• 폴리머
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• 제37권5호
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• pp.606-612
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• 2013

$Al(O-i-Pr)_3$을 촉매로 이용하고 중합 개시제로 glycidol을 사용하여 L-lactide를 개환중합하여 glycidol-poly(lactide)(Gly-PLA)를 얻었다. $^1H$ NMR 분석 결과 glycidol의 말단에 존재하는 수산기가 Gly-PLA에는 존재하지 않았고 이를 통해 glycidol의 말단에 존재하는 OH기가 개시제의 역할을 하여 중합이 진행되었음을 확인하였다. Llactide용액중합과 벌크중합을 진행하였으며, L-lactide/glycidol 몰비, 중합 온도와 시간에 따라 생성된 Gly-PLA의 분자특성을 관찰하였다. L-lactide/glycidol 몰비가 증가할수록 수율과 분자량은 증가하였다. 또한 L-lactide/glycidol 몰비가 증가할수록 저분자량에 해당하는 낮은 녹는점 피크는 줄어들고, 고분자량에 해당하는 높은 녹는점 피크가 증가하였다.

• 한국자원식물학회지
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• 제21권5호
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• pp.357-361
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• 2008

고품질의 곰취, 곤달비 및 한대리곰취를 지속적으로 생산할 수 있는 임간재배기술을 개발하고자 횡성군 둔내면의 산채마을 임간재배지에 생육중인 세 식물종의 광합성을 특성을 조사 비교하였다. 광도에 따른 곰취류의 광합성율의 평균은 광도가 높아질수록 높아지는 경향을 보였다. 광도에 따른 곰취의 광합성율의 평균은 광도가 높아질수록 높아지다가 1,600 PPFD에서 최대치인 $21.1{\mu}mol\;CO_{2}m^{-2}s^{-1}$를 보이고 2,000 PPFD에서는 낮아졌다. 한대리곰취가 $27.39({\mu}mol\;CO_{2}m^{-2}s^{-1})$로 가장 높은 광합성율을 보였고, 곰취, 곤달비 순으로 낮아졌다. 5월 27일 측정에서 모두 식물종간 통계적 유의차가 인정되었으며 광합성율은 한대리곰취, 곰취, 곤달비 순이었고, 6월 21일 측정 광합성율은 한대리금취, 곤달비, 곰취순이었다. 횡성군 둔내면 산채마을과 같은 해발고가 낮은 지역에서는 곰취나 곤달비 보다는 한대리곰취의 임판재배가 적합할 것이라 사료된다.

• 분석과학
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• 제32권5호
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• pp.163-172
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• 2019

Methamphetamine (MA) is currently the most abused illicit drug in Korea and its major metabolite is amphetamine (AP). As MA exist as two enantiomers with the different pharmacological properties, it is necessary to determine their respective amounts in a sample. Thus a chiral stationary phase liquid chromatography-tandem mass spectrometric (LC-MS/MS) method was developed for identification and quantification of d-MA, l-MA, d-AP, and l-AP in human urine. Urine sample ($200{\mu}L$) was diluted with pure water and purified using solid-phase extraction (SPE) cartridge. A $5-{\mu}L$ aliquot of SPE treated sample solution was injected into LC-MS/MS system. Chiral separation was carried out on the Astec Chirobiotic V2 column with an isocratic elution for each enantiomer. Identification and quantification of enantiomeric MA and AP was performed using multiple reaction monitoring (MRM) detection mode. Linear regression with a $1/x^2$ as the weighting factor was applied to generate a calibration curve. The linear ranges were 25-1000 ng/mL for all compounds. The intra- and inter-day precisions were within 3.6 %, while the intra- and inter-day accuracies ranged from -5.4 % to 11.8 %. The limits of detection were 2.5 ng/mL (d-MA), 3.5 ng/mL (l-MA), 7.5 ng/mL (d-AP), and 7.5 ng/mL (l-AP). Method validation parameters such as selectivity, matrix effect, and stability were evaluated and met acceptance criteria. The applicability of the method was tested by the analysis of genuine forensic urine samples from drug abusers. d-MA is the most common compound found in urine and mainly used by abusers.

• The Korean Journal of Ecology
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• 제6권4호
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• pp.243-249
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• 1983

Absorption pattern of potassium, calcium, phosphate and nitrate ions, and the pH change during ion-absorption at pH 3.0-11.0 by Oryza sativa L. were studied to investigate indirectly the evidence of H^+-efflux by ATPase. The rice seedlings which were grown either in $L^{\circ} -dark or in L^+-sunlight$, were used both in each ion-absorption to compare with one another. The uptake rate of these ions appeared to favor more in $L^+than in L^{\circ}$, over all range in pH, nearly with the same pattern. The absorption of potassium resulted in bell shape and that of calcium increased linearly to the alkali range. The shape of phosphate-absorption showed nearly the t-distribution curve with high value in acid range and the uptake of nitrate resulted in the dual peaks, but higher in acid range. The pH of the external solution changed from the range of 3.5-11.0 to 3.5-7.0 after lhr-absorptioin, and further acidified after 3hr-absorption. It is suggested that the pH change of the external solution be affected by $ H^+-efflux$ which may be caused by the ATP-hydrolysis.

• 분석과학
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• 제15권1호
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• pp.67-71
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• 2002

Imidzole계 살균제 prochloraz의 토양(미사질식토) 잔류량 및 반감기를 전자포획검출기를 이용한 기페크로마토그래피로 분석하였다. 토양시료는 acetone/hexane (1:1) 용매로 추출하였고, $LC-NH_2$ Sep-Pak 고체컬럼으로 분리하였다. 표준검정곡선의 감응함수는 0.05~1.00 ng 범위에서 Y = 268.8600X + 0.0664, $R^2=0.9998$ 이었다. 검출한계는 0.02 mg/mL 이었고, 회수율은 0.10 mg/L의 경우 97.3%, 0.40 mg/L의 경우 94.5% 이었다. 반감기는 실내토양에서 24.4일, 포장토양에서 7.6일 이었다.

• Journal of Astronomy and Space Sciences
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• 제2권2호
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• pp.101-115
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• 1985

Using Brandt model the mess distribution of the late type spiral galaxy NGC 6946 was derived, and the total mass was reestimated to understand the M/L ratio of this galaxy. Two kinds of the rotation curve with shape parameter n=1 and 3.3 were examined. The following are the main results; (1) The total masses of NGC 6946 are $3.1\times$$10^{11}$ M(n=1) AND $2.8\times$$10^{11}$ M(n=3.3) respectively. and the corresponding M/L are about 17 and 16 for both cases. (2) The optical image in the blue light, whose radius is 9.6 kpc, has 8$\times$$10^{10}$ M and 1.4$\times$$10^{11}$ M. These give the value of M/L about 5 and 8 respectively. (3) The masses and M/L of the nuclear region within 1.2 kpc are 4.0$\times$$10^{9}$ M 4.7$\times$$10^9$ M and 3, 4 for both cases. Those of the disk from 1.2 kpc to 9.6 kpc are 7.6$\times$1$10^{10}$M, 1.4$\times$$10^{11}$M, and 5, 8. (4) The masses of the outer halo extended to few hundreds kiloparsecs are 2.3$\times$$10^{11}$ M and 1.4$\times$$10^{11}$M. The corresponding M/L are about 62 and 37.

• 한국농공학회지
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• 제43권3호
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• pp.85-93
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• 2001

In this study, a computer program considering shape imperfections of arch under dynamic loading was developed. The shape imperfection of arch was assumed as higher degree polynomial expressed as $\omega$$_{i}$ = $\omega$$_{o}$ (1-(2$\chi$/L)$^{m}$ )$^n$and sinusoidal curve such as $\omega$$_{i}$ = $\omega$$_{o}$ sin(η$\pi$$\chi$/L). In finite element formulation, the material nonlinear behavior was assumed the elasto-viscoplastic model highly corresponding to the real behavior of the material and the geometrically nonlinear behavior was modeled using Lagrangian description of motion. Also, the behavior of steel was modeled by applying yield criteria of Von Mises. The developed program was applied to the analysis of the dynamic behavior for the clamped beam subjected to the concentrated load at midspan and the results were compared with those from other research to investigate accuracy of the presented finite element program. In numerical examples, the shape imperfections of L/500, L/1,000 and L/2,000 were considered and the modes of shape imperfections of the symmetric and antisymmetric were adopted. The effects of the shape imperfections on the dynamic behavior of arch were conspicuous and results of analysis indicate that the reasonable values of arch rise to arch span ratio ranged between 0.1 and 0.3.

• 한국임상수의학회지
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• 제14권2호
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• pp.195-200
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• 1997

In order to compare the pharmacokinetic profiles of enrofloxacin-HCL)ENFLX-HCL) and enrofloxacin-KOH (ENFLX-KOH) after oral administration in broiler chickens, the study was performed. The chickens used in this study weighed $1.82 {\pm}0.2 kg$ and clinically healthy. The dose of intravenous and lral administration was 5 mg per kg of body weight as enrofloxacin. After intravenous injection of enrofloxacin, it showed two-compartment model with the rapid distribution phase and the slow elimination phase. The mean apparent volume of distribution (Vd) was 2.70 l/kg. The mean half-life of elimination and distribution showed 8.26 h and 0.44 h, respectively. The mean area under curve (AUC) was calculated as $19.7 {\mu} g{\cdot} h/ml$. After oral administration of ENFLX-HCL and ENFLX-KOH with a rate of dose 5 mg of enrofloxacin/kg of body weight, Both of the products were showed one-compartment model unlike that of i.v. enrofloxacin standard solution showed the mean bioavailability of 79.64% for the ENFLX-KOG and 86.24% for the ENFLX-HCL. The mean total body clearance of the former was 0.24 l/kg/h and the latter 0.42 l/kg/h. Both enorfloxacin formulations seemed to have good tissue distribution and penetration as indicated by large volume of distribution : 2.72 l/kg for the -KOH and 4.44 l/kg for the -HCL. With the results obtained in this study, ENFLX-HCL could be used in place of its salt form in chickens.

• Bulletin of the Korean Chemical Society
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• 제23권10호
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• pp.1381-1391
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• 2002

The solvent sublation using ion pairs of metal-2-naphthoate(2-HNph) and tetrabutyl ammonium ($TBA^+$) ion has been studied for the concentration and determination of ultra trace Bi(III), In(III) and Tl(Ⅲ) ions in water samples. The partition coefficients ($K_p$) and the extraction percentages of 2-HNph and the ion pairs to methyl isobutyl ketone (MIBK) were obtained as basic data. After the ion pair $TBA^+$·M$(Nph)_4^-$ was formed in water samples, the analytes were concentrated by the solvent sublation and the elements were determined by GF-AAS. The pH of the sample solution, the amount of the ligand and counter ion added and stirring time were optimized for the efficient formation of the ion pair. The type and amount of optimum surfactant, bubbling time with nitrogen and the type of solvent were investigated for the solvent sublation as well. 10.0 mL of 0.1 M 2-HNph and 2.0 mL of 0.1 M $TBA^+$ were added to a 1.0 L sample solution at pH 5.0. After 2.0 mL of 0.2%(w/v) Triton X-100 was added, the ion pairs were extracted into 20.0 mL MIBK in a flotation cell by bubbling. The analytes were determined by a calibration curve method with measured absorbances in MIBK, and the recovery was 80-120%.

• 대한기계학회논문집A
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• 제28권4호
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• pp.333-342
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• 2004

Tensile and low cycle fatigue (LCF) tests on prior cold worked 316L stainless steel were carried out at various temperatures from room temperature to 650$^{\circ}C$. At all test temperatures, cold worked material showed the tendency of higher strength and lower ductility compared with those of solution treated material. The embrittlement of material occurred in the temperature region from 300$^{\circ}C$ to 600$^{\circ}C$ due to dynamic strain aging. Following initial cyclic hardening for a few cycles, cycling softening was observed to dominate until failure occurred during LCF deformation, and the cyclic softening behavior strongly depended on temperature and strain amplitude. Non-Masing behavior was observed at all test temperatures and hysteresis energy curve method was employed to describe the stress-strain hysteresis loops at half$.$life. The prediction shows a good agreement with the experimental results.