• Elastomers and Composites
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• v.25 no.2
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• pp.112-116
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• 1990

In this study, as one way of developing the new cross-linking method that is curable in water, kinetic analysis of solution reaction between CR and silane coupling agents was attemped. First, CR was reacted with silane coupling agents in solution state. According to the time, reaction quantity was pursued by gas chromatography. Also, reaction rate coefficient and activation energy were calculated from the reaction quantity. Silane coupling agents which were used in this study were MPS, CPS and VES.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2022.05a
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• pp.481-482
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• 2022

In this paper, effect of random dopant fluctuation (RDF) of the top-transistor in a monolithic 3D inverter composed of MOSFET transistors is investigated with 3D TCAD simulation when the gate voltage of the bottom-transistor is changed. The sampling for investigating RDF effect was conducted through the kinetic monte carlo method, and the RDF effect on the threshold voltage variation in the top-transistor was investigated, and the electrical coupling between top-transistors and bottom-transistors was investigated.

• Journal of Ocean Engineering and Technology
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• v.8 no.2
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• pp.151-156
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• 1994

The equations of motion of a submarine pipeline with the internal flowing fluid and subject to hydrodynamic loadings are derived by using Hamilton's principle. Coupling between the bending and the longitudinal extension due to axial load and thermal expansion are considered. Coupling between the twisting and extension are not considered. The equations of motion are well agreed with the results which are derived by the vector method.

• Wind and Structures
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• v.14 no.3
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• pp.239-252
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• 2011

The wind-induced mean, background and resonant responses of Beijing National Stadium are investigated in this paper. Based on the concepts of potential and kinetic energies, the mode participation factors for the background and the resonant components are presented and the dominant modes are identified. The coupling effect between different modes of the resonant response and the coupling effect between the background and resonant responses are analyzed. The coupling effects between the background and resonant components and between different modes are found all negligible. The mean response is approximately analogous to the peak responses induced by the fluctuating wind. The background responses are significant in the fluctuating responses and it is much larger than the resonant responses at the measurement locations.

• Applied Chemistry for Engineering
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• v.3 no.2
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• pp.256-265
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• 1992

The kinetics for the oxidative coupling of methane over NaCl(30wt%)/ZnO(60wt%)/${\alpha}-Al_2O_3$ catalyst was investigated, and then the active oxygen species were discussed. The conversion rate of methane was measured at the atmospheric pressure with various combinations of partial pressure of methane and oxygen at temperature range of $650^{\circ}C{\sim}750^{\circ}C$, at conversions less than with 10%. These rate data were then used to verify the proposed Langmuir-Hinshelwood kinetic equation. The rate limiting step appeared to be the formation of the methyl radicals by the reactin of the adsorbed methane and the adsorbed oxygen, which were adsorbed on the different active sites of the catalyst. The activation energy of the methyl radical formation was estimated to be ca. 39 kcal/mol. From the kinetic studies, the oxygen species respolsible for the formation of methyl radicals was proposed to be diatomic oxygen such as $O{_2}{^{2-}}$ or $O_2{^-}$ on the surface.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.967-972
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• 2008

This paper presents the free vibration analysis of a circular plate with a concentric square hole. The present problem deals with the numerical calculation of the natural frequencies and mode shapes of vibration of the structure by means of Independent Coordinate Coupling Method (ICCM). In this study, the boundary condition is the edge of the square hole is free and the outer circular plate is simply supported. Due to the geometric abnormality, this analysis does not permit an exact solution. Since the ICCM employs coordinate systems corresponding to each domain independently, the kinetic and potential energy expressions necessary for the Rayleigh-Ritz method can be easily obtained. Lastly, the kinematic relation is imposed. In this way, the eigenvalue problem can be easily set up. The numerical results show the efficacy of the ICCM and changes in natural frequencies and modes due to the square hole size.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.20 no.4
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• pp.440-445
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• 2011

This paper presents a new regenerative brake system of electric vehicles that employs a continuous variable transmission(CVT) and a flywheel. The developed device has advantages over existing regenerative brakes from a standpoint of reliability and versatility in actual driving conditions. The system consists of a CVT, two wheels, a flywheel, a coupling and auxiliary powertrain components. The CVT is designed as a combination of two cones and a roller, which causes the velocity difference between the wheel and the flywheel. The power flow of the flywheel system is controlled by the CVT roller and the coupling through step motors. A prototype has been developed and then its performance has been investigated for various operating conditions. Results show that the storage efficiency of the flywheel is much affected by the vehicle's velocity and it is reduced below 20% for high speed, as compared to the 25% efficiency for an ideal condition. The CVT is a primary factor for lowering the flywheel efficiencies due to large friction and slipping between the cone and the roller.

• Journal of the Korean Ceramic Society
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• v.32 no.3
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• pp.341-348
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• 1995

An analysis of the use of temperature profiles in the determination of the kinetic parameters of combustion synthesis of Ti5Si3 were investigated. From profile analysis, an apparent activation energy of 12KJ/mol was calculated. The Maximum heating rate achieved during 10wt% Ti5Si3 reaction by the product dilution method was approximately $1.5\times$104 K/s. Coupling this value with the measured wave velocity of 7.02 cm/s yields a maximum thermal gradient of 2.14$\times$103 K/cm. The value of tr (=t*) was calculated to be 1.2$\times$10-1 s and the value of td (=tx) was calculated to be 32.89 s. Using the definition of t* and the measured wave velocity, the effective thermal diffusivity, $\alpha$, was calculated to be 0.59$\times$10 $\textrm{cm}^2$/s. From these analysis, the power function, G, was also calculated.

• Proceedings of the Korean Society for Applied Microbiology Conference
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• 1986.12a
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• pp.510.1-510
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• 1986

Many enzymes require the participation of readily dissociable coenzymes as NAD for thir catalytic activities. The continuous utilization of the enzymes requires the retention and regeneration of the coenzymes. For this purpose, several kinds of macromolecular NAD derivatives have been prepared by covalently attaching NAD to watersoluble polymers. We have prepared poly (ethylene glycol)-bound NAD (PEG-NAD) by coupling N$\^$6/-(2-carboxyethyl)-NAD to one terminal of ${\gamma}$ $\omega$-diaminoly (ethylene glycol) (Mr 3000) with water-soluble carbodiimide. PED-NAD thus obtained has one NAD moiety located at a terminal of the linear, flexible and hydrophilic chain of poly (ethylene glycol). PED-NAD has good coenzyme activity for various dehydrogenases and is applicable in a continuous enzyme reactor. To use these macromolecular NAD derivatives in an enzyme reactor, it si necessary to understand the behavior of the system in which the reactions of dehydrogenases are coupled by the recycling of the NAD derivative. We investigated the kinetic properties of a continuous enzyme reactor containing lactate dehydrogenase, alcohol dehydrogenase and PEG-NAD. The steady-state behavior of the enzyme reactor is explained by a simple kinetic model.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.5
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• pp.855-861
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• 1989

An inertia redistribution technique for liberalizing and reducing the complexity of manipulator dynamics with a parallel drive mechanism is presented in this paper. The dynamic design method is based on eliminating nonlinear terms, such as Coriolis, centrifugal and gravity torque in the kinetic and the potential energy of a manipulator. A set of design criteria regarding the inertia properties of links is derived. The resulting manipulator dynamics can be greatly simplified for each robot. This paper particularly presents that it is possible to completely linearize the manipulator dynamics with a parallel drive mechanism.