• Title/Summary/Keyword: LI10

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Properties of MFS capacitors with various gate electrodes using $LiNbO_3$ferroelectric thin film ($LiNbO_3$ 강유전체 박막을 이용한 MFS 커패시터의 게이트 전극 변화에 따른 특성)

  • 정순원;김광호
    • Journal of the Korean Vacuum Society
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    • v.11 no.4
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    • pp.230-234
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    • 2002
  • Metal-ferroelectric-semiconductor(MFS) capacitors by using rapid thermal annealed $LiNbO_3$/Si structures were successfully fabricated and demonstrated nonvolatile memory operations of the MFS capacitors. The C-V characteristics of MFS capacitors showed a hysteresis loop due to the ferroelectric nature of the $LiNbO_3$thin film. The dielectric constant of the $LiNbO_3$film calculated from the capacitance in the accumulation region in the capacitance-voltage(C-V) curve was about 25. The gate leakage current density of MFS capacitor using a platinum electrode showed the least value of $1{\times}10^{-8}\textrm{A/cm}^2$ order at the electric field of 500 kV/cm. The minimum interface trap density around midgap was estimated to be about $10^{11}/cm^2$.eV. The typical measured remnant polarization(2Pr) value was about 1.2 $\mu\textrm{C/cm}^2$, in an applied electric field of $\pm$ 300 kv/cm. The ferroelectric capacitors showed no polarization degradation up to about $10^{10}$ switching cycles when subjected to symmetric bipolar voltage pulse in the 500 kHz.

A Study on the Corrosion Behavior of Fe-Ni-Cr Alloys in Molten Salts of LiCl and LiCl-${Li_2}O$ (LiCl 및 LiCl-${Li_2}O$ 용융염에서 Fe-Ni-Cr 합금의 부식거동 연구)

  • Jo, Su-Haeng;Jang, Jun-Seon;Hong, Sun-Seon;Sin, Yeong-Jun;Park, Hyeon-Su
    • Korean Journal of Materials Research
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    • v.10 no.7
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    • pp.471-477
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    • 2000
  • Corrosion behavior of Fe-Ni-Cr alloy in molten salts of LiCl and LiCl-$Li_2O was investigated in the tempera-ture range of $650~850^{\circ}C$. In the molten salt of LiCl, and internal oxidation of Fe occurred in the KSA(Kaeri Superalloy)-1 alloy without containing Cr, while a dense protective oxide scale of $LiCrO_2$ was formed in the KSA-4, Incoloy 800H and KSA-5 alloys. In the mixed molten salt of LiCl-$Li_2O$, internal oxidation of Fe and Cr took place in the KSA-1 and KSA-4 alloys, respectively. Non-protective porous oxide scales consisting of $LiCrO_2$ and Ni were formed in the Incoloy 800H and KSA-5. The corrosion rate of the alloys increased with the increase in Cr content and the corrosion rate followed the parabolic law for the alloy containing Cr content less than 8%, and the linear law for the alloy containing Cr content more than 8%. Such a corrosion behavior of the alloy in the mixed molten salt of LiCl-$Li_2O$ was interpreted in terms of the basic fluxing mechanism of protective oxide scale of $Cr_2O_3$.

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Synthesis of Defective-Structure Li4Mn5O12 by Combustion Method and Its Application to Hybrid Capacitor (연소합성법에 의한 결함구조 Li4Mn5O12제조와 하이브리드 커패시터 적용)

  • Kim, Hun-Uk;Sun, Yang-Kook;Lee, Bum-Suk;Jin, Chang-Soo;Shin, Kyoung-Hee
    • Journal of the Korean Electrochemical Society
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    • v.13 no.2
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    • pp.103-109
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    • 2010
  • $Li_4Mn_5O_{12}$ was synthesized by combustion method using $LiNO_3$, $Li(CH_3COO){\cdot}2H_2O$ and $Mn(CH_3COO)_2{\cdot}4H_2O$. $Li_4Mn_5O_{12}$ was obtained over $400^{\circ}C$, however, the sample calcined at $400^{\circ}C$ for any time was mixed phases of $Li_4Mn_5O_{12}$ and $Mn_2O_3$. $Li_4Mn_5O_{12}$ calcined at $400^{\circ}C$ for 5 h had larger first discharge capacity (41.5mAh/g) at 1C-rate for 3.7~4.4V than other calcined samples. Moreover, applying to hybrid capacitor, it had good discharge capacity (24.74 mAh/g or 10.46 mAh/cc) at 100 mA/g for 1~2.5 V and higher energy density (39Wh/kg or 16.49Wh/cc) at same condition.

Utilization of Drone LiDAR for Field Investigation of Facility Collapse Accident (붕괴사고 현장조사를 위한 드론 LiDAR 활용)

  • Yonghan Jung ;Eontaek Lim ;Jaewook Suk;Seul Koo;Seongsam Kim
    • Korean Journal of Remote Sensing
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    • v.39 no.5_2
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    • pp.849-858
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    • 2023
  • Investigating disaster sites such as earthquakes and landslides involves significant risks due to potential secondary disasters like facility collapse. In situations where direct access is challenging, there is a need to develop methods for safely acquiring high-precision 3D disaster information using light detection and ranging (LiDAR) equipped drone survey systems. In this study, the feasibility of using drone LiDAR in disaster scenarios was examined, focusing on the collapse accident at Jeongja Bridge in Bundang-gu, Seongnam City, in April 2023. High-density point clouds for the accident bridge were collected, and the bridge's 3D terrain information was reconstructed and compared to the measurement performance of 10 ground control points. The results showed horizontal and vertical root mean square error values of 0.032 m and 0.055 m, respectively. Additionally, when compared to a point cloud generated using ground LiDAR for the same target area, a vertical difference of approximately 0.08 m was observed, but overall shapes showed minimal discrepancies. Moreover, in terms of overall data acquisition and processing time, drone LiDAR was found to be more efficient than ground LiDAR. Therefore, the use of drone LiDAR in disaster sites with significant risks allows for safe and rapid onsite investigations.

A study on the approximation function for pairs of primes with difference 10 between consecutive primes (연속하는 두 소수의 차가 10인 소수 쌍에 대한 근사 함수에 대한 연구)

  • Lee, Heon-Soo
    • Journal of Internet of Things and Convergence
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    • v.6 no.4
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    • pp.49-57
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    • 2020
  • In this paper, I provided an approximation function Li*2,10(x) using logarithm integral for the counting function π*2,10(x) of consecutive deca primes. Several personal computers and Mathematica were used to validate the approximation function Li*2,10(x). I found the real value of π*2,10(x) and approximate value of Li*2,10(x) for various x ≤ 1011. By the result of theses calculations, most of the error rates are margins of error of 0.005%. Also, I proved that the sum C2,10(∞) of reciprocals of all primes with difference 10 between primes is finite. To find C2,10(∞), I computed the sum C2,10(x) of reciprocals of all consecutive deca primes for various x ≤ 1011 and I estimate that C2,10(∞) probably lies in the range C2,10(∞)=0.4176±2.1×10-3.

Electric Properties of MFIS Capacitors using Pt/LiNbO3/AlN/Si(100) Structure (Pt/LiNbO3/AlN/Si(100) 구조를 이용한 MFIS 커패시터의 전기적 특성)

  • Jung, Soon-Won;Kim, Kwang-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.12
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    • pp.1283-1288
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    • 2004
  • Metal-ferroelectric-insulator-semiconductor(WFIS) capacitors using rapid thermal annealed LiNbO$_3$/AlN/Si(100) structure were fabricated and demonstrated nonvolatile memory operations. The capacitors on highly doped Si wafer showed hysteresis behavior like a butterfly shape due to the ferroelectric nature of the LiNbO$_3$ films. The typical dielectric constant value of LiNbO$_3$ film in the MFIS device was about 27, The gate leakage current density of the MFIS capacitor was 10$^{-9}$ A/cm$^2$ order at the electric field of 500 kV/cm. The typical measured remnant polarization(2P$_{r}$) and coercive filed(Ec) values were about 1.2 $\mu$C/cm$^2$ and 120 kV/cm, respectively The ferroelectric capacitors showed no polarization degradation up to 10$^{11}$ switching cycles when subjected to symmetric bipolar voltage pulses of 1 MHz. The switching charges degraded only by 10 % of their initial values after 4 days at room temperature.e.

A Case Report of Cold Sensitivity of Hand by Korean Medical Treatment with Hominis Placenta Pharmacopunture at LI4 and LI10 (합곡, 수삼리 자하거약침요법을 병행한 복합 한방치료의 수부냉증 치험례)

  • Jang, Seung Hoon;Kim, Ki-Choon;Yun, Jung Hun;Yim, Yun-Kyoung
    • Korean Journal of Acupuncture
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    • v.31 no.4
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    • pp.240-246
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    • 2014
  • Objectives : The purpose of this study is to report the clinical effects of Korean medical treatment with Hominis Placenta Pharmacopunture(HPP) on cold hypersensitivity of hands. Methods : A 46-year-old female patient whose chief complaint was cold hypersensitivity of hands was treated with Placenta Pharmacopunture at LI4 and LI10, ten times for a month. Acupuncture and herbal medicine were added depending on the symptoms. Digital Infrared Thermal Imaging(D.I.T.I) was taken and Visual Analog Scale(VAS) was examined before and after each treatment. Results : After the treatments, the symptoms were improved. Conclusions : DITI and VAS showed that the patient's cold hypersensitivity of hands was improved after Korean medical treatment with Hominis Placenta Pharmacopuncture.

Dynamic Pyroelectric Properties and Their Frequency Dependences of $LiTaO_3$ crystal ($LiTaO_3$crystal Dynamic 초전 특성과 그 주파수 의존성)

  • 이원재;윤영섭
    • Proceedings of the IEEK Conference
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    • 1998.10a
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    • pp.605-608
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    • 1998
  • In this paper, we have investigated the pyroelectric characteristics of the $20\mu\textrm{m}-thick$ $LiTaO_3$ single crystal with black coating by using the nondestructive dynamic method. The $LiTaO_3shows$ the maximum pyroelectric coefficient (${\gamma}$) of $1.56$\times$10-8C/\textrm{cm}^2K$ at 40Hz and the responsivity (Rv) is 488V/W at 2Hz. The noise equivalent power (NEP) is obtained as 3.95$\times$10-10W/√Hz at 40Hz. The detectivity (D*) is obtained divided by the sample area and estimated to be 5.6$\times$108cm√Hz/W at 40Hz. These results, shows that the $LiTaO_3$ single crystals are the best candidates to pyroelectric IR sensors.

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One-step Microwave Synthesis of Hierarchical Structured LiFePO4 using Citric Acid

  • Wu, Mihye;Choi, Sungho;Kang, Yongku;Jung, Ha-Kyun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.10
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    • pp.2901-2905
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    • 2014
  • The hierarchical-structured $LiFePO_4$ cathode materials were synthesized by one-step microwave synthesis, and their electrochemical properties were investigated. Addition of citric acid during the reaction lead to the formation of hierarchical structured $LiFePO_4$, which has both nano- and micron-characteristics advantageous for energy density and electrode fabrication. Adjusting the molar ratio of Fe to citric acid enhanced the electrochemical properties of $LiFePO_4$.

Effect of Cations on the open-Circuit Photovoltage and the Charge-Injection Efficiency of Dye-Sensitized Nanocrys-talline Rutile $TiO_2$ Films

  • Park, Nam Gyu;Jang, Sun Ho;Kim, Gang Jin
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.1047-1048
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    • 2000
  • Dye-sensitized nanocrystalline rutile $TiO_2$ solar cells were prepared, and the influence of Li+ and 1,2-dimethyl-3-hexyl imidazolium ions in the electrolyte on the photovoltaic properties was compared. The electrolyte con-taining Li+ ions produced a lower open-circuit photovoltage than the electrolyte with 1,2-dimethyl-3-hexyl im-idazolium ions, suggesting that the adsorption of Li+ ions to the rutile $TiO_2$ surface causes a shift in the band edges toward more positive potentials. At the same time, both the short-circuit photocurrent and the maximum value of the incident-photon-current conversion efficiency (IPCE) of the electrolyte containing Li+ ions were relatively higher. Data analysis suggests that presence of adsorbed Li+ ions improves via the phenomenon of band-edge movement the charge-injection efficiency by altering both the energy and number of excited state levels of the dye that participate in electron injection.