• 제목/요약/키워드: Langmuir-Blodgett technique

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말레에이트계 유기초박막의 가스 반응 특성 분석 (Analysis of Gas Response Characteristics of Maleate Organic Ultra-thin Films)

  • 최용성;김정명;김도균;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권6호
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    • pp.442-450
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    • 1999
  • In this paper, we have fabricated Langmuir-Blodgett(LB) films by LB technique and evaluated the deposited status of LB films by UV-vis absorbance. It was found thatthe thickness of LB films per a layer are $27~30[{\AA}]$ by ellipsometry. The responeses between LB films and organic gases were investigated using by I-V characteristics of LB films and F-R diagram of quartz crystal. The response orders between LB films and organic gases observed by I-V characteristics were as following ; chloroform, methanol, acetone and ethanol in the order of their short chain length. The response mechanism between LB films and organic gases observed by F-R diagram of quartz crystal could be modeled on adsorption at surface, penetration, desorption at surface and inside.

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의료용 초박막 액정의 광배향 제어와 광변위 전류 특성 (Properties of Photo-regulation of Liquid Crystal Alignment and Generation of Maxwell-displacement-current for Application with a Medical Engineering Device)

  • 이호식;안준호;김우연;;이원재
    • 한국전기전자재료학회논문지
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    • 제19권12호
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    • pp.1160-1166
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    • 2006
  • Maxwell-displacement-current (MDC) measuring technique has been applied for the investigation of monolayers of poly(vinyl alcohol)s bearing azobenzene side-chains (6Az5PVA) mixed with p-pentyl-p'-cyano-biphenyls (5CBs) on a water surface. For mixed monolayers containing trans-form 6Az5PVA and LCs, displacement current due to photo isomerization was not generated with alternative photo-irradiation with UV and svisible light. In contrast, for mixed monolaters containing cis-form 6Az5PVA and LCs, displacement current was generated. Finally, it was found that the alignment layers deposited in cis-form could photoregualte the orientation of LCs.

Au/Pl/Au구조의 유기박막 절연성에 관한 연구 (A Study on the Insulation Characteristics of Organic Thin Films of Au/Pl/Au structure)

  • 전동규;김영근;조제황;이경섭;최영일
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1468-1470
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    • 1998
  • Using a solution of polyamic acid salt obtained in combination with polyimide acid, we successfully prepared thermally stable multilayers(41, 35, 31 layers) films disilane-containing polyimide by Langmuir-Blodgett(LB) technique. We studied the electrically phenomena occurring at the metal(Au)/polyimide(Pl) LB film/metal(Au). Also, we then examined the of Pl LB films by means of current-voltage (I-V) and resistance measurement.

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온도 변화에 대한 Q.C.M.의 가스 반응 특성 (Gas Response Properties of Q.C.M. for Various Temperature)

  • 진철남;김경환;강현욱;유승엽;박재철;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1503-1505
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    • 1998
  • Stearic acid was deposited on surface of 9[MHz], AT-cut quartz crystal microbalance as gas sensing material using Langmuir-Blodgett(LB) technique. We measured gas response between deposited LB films and organic gas for various temperature($0{\sim}80^{\circ}C$). The resonant frequency changed due to absorbance of organic gas such as methanol and butanol gas at room temperature. However, the resonant frequency not responded to methanol gas at temperature above melting point of deposited LB films.

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LB법을 이용한 polyimide 초박막의 제작 (Fabrication of Ultrathin Polyimide Films by LB Technique)

  • 김재환;유덕선;김영관;손병청;강도열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1993년도 정기총회 및 추계학술대회 논문집 학회본부
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    • pp.174-177
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    • 1993
  • The polyimide films were prepared by imidizing the polyamic acid long-chain alkylamine (dimethylhexadecylamine) salt films with a thermal and chemical treatment, where the polyamic acid alkylamine salt film were formed on various substrates by using Langmuir-Blodgett (LB) method. The imidization of polyamic acid alkylamine salt films with various thickness were identified with FT-IR and UV-visible absorption spectroscopies. Atomic Force Microscopy (AFM) have been used to investigate the surface morpology of polyamic acid alkylamine salt and imidized films.

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PAHPV LB막의 제작 및 그 발광 특성에 관한 연구 (Study on Preparation of PAHPV LB Films and Their Luminescent Characterisrics)

  • 황장환;추정우;김영관;손병청
    • 한국응용과학기술학회지
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    • 제14권2호
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    • pp.71-79
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    • 1997
  • Ultra-thin films of poly[2-[4-(9-(10-phenyl)anthracenyl)phenoxy)hexyloxy]]-1,4-phenylenevinyleylene(PAHPV) were prepare-d on the hydrophilic ITO substrate by Langmuir-Blodgett(LB) technique. ${\lambda}_{max}$ in the photoluminescence spectrum of these films was 458nm at the excitation wavelength of 365nm before thermal treatment, which comes from diphenylanthracene side chain of PAHPV. It was also confirmed with UV-Vis spectrometer that ultra-thin LB films of PAHPV precursor polymer were prepared well. After thermal treatment for conjugation of PAHPV precursor polymer, ${\lambda}_{max}$ in the photoluminescence spectrum of these films changed to 365nm, which means that the conjugation of these PAHPV films was completed.

유기 한분자학의 광자극 전달에 관한 연구 (A Study on the Light Stimulated Transmit of Organic Monolayers)

  • 강용철;권영수;조수영;박석순;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.156-159
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    • 1996
  • Detection of displacement current across spreading organic Azodyes was investigated using a displacement current measuring technique. It was found that displacement current was generated only when dynamical motion of organic monolayers was initiated on the water surface by photo-isomerization and application of surface pressure. Displacement current was generated only in the range before the initial rise of Surface pressures for azo dyes(8A5H) we are using the Langmuir-Blodgett(LB) films deposition apparatus. We are obtain displacement current by pressure and light

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Disperse diazo black D(DBD) photopolymer의 박막 제작과 이의 물리적 특성에 관한 연구 (A manufacture of disperse diaso black D(DBD) photopolymer thin films and its Physical Properties)

  • 정용환;이호식;변대현;김태완
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1333-1335
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    • 1997
  • We have made disperse diazo black D(DBD) thin films using Langmuir-Blodgett(LB) and vacuum-evaporation technique. Physical and optical properties of the films were investigated. Solution was made with a concentration of $10^{-3}mol/{\ell}$ using chloroform. Moving wall apparatus, (NL-LB140S-MWC) was employed to make the LB films. X,Y and Z-type LB films were manufactured and studied UV/visible absorbance spectra and morphology of surface using atomic force microscopy(AFM). Vacuum-evaporated DB D thin films were made at a pressure of $10^{-5}$ torr. The absorption peaks were observed at 200 and 400 nm in the LB films and vacuum-deposited films. We have also studied photoluminescence spectrum of the DBD films.

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SAW 디바이스를 이용한 냄새센서의 특성 (Characteristics of odorant sensor using SAW Device)

  • 김기영;김종민;신훈규;최웅성;권영수;장상목
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1457-1459
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    • 1994
  • A surface acoustic wave(SAW) sensor for the detection of odorants has been constructed by depositing various phospholipids and fatty acids onto the surface of the SAW device. Applying the Langmuir-Blodgett technique, it was possible to deposit the optimal number of layers which was found to be between 10 and 20. Menthone, amylacetate, acetoin, and other organic gases showed different affinities to the coated lipids. An explanation is given for different odorant affinities based on the monolayer properties of phospholipids.

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Hexyltriphenylphonium-TCNQ 착물(錯物)의 합성(合成)과 분산용매 중에서의 안정성 (Synthesis of Hexyltriphenylphosphonium-TCNQ Complex and Stability in Spreading Solvent)

  • 한종수;황교현;손병청
    • 한국응용과학기술학회지
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    • 제12권1호
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    • pp.115-118
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    • 1995
  • Hexyltriphenylphosphonium-TCNQ(HTPP-TCNQ) complex for preparing organic thin film by Langmuir-Blodgett technique was synthesized from LiTCNQ and Hexyltriphenylphosphonium bromide. The structure of the new complex was confirmed by $^{1}H$ NMR, $^{31}P$ NMR, IR, UV spectroscopies, TGA and elemental analysis. A stability to spreading solvent, which is acetonitrile, ethylacetate, ethanol and acetonitrile-ethylacetate(1:1 v/v), of HTPP-TCNQ complex was investigated by UV-visible spectrophotometer. The complex was stabilized in acetonitrile, ethylacetate, aceton, acetonitrile-ethylacetate (1:1 v/v) for 6 h.