• Restorative Dentistry and Endodontics
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• v.43 no.1
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• pp.11.1-11.10
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• 2018

Objectives: This study aimed to introduce the use of laser-induced breakdown spectroscopy (LIBS) for evaluation of the mineral content of root canal dentin, and to assess whether a correlation exists between LIBS and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) methods by comparing the effects of irrigation solutions on the mineral content change of root canal dentin. Materials and Methods: Forty teeth with a single root canal were decoronated and longitudinally sectioned to expose the canals. The root halves were divided into 4 groups (n = 10) according to the solution applied: group NaOCl, 5.25% sodium hypochlorite (NaOCl) for 1 hour; group EDTA, 17% ethylenediaminetetraacetic acid (EDTA) for 2 minutes; group NaOCl+EDTA, 5.25% NaOCl for 1 hour and 17% EDTA for 2 minutes; a control group. Each root half belonging to the same root was evaluated for mineral content with either LIBS or SEM/EDS methods. The data were analyzed statistically. Results: In groups NaOCl and NaOCl+EDTA, the calcium (Ca)/phosphorus (P) ratio decreased while the sodium (Na) level increased compared with the other groups (p < 0.05). The magnesium (Mg) level changes were not significant among the groups. A significant positive correlation was found between the results of LIBS and SEM/EDS analyses (r = 0.84, p < 0.001). Conclusions: Treatment with NaOCl for 1 hour altered the mineral content of dentin, while EDTA application for 2 minutes had no effect on the elemental composition. The LIBS method proved to be reliable while providing data for the elemental composition of root canal dentin.

• Journal of the Korea Institute of Building Construction
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• v.21 no.3
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• pp.189-194
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• 2021

LIBS has been attracting attention as an analytical method capable of real-time measurement without sample preparation. In this study, a Lab. scale LIBS device was fabricated to examine the applicability and reproducibility of LIBS in the analysis of chloride contents in mortar. The existing analysis method and LIBS analysis were performed simultaneously on the mortar test specimen with the chloride content adjusted. Compared to the chloride content condition of the mortar, the XRF and Potentiometric Titration results also showed a similar trend. As a result of LIBS analysis, chlorine ions were detected at a wavelength of 837.59 nm according to the chloride content condition. In order to improve the precision in various concentration ranges, the LIBS signal amplification of about 50 times through the electric field enhancement was implemented. Through the verification of the aqueous solution-based reproducibility, a high correlation between the LIBS signal strength and the Cl concentration was confirmed, and the possibility of applying LIBS to the durability diagnosis of concrete damage by chloride was confirmed.

• Advances in environmental research
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• v.2 no.3
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• pp.167-177
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• 2013

We investigated that removal of aqueous U(VI) by nano-sized Zero Valent Iron (nZVI) and Fe(II) bearing minerals (controls) in this study. Iron particles showed different U(VI) removal efficiencies (Mackinawite: 99%, green rust: 95%, nZVI: 91%, magnetite: 87%, pyrite: 59%) due to their different PZC (Point of Zero Charge) values and surface areas. In addition, noticeable amount of surface Fe(II) (181 ${\mu}M$) was released from nZVI suspension in 6 h and it increased to 384 ${\mu}M$ in the presence of U(VI) due to ion-exchange of U(VI) with Fe(II) on nZVI surface. Analysis of Laser-Induced Breakdown Detection (LIBD) showed that breakdown probabilities in both filtrates by 20 and 200 nm sizes was almost 24% in nZVI suspension with U(VI), while 1% of the probabilities were observed in nZVI suspension without U(VI). It indicated that Fe(II) colloids in the range under 20 nm were generated during the interaction of U(VI) and nZVI. Our results suggest that Fe(II) colloids generated via ion-exchange process should be carefully concerned during long-term remediation site contaminated by U(VI) because U could be transported to remote area through the adsorption on Fe(II) colloids.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.4
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• pp.912-919
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• 1994

The engine combustion is one of the most important processes affecting performance and emissions. One effective way to improve the engine combustion is to control the motion of the charge inside a cylinder by means of optimum induction system design, because the flame speed is mainly determined by the turbulence at compression(TDC) process in S.I. engine. It is believed that the tumble and swirl motion generated during intake stroke breaks down into small-scale turbulence in the compression stroke of the cycle. However, the exact nature of this relationship is not well known. This paper describes the tumble flow measurements inside the cylinder of a 4-valve S.I. engine using laser Doppler velocimetry(LDV) under motoring(non-firing) conditions. This is conducted on an optically assesed single cylinder research engine under motored conditions at an engine speed of 1000rpm. Three different cylinder head intake port configurations are studied to develop a better understanding the tumble flow generation, development, and breakdown mechanisms.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.13 no.1
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• pp.1-8
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• 1999

In recent years, concern has been raised about the technique of controlling electrical breakdown by using laser in many fields. Especially, laser has attracted much attention in the Electro-Discharge Machining(EDM) because of its many rrents. 1berefore, this research has been perfonred to obtain fundarrental data for the discharge guide technology by a pulsed Nd:YAG laser which can be awJied to discharge processing machining. 1be experilnnts of laser-guided de discharge have been carried out at low air pressure ranging from 0.2 to 20 torr. The minimum laser-guided de discharge voltage $V_{G.min}$ at the given pressures P and distances d between an anode and a cathode was rreasured It is found that $V_{G.min}$ is much lower than the natural discharge voltage $V_{ND}$, and the values of VGrrin and $V_{ND}$ as a function of P.d has a similar tendency. The laser output energy $E_{out}$ decreases with input pulse duration $t_p$ increasing, and the rrore the value of $t_p$ increases, the higher that of V$V_{G.min}$ is obtained because the number of photons N decreases with $t_p$ increasing. In addition, the laser-guided de discharge range and the discharge guide characteristics as laser outpIt $E_{out}$ was investigated.igated.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.6
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• pp.1175-1179
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• 2009

We analyze voltage characteristics of charged particle type display according to particle layers and cell gap between two electrodes and ascertain the aging effects by measuring the response time of particles with and without aging process. The threshold/driving/breakdown voltage is proportional to layers of charged particles and cell gap and the response time at driving voltage is faster than that of threshold and breakdown voltage because of different q/m of color and black particles. The analysis of response time is a method of estimation of optical characteristics, driving voltage and particle lumping and these results are promoted by aging process. We use the laser and photodiode to measure response time and optical properties. It has not been studied and reported to analyze the relationship of response time, threshold/driving/breakdown voltage, lumping phenomena, cell gap, and aging process for charged particle type display.

• Korean Journal of Materials Research
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• v.15 no.4
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• pp.257-262
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• 2005

Nano-sized ZrVFe alloy powders were prepared by the ablation of powder compact in alcobol using a Nd-YAG pulsed Laser. The $Zr_{57}V_{35.}8Fe_{7.2}$ alloy commercially designated as ST707 has long been known as the ideal solution for various vacuum applications. The target for the ablation was sintered pellets of $Zr_{57}V_{35.}8Fe_{7.2}$ alloy powder. The alloy was prepared by arc melting and Hydride-DeHydride method. The ablated powders were mostly circular having fairly large size distribution smaller than 200 nm in all cases. The X-ray diffraction study revealed that the ablated alloy retained the crystal structure of the target alloy. Nevertheless, Fe and V contents in the ablated powder were lower than those in the target alloy. This was believed to result from the high vapour pressures of Fe and V compared to that of Zr. The size of the powders ablated at high energy fluence tends to decrease due at least partly to the breakdown of previously made ones.

• Proceedings of the KIEE Conference
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• 1990.11a
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• pp.85-87
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• 1990

Silicon nitride film was deposited on a silicon wafer using a laser CVD(LCVD) technique, which is based on direct photolysis of $SiH_4/NH_3$ gas mixture by ArF laser beam(${\lambda}=193\;nm$). The refractive index of deposited SiN film is 1.9 at the temperature of $300^{\circ}C$, pressure of 5 torr. The breakdown field strength of LCVD SiN film was 10MV/cm. In IR spectrum, the absorption peak of Si-H, N-H, and Si-N is detected and it is shown that hydrogen is included in SiN film. From analysis of absorption band. it is calculated that density of Si-H, N-H bond is higher than $5{\times}10^{22}cm^{-3}$. LCVD MIS capacitor and PECVD MIS capacitor have injection-type hysteresis but it is known that hysteresis loss of LCVD MIS capacitor is smaller than that of PECVD MIS capacitor. It means that Interface state density of LCVD capacitor is smaller than that of PECVD capacitor. In addition, the flatband voltage($V_{FB}$) of LCVD is smaller than that of PECVD capacitor. And it means that fixed charged density($Q_{FIX}$) of LCVD capacitor is smaller than that of PECVD MIS capacitor.

• Journal of Electrical Engineering and Technology
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• v.7 no.5
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• pp.784-788
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• 2012

In this paper, a high-performance optical gating in a junction device based on a vanadium dioxide dioxide ($VO_2$) thin film grown by a sol-gel method was experimentally demonstrated by directly illuminating the $VO_2$ film of the device with an infrared light at ~1554.6 nm. The threshold voltage of the fabricated device could be tuned by ~76.8 % at an illumination power of ~39.8 mW resulting in a tuning efficiency of ~1.930 %/mW, which was ~4.9 times as large as that obtained in the previous device fabricated using the $VO_2$ thin film deposited by a pulsed laser deposition method. The rising and falling times of the optical gating operation were measured as ~50 ms and ~200 ms, respectively, which were ~20 times as rapid as those obtained in the previous device.

• Fibers and Polymers
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• v.7 no.2
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• pp.146-157
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• 2006

Traditional spinning systems have reached profitability limits in developed countries due to high production costs and low system productivity. Pneumatic spinning is seen as a developing system, because productivity is much higher than conventional systems. This study evaluates one of the main problems to increase productivity in pneumatic spinning, where air mass-flow is dragged by the drafting cylinders. This flow interacts with the incoming fibres deviating them from their expected path. Via laser anemometry, airflow velocity distribution around drafting cylinders has been measured and it has been found that vorticity is created at the cylinder's inlet. Extensive CFD simulation on the air flow dragged by the cylinders has given a clear insight into the vortex created, producing valuable information on how cylinder design affects the vorticity created. Several drafting cylinder designs have been tested without giving any improvement in productivity. However, the use of a drafting cylinder with holes in it produced good results to the problem of air currents, strongly reducing them and therefore allowing a sharp increase in yarn quality, as well as an increase in productivity. An extensive study on vortex kinematics has been undertaken, bringing with it a better understanding of vortex creation, development and breakdown.