonics
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    • v.35 no.2
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    • pp.71-80
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    • 2024
  • We developed a Raman lidar system for remote measurement of carbon dioxide present in atmospheric space. An air-cooled laser with 355-nm wavelength and a 6-inch optical receiver was used to miniaturize the Raman lidar system, and a scanning Raman lidar system was developed using a two-axis scanning device and a photon counter. To verify the performance of the developed Raman lidar system, a gas chamber capable of maintaining a concentration was located at a distance of about 87 m, and the change in Raman signal according to the change in the concentration of carbon dioxide was measured. As a result, it was confirmed that the change in the Raman scattering signal of carbon dioxide that appeared for a change in carbon dioxide concentration from about 0.67 to 40 vol% was linear, and the coefficient of determination (R2) value, which indicates the correlation between the carbon dioxide concentration and Raman scattering signal, showed a high linearity of 0.9999.

Analysis of Xe Plasma by LAS (레이저 흡수법을 이용한 제논 플라즈마 분석)

  • Yang, Jong-Kyung;Her, In-Sung;Lee, Jong-Chan;Choi, Yong-Sung;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.220-222
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    • 2005
  • We can classify two cases in a way to observe an atom of gas state or a molecule using the laser. First case is way to use dispersion phenomenon like Rayleigh scattering, Thomson scattering, Mie scattering, Raman Scattering. And Second case is a way to use change phenomenon like a LAS (Laser Absorption Spectroscopy), LIF (Laser Induced Fluorescent). In this paper, we have measured the meta-stable density and the distribution by using a LAS method in Xe discharge lamp. The laser absorption spectroscopy (LAS) is useful to investigate the behavior of such species. The xenon atoms in the $1S_4$ and $1S_5$ generate excited $Xe^*$(147nm) and $Xe_{2}^*$(173nm) dimers in Xe plasma. It is found that the intensity of VUV 147nm emission is proportional to that of the IR 828nm emission, and the VUV 173nm emission is roughly proportional to that of the IR 823nm emission. The laser is used CW laser that consist of AlGaAs semiconductor and energy level is used 823.16nm wavelength. We measured signal of monochrometer from the lamp center while will change a discharge electric current by 6mA in 3mA and calculated meta-stable state density of a xenon atom through a measured value.

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Aggregation of Polyynes on Metal Nanoparticles

  • Kim, Kuk-Ki;Shin, Seung-Keun;Park, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.625-628
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    • 2012
  • We investigated the interaction between polyynes (linear carbon chains) and various metal nanoparticles (Ag, Au, and Cu) to provide insight into the optical properties of metal-polyynes systems prepared by different experimental techniques. Polyynes were produced by laser ablation in deionized water, metal nanoparticles solutions, and copper chloride solution. Metal nanoparticles complexes with polyynes were analyzed by Raman, surface-enhanced Raman scattering, and UV-vis spectroscopy.

Evolution of stokes pulses of stimulated Raman scattering in a Ge$O_2$-doped multimode fiber (Ge$O_2$-doped 다중모드 파이버에서 유도라만산한의 스토크스 펄스의 발생)

  • Yi, Yong-Woo;Hwang, In-Duk
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.11a
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    • pp.529-532
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    • 2002
  • We experimentally investigate the evolution of nanosecond Stokes pulses in a single-pass Raman laser pumped by a Q-switched Nd: YAG laser at 1064 nm. As a Raman medium, a GeO$_2$-doped graded-index multimode fiber of 220m long is used. We demonstrate that efficient generation of several Stokes components with 1.5-2.7 nanosecond pulsewidth is obtained by varying the input pump energy.

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The Design and Test of the Stand-off Surface Chemical Contaminant Detection System based on Raman Spectroscopy (비접촉식 지표면 화학 오염 탐지용 라만 분광시스템 설계 및 성능확인)

  • Koh, Young Jin
    • Journal of the Korea Institute of Military Science and Technology
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    • v.22 no.3
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    • pp.433-440
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    • 2019
  • In order to detect toxic chemical spread on field ground, we developed stand-off Raman spectrometer system which employed a deep UV laser. In this paper, the design and specification of various components in the spectrometer system are described. Some results when the detection system was tested on the outdoor roads are shown, which may help researching stand-off chemical detectors based on Raman spectroscopy.

Local transport properties of coated conductors by laser-scan imaging methods

  • Kim, Gracia;Jo, William;Nam, Dahyun;Cheong, Hyeonsik;Moon, Seoung Hyun
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.2
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    • pp.1-4
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    • 2016
  • To observe the superconducting current and structural properties of high critical temperature ($T_c$) superconductors (HTS), we suggest the following imaging methods: Room temperature imaging (RTI) through thermal heating, low-temperature bolometric microscopy (LTBM) and Raman scattering imaging. RTI and LTBM images visualize thermal-electric voltages as different thermal gradients at room temperature (RT) and superconducting current dissipation at near-$T_c$, respectively. Using RTI, we can obtain structural information about the surface uniformity and positions of impurities. LTBM images show the flux flow in two dimensions as a function of the local critical currents. Raman imaging is transformed from Raman survey spectra in particular areas, and the Raman vibration modes can be combined. Raman imaging can quantify the vibration modes of the areas. Therefore, we demonstrate the spatial transport properties of superconducting materials by combining the results. In addition, this enables visualization of the effect of current flow on the distribution of impurities in a uniform superconducting crystalline material. These imaging methods facilitate direct examination of the local properties of superconducting materials and wires.